Results 91 to 100 of about 226,730 (296)

Remarkable effect of stacking on the electronic and optical properties of few layer black phosphorus

, 2015
The effect of the number of stacking layers and the type of stacking on the electronic and optical properties of bilayer and trilayer black phosphorus are investigated by using first principles calcula- tions within the framework of density functional ...
Cakir, Deniz, Peeters, Francois M., Sevik, Cem   +2 more
core   +1 more source

Band Alignment in In‐Oxo Metal Porphyrin SURMOF Heterojunctions

Advanced Functional Materials, EarlyView.
Porphyrin core metalation in indium‑oxo SURMOFs enables systematic tuning of band edge positions without altering the crystal structure. First‑principles calculations reveal type‑I and type‑II heterostructures as well as multi‑junction energy cascades, establishing a modular strategy for exciton funneling and charge separation in optoelectronic ...
Puja Singhvi, Nina Vankova, Thomas Heine
wiley   +1 more source

tert-Butyl 2,3-dihydro-1H-cyclopenta[b]indole-4-carboxylate

IUCrData, 2016
In the title molecule, C16H19NO2, all the non-hydrogen atoms except two of the C atoms of the tert-butyl group lie on a crystallographic mirror plane. No classical hydrogen bonds are observed.
Jason A. Jordon, Jeanese C. Badenock, Gordon W. Gribble, Manpreet Kaur, Jerry P. Jasinski   +4 more
doaj   +1 more source

Photoswitching Conduction in Framework Materials

Advanced Functional Materials, EarlyView.
This mini‐review summarizes recent advances in state‐of‐the‐art proton and electron conduction in framework materials that can be remotely and reversibly switched on and off by light. It discusses the various photoswitching conduction mechanisms and the strategies employed to enhance photoswitched conductivity.
Helmy Pacheco Hernandez, Stefan Hecht, Wolfgang Wenzel, Lars Heinke, Mariana Kozlowska   +4 more
wiley   +1 more source

Crystal structure of 2-(adamantan-1-yl)-5-(4-bromophenyl)-1,3,4-oxadiazole

Acta Crystallographica Section E, 2014
In the title molecule, C18H19BrN2O, the benzene ring is inclined to the oxadiazole ring by 10.44 (8)°. In the crystal, C—H...π interactions link the molecules in a head-to-tail fashion, forming chains extending along the c-axis direction.
Nourah Z. Alzoman, Ali A. El-Emam, Hazem A. Ghabbour, C. S. Chidan Kumar, Hoong-Kun Fun   +4 more
doaj   +1 more source

Controlled Synthesis of Organic/Inorganic van der Waals Solid for Tunable Light-matter Interactions

, 2015
Van der Waals (vdW) solids, as a new type of artificial materials that consist of alternating layers bonded by weak interactions, have shed light on fascinating optoelectronic device concepts.
Chang, Tay Rong, Cong, Chunxiao, Fu, Qundong, Fu, Wei, He, Haiyong, Jeng, Horng Tay, Jin, Chuanhong, Lin, Hsin, Liu, Xinfeng, Liu, Zheng, Najmaei, Sina, Niu, Lin, Sum, Tze Chien, Tay, Beng Kang, Wang, Hong, Wang, Xingli, Wu, Chunyang, Wu, Di, Yakobson, Boris I., Yu, Peng, Yu, Ting, Zeng, Qingsheng, Zhang, Zhuhua, Zhou, Jiadong, Zhou, Wu   +24 more
core   +1 more source

Backbone Heterojunction Photocatalysts for Efficient Sacrificial Hydrogen Production

Advanced Functional Materials, EarlyView.
Herein, a ‘single‐component’ organic semiconductor photocatalyst is presented in which a molecular donor is bonded to a polymer acceptor. The resultant material demonstrates exceptional photocatalytic activity for hydrogen evolution in aqueous triethylamine with an outstanding external quantum efficiency of 38% at 420 nm.
Richard J. Lyons, Rhys J. Bourhill, Ewan McQueen, Sam D. Harding, Krzysztof Pawlak, Thomas Fellowes, Harry W. Capps, Alexander J. Cowan, Andrew I. Cooper, Adrian M. Gardner, Martijn A. Zwijnenburg, Reiner Sebastian Sprick   +11 more
wiley   +1 more source

2-Oxo-2H-chromen-4-yl 4-ethylbenzoate

IUCrData
In the title compound, C18H14O4, the dihedral angle between the coumarin moiety and the phenyl fragment is 63.46 (5)°. In the crystal, the molecules are linked by weak C—H...O hydrogen bonds and aromatic π–π stacking interactions. A short C=O...π [O...π =
Valentin Bationo, Abel Landry Tebily, Akoun Abou, Charles Bavouma Sombié, Rasmané Semdé, Abdoulaye Djandé   +5 more
doaj   +1 more source

N-Centered Chiral Self-Sorting and Supramolecular Helix of Tröger's Base-Based Dimeric Macrocycles in Crystalline State

Frontiers in Chemistry, 2019
Three stereoisomers of Tröger's Base-based dimeric macrocycles Trögerophane 1 (T1) including one pair of enantiomers (rac-T1) and one meso isomer (R2NS2N-T1) were obtained and fully characterized by X-ray analysis.
Yuan Chen, Ming Cheng, Benkun Hong, Qian Zhao, Cheng Qian, Juli Jiang, Shuhua Li, Chen Lin, Leyong Wang, Leyong Wang   +9 more
doaj   +1 more source

Supraparticles Composed of Graphitic Carbon Nitride Nanoparticles and Silica‐Supported Horseradish Peroxidase as Customizable Hybrid Catalysts for Photo‐Biocatalytic Cascade Reactions in Continuous Flow

Advanced Functional Materials, EarlyView.
Herein presented supraparticles combine the nanoparticulate photocatalyst graphitic carbon nitride with the enzyme horseradish peroxidase, which is immobilized on silica nanoparticles. In an optimized compatibility range, both catalysts operate effectively within the hybrid supraparticles and catalyze a cascade reaction consisting of the photocatalytic
Bettina Herbig, Egzon Cermjani, Doris Hanselmann, Johannes Prieschl, Angelika Schmitt, Michael S. Moritz, Christian Papp, Greta Nölke, Stefano Di Fiore, Christoph Deckers, Thomas H. Rehm, Susanne Wintzheimer   +11 more
wiley   +1 more source