, 2008 本发明涉及一种酶催化烯烃环氧化的方法，于水溶液中，以溴过氧化物酶为生物催化剂，以双氧水或氧气为氧源，将烯烃氧化成为环氧化合物；以环己烯为例，双氧水为氧源，在20～75℃温度下，反应2-10小时，产物环氧环己烷对双氧水的收率大于50％，环氧环己烷的选择性大于85％。反应结束后，水相与有机相自动分层，存在于水相中的酶等可重复利用。本方法工艺操作简单，酶可重复利用，产物易分离，是环境友好的绿色化学过程 ...
于 瑶, 张 卫, 靳 艳
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