Vanadium-Containing Anionic Chelate for Spectrophotometric Determination of Hydroxyzine Hydrochloride in Pharmaceuticals [PDF]
Four azo dyes known to form anionic complexes with V(V) were investigated as potential liquid–liquid extraction–spectrophotometric reagents for the antihistamine medication hydroxyzine hydrochloride (HZH).
Gergana Kirilova Kirova +3 more
doaj +2 more sources
State-of-the-Art, Insights, and Perspectives for MOFs-Nanocomposites and MOF-Derived (Nano)Materials. [PDF]
Different approaches to MOF‐NP composite formation, such as ship‐in‐a‐bottle, bottle‐around‐the‐ship and in situ one‐step synthesis, are used. Owing to synergistic effects, the advantageous features of the components of the composites are beneficially combined, and their individual drawbacks are mitigated.
Mourdikoudis S +6 more
europepmc +2 more sources
The Crystal Structure of 1-(2-Thiazolylazo)-6-bromo-2-naphthol [PDF]
Abstract The crystals of 1-(2-thiazolylazo)-6-bromo-2-naphthol are orthorhombic, with a space group of P212121, and with unit-cell dimensions of a=19.044(3), b=31.996(9), c=4.221(1) Å, and z=8. The crystal structure was solved by the heavy-atom method and refined by the least-squares technique to give an R value of 0.064 for 1608 ...
Masayasu Kurahashi
exaly +2 more sources
Use of 1-(2-thiazolylazo) 2-naphthol in rapid determination of iron in geological matrices [PDF]
The present work describes the use of 1-(2-thiazolylazo)-2-naphthol (TAN) as a spectrophotomeric reagent for iron determination. TAN reacts with iron(II) forming a brown complex with absorption maximum at 575 and 787 nm. The following parameters were studied: complex stability, pH effect, amount of the TAN, buffer selection, amount of acetate buffer ...
Sérgio Luis Costa Ferreira
exaly +3 more sources
Rapid Spectrophotometric Determination of Chromium(III) with 1-(2-Thiazolylazo)-2-naphthol in Presence of Surfactant [PDF]
Abstract Chromium(III) reacts with 1-(2-thiazolylazo)-2-naphthol at 80–95°C in acid media (pH 5.7), in presence of benzoate and sodium dodecyl sulfate. Presence of surfactant increases sensitivity of the complex and reduces heating time to 5 min, thus giving rise to perhaps the most rapid method for absorptiometric determination of ...
RATHAIAH, GV, ESHWAR, MC
exaly +3 more sources
THE MOLECULAR STRUCTURES OF PALLADIUM(II), COPPER(II) AND NICKEL(II) CHELATE OF 1-(2-THIAZOLYLAZO)-2-NAPHTHOL [PDF]
Abstract The structures of palladium(II), copper(II) and nickel(II) chelate of 1-(2-thiazolylazo)-2-naphthol have been determined by X-ray analysis. The coordination configuration around the metal atom has been found to be square-planar, square-pyramidal and octahedral for palladium, copper and nickel, respectively.
Masayasu Kurahashi
exaly +2 more sources
Crystal Structures of 1-(2-Thiazolylazo)-6-bromo-2-naphthol and Bis(1-(2-thiazolylazo)-2-naphthol)iron(II) [PDF]
Masayasu Kurahashi, Ken Hirotsu
exaly +2 more sources
Comparing CLE-AdCSV applications using SA and TAC to determine the Fe-binding characteristics of model ligands in seawater [PDF]
Competitive ligand exchange–adsorptive cathodic stripping voltammetry (CLE-AdCSV) is used to determine the conditional concentration ([L]) and the conditional binding strength (logKcond) of dissolved organic Fe-binding ligands, which together influence ...
L. J. A. Gerringa +4 more
doaj +1 more source
The hydrophobic azo dye 6-hexyl-4-(2-thiazolylazo)resorcinol (HTAR, H2L) was studied as part of a system for the centrifuge-less cloud point extraction (CL-CPE) and spectrophotometric determination of traces of cobalt. The extracted 1:2 (Co:HTAR) complex,
Kiril Blazhev Gavazov +6 more
doaj +1 more source
Two new vanadium (V) complexes involving 6-hexyl-4-(2-thiazolylazo)resorcinol (HTAR) and tetrazolium cation were studied. The following commercially available tetrazolium salts were used as the cation source: tetrazolium red (2,3,5-triphenyltetrazol-2 ...
Kiril B. Gavazov +4 more
doaj +1 more source

