Results 121 to 130 of about 29,210 (204)

Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation

Angewandte Chemie, EarlyView.
A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang, Irena Efremenko, Thiyagarajan Subramanian, Amit Kumar, Liat Avram, Yael Diskin‐Posner, David Milstein   +6 more
wiley   +2 more sources

Cobalt‐Catalyzed Radical Ligand Transfer (RLT) Enables Remote‐Markovnikov Hydroamination of Alkenes

Angewandte Chemie, EarlyView.
A cobalt‐catalyzed remote‐Markovnikov 1,3‐hydroamination of allyl carboxylates proceeds through MHAT, 1,2‐radical acyloxy migration (1,2‐RAM), and radical ligand transfer (RLT) from a Co‐N intermediate, providing protected amino alcohols. ABSTRACT Amino alcohols are prevalent in pharmaceuticals, agrochemicals, and functional materials, yet ...
Arman Khosravi, Ho Martin Yuen, Seth Fremin, Nuwan A. Pannilawithana, Nol Supasueb, Yu Zhang, Peng Liu, Ming‐Yu Ngai   +7 more
wiley   +2 more sources

Three Component Thio‐ and Carboboration of Alkynes: A Modular Route to Functionalised Bicyclic Boronates

Angewandte Chemie, EarlyView.
Three‐component thio‐ and carbo‐boration reactions to form functionalised benzoxaborinines and benzazaborinines are reported. The nucleophile scope includes thioethers, thiols, and (hetero)arenes. Mechanistic studies revealed a disparity between thioboration using thioethers and using thiols.
Laura Winfrey, Gary S. Nichol, Stephen P. Thomas, Dominic R. Willcox, Michael. J. Ingleson   +4 more
wiley   +2 more sources

Synthesis of LY503430 by using a selective rearrangement of β-amino alcohols induced by DAST

ARKIVOC, 2014
Béranger Duthion, Domingo Gomez Pardo, Janine Cossy   +2 more
doaj   +1 more source

Exploring Zinc(II) Coordination Chemistry with Picolinate and Amino Alcohols: Toward New Antibacterial Agents. [PDF]

ACS Omega
Modec B, Podjed Rihtaršič N, López-Serrano J, Hrast Rambaher M, Golob M.   +4 more
europepmc   +1 more source

Functional and Network PHAs via Stereoselective Polymerization and Tailored Post‐Transformation

Angewandte Chemie, EarlyView.
Catalyst‐controlled stereoselective (co)polymerization of functionalized lactones produces vinyl‐, allyl‐, and propargyl‐functionalized PHAs with high syndiotacticity and a broad applicable temperature window, which can be further transformed into crosslinked PHA thermosets, elastic supramolecular networks, and functional grafts. ABSTRACT Incorporation
Ruirui Li, Yingluo Zhao, Jun‐Jie Tian, Ethan C. Quinn, Yunpeng Gao, Maëlle T. Gace, Eugene Y.‐X. Chen   +6 more
wiley   +2 more sources

Copper-Catalyzed Amino-alkoxycarbonylation of Unactivated Alkenes: Synthesis of β-Amino Esters via Primary Tosyl Amidyl Radical. [PDF]

Org Lett
Mao X, Hou M, Wang Y, Miao RG, Wu XF.
europepmc   +1 more source

Hydrogen transfer-triggered C(sp³)-C(sp³) cleavage of 1,3-diols for mono-N-methylation of primary amines. [PDF]

Nat Commun
Long Y, Liu J, Chen L, Dong J, Fan X, Qu L, Su Z, Zheng Y.   +7 more
europepmc   +1 more source

Interaction and Flavor Metabolic Function of Microbiota During Fermentation of Pigskin Through Bioaugmentation with <i>Latilactobacillus sakei</i>. [PDF]

Molecules
Wang Q, Ji L, Dong X, Zhang S, Liu K, Zheng J.   +5 more
europepmc   +1 more source

A new approach to morpholin-2-one derivatives via the reaction of β-amino alcohols with dicyanofumarates

ARKIVOC, 2012
Grzegorz Mlostoń, Adam M. Pieczonka, Korany A. Ali, Anthony Linden, Heinz Heimgartner   +4 more
doaj   +1 more source