Modular Approach to Saturated and α,β-Unsaturated Ketones
2-Fluoro-6-pyridinyloxy derivatives of 2-ethoxyvinyl carbinols react with radicals derived from xanthates by an addition–fragmentation pathway to give highly functionalized ketones after acid hydrolysis.
Béatrice Quiclet-Sire (1672969) +2 more
core +1 more source
Strategies Towards Asymmetric Conjugate Trifluoromethylation of α,β-Unsaturated Ketones and the Asymmetric Conjugate Addition of Boronates to β-Trifluoromethyl α,β-Unsaturated Ketones [PDF]
Currently, there are no reported methods in the literature for the conjugate addition of the trifluoromethyl group to α,β-unsaturated ketones. A bulk of this thesis focused on developing a method to overcome this problem.
Wawrykow, Matthew
core
Presented are reactivities of 2-oxo-alkenylphosphonates as hetero 1,3-diene and some synthetic utilization of these new types of functionalized α, β-unsaturated ketones via hetero Diels-Alder reaction or Michael reaction.
Wada, Eiji, 和田, 英治
core
Chromium-catalyzed cross-coupling of methyl ketones with cyclic ketones to β-branched β,γ-unsaturated ketones are reported. Interestingly, single-crossed aldol condensation products are formed, even in reactions in which a mixture of products is possible.
Kalishankar Bhattacharyya (1479832) +3 more
core +1 more source
Acyl-oxyallenes as α,β-unsaturated ketone surrogates for Giese radical addition. [PDF]
Jin J +5 more
europepmc +1 more source
Room temperature synthesis of α,β-unsaturated nitriles by manganese-catalysed base-free coupling of α-saturated nitriles with aldehydes. [PDF]
Thiyagarajan S +5 more
europepmc +1 more source
Oxidative Stability and Quality Deterioration of <i>Ganoderma lucidum</i> Spore Oil Under Accelerated Storage Conditions. [PDF]
Ge Z +5 more
europepmc +1 more source
Chemical Diversity and Microbial Complexity of Liupao Tea Aroma: A Comprehensive Review. [PDF]
Ye S +5 more
europepmc +1 more source
Metal-Free Oxidative Functionalization of Allylic Sulfones/Allylic Triflones with Water Participation Enabled by Hypervalent Iodine Reagents. [PDF]
Tong Q, Xiao LT, Gu MY, Chu XQ, Ge D.
europepmc +1 more source
Emerging progress in ruthenium-catalyzed transfer and asymmetric transfer hydrogenation. [PDF]
Wahidur Rahaman SM.
europepmc +1 more source

