Results 61 to 70 of about 1,019,081 (92)

Synthesis of β,γ-Unsaturated Ketones via Cerium-Mediated Addition of Organolithiums to Silylated Enaminones

open access: yes, 2016
Synthesis of β,γ-Unsaturated Ketones via Cerium-Mediated Addition of Organolithiums to Silylated ...
Letizia Sambri (1724191)   +5 more
core   +1 more source

Strategies Towards Asymmetric Conjugate Trifluoromethylation of α,β-Unsaturated Ketones and the Asymmetric Conjugate Addition of Boronates to β-Trifluoromethyl α,β-Unsaturated Ketones [PDF]

open access: yes, 2014
Currently, there are no reported methods in the literature for the conjugate addition of the trifluoromethyl group to α,β-unsaturated ketones. A bulk of this thesis focused on developing a method to overcome this problem.
Wawrykow, Matthew
core  

Strategy for the Preparation of Allenes from α,β-Unsaturated and Saturated Ketones via Enol Phosphates

open access: yes, 2016
Strategy for the Preparation of Allenes from α,β-Unsaturated and Saturated Ketones via Enol ...
Kay M. Brummond (1334937)   +2 more
core   +1 more source

Catalytic Asymmetric Epoxidation of α,β-Unsaturated Ketones Promoted by Lanthanoid Complexes

open access: yes, 2016
Catalytic Asymmetric Epoxidation of α,β-Unsaturated Ketones Promoted by Lanthanoid ...
Hiroaki Sasai (1764031)   +4 more
core   +1 more source

Chromium-Catalyzed Cross-Coupling of Methyl Ketones with Cyclic Ketones toward the Selective Synthesis of β‑Branched β,γ-Unsaturated Ketones

open access: yes
Chromium-catalyzed cross-coupling of methyl ketones with cyclic ketones to β-branched β,γ-unsaturated ketones are reported. Interestingly, single-crossed aldol condensation products are formed, even in reactions in which a mixture of products is possible.
Kalishankar Bhattacharyya (1479832)   +3 more
core   +1 more source

Thionation of Some α,β-Unsaturated Steroidal Ketones

open access: yes, 2010
The reactions of selected α,β-unsaturated steroidal ketones with Lawesson’s reagent (LR) in CH2Cl2 and toluene under the standard reaction conditions and with a combination of phosphorus pentasulfide with hexamethyldisiloxane (P4S10/HMDO) in 1,2 ...
Pavlović   +3 more
core   +1 more source

β′‐Hydroxy‐α,β‐unsaturated ketones: A new pharmacophore for the design of anticancer drugs. Part 2.

open access: yes, 2008
Novel antiproliferative β′‐acyloxy‐α,β ‐unsaturated ketones were obtained by means of an iron(III)‐catalyzed multicomponent domino process (ABB′ 3CR).
Miranda, Pedro O.   +13 more
core   +1 more source

Regioselective 1,4-trifluoromethylation of α,β-unsaturated ketones via a S-(trifluoromethyl)diphenylsulfonium salts/copper system

open access: yes, 2013
Regioselective conjugate 1,4-trifluoromethylation of α,β-unsaturated ketones by the use of shelf-stable electrophilic trifluoromethylating reagents, S-(trifluoromethyl)diphenylsulfonium salts and copper under mild conditions is described. A wide range of
Etsuko Tokunaga   +3 more
core   +1 more source

Studies on the Development of New Synthetic Reagents : Synthetic Utilization of Functionalized α,β-Unsaturated Ketones

open access: yes, 1993
Presented are reactivities of 2-oxo-alkenylphosphonates as hetero 1,3-diene and some synthetic utilization of these new types of functionalized α, β-unsaturated ketones via hetero Diels-Alder reaction or Michael reaction.
Wada, Eiji, 和田, 英治
core  

Bismuth(III) bromide catalyzed Michael addition of allyltrimethylsilanes to α,β-unsaturated ketones

open access: yes, 2019
The products of 1,4-addition of nucleophiles to α,β-unsaturated ketones are of interest as they are easily amenable to further synthetic manipulations.
Guingrich, Richard, Reichert, Robert
core  

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