Results 41 to 50 of about 415,539 (315)

1H-NMR based lipid profiling of Gossypium hirsutum seed oil at different developmental stages

open access: yesCurrent Research in Green and Sustainable Chemistry, 2021
1H-NMR spectroscopy is emerging as powerful robust analytical technique in analyzing bio constituents present in plants. It offers non-invasive method for identification and quantification of several Phyto-constitutes in a single step without much pre ...
Nikita J. Kurkuri   +3 more
doaj   +1 more source

Solvent-Induced 1h Nmr Chemical Shifts of Annulenes

open access: yesComputational and Theoretical Chemistry, 2023
We investigate the effect of solvent polarity on the 1H NMR chemical shifts of [n]annulenes (n = 12, 18, and 30) using density functional theory and corroborate the computational results with Onsager’s reaction field theory. We observe that there is a complete deshielding of the proton NMR chemical shifts for the outer protons and these shifts depend ...
Swrangsi Goyary   +3 more
openaire   +1 more source

Synthesis and structure of trans-1,2,3- tris(3-thenoyl)cyclopropane [PDF]

open access: yes, 1994
The title cyclopropane derivative, C18H12O3S3, was synthesized and its structure investigated by single-crystal X-ray diffraction and spectroscopic methods.
Saba, Antonio
core  

Study of cascade ring-closing metathesis reactions en route to an advanced intermediate of Taxol [PDF]

open access: yes, 2016
A highly functionalized intermediate in the synthesis of Taxol has been synthesized, which features the tricyclic core and the required oxygen substituents at C1, C2, C7, C10 and C13. The key step, a ring-closing dienyne metathesis (RCDEYM) reaction, has
Letort, Aurélien   +2 more
core   +1 more source

MnI‐Functionalized Covalent Organic Framework as Efficient Electrocatalyst for CO2 Reduction in a Catholyte‐Free Zero‐Gap Electrolyzer

open access: yesAdvanced Functional Materials, EarlyView.
This work demonstrates the successful integration of a phenanthroline‐based 2D COF with MnI catalytic sites into a catholyte‐free membrane‐electrode‐assembly cell for CO2 electroreduction. The crystalline COF actively suppresses Mn⁰–Mn⁰ dimerization, achieving a turnover frequency of 617 h⁻¹ at 2.8 V (full‐cell potential), and enabling stable operation.
Laura Spies   +8 more
wiley   +1 more source

Spectral Analysis of Glucose-Based Chiral N-heterocyclic Carbene Precursors

open access: yesChinese Journal of Magnetic Resonance, 2018
1-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-3-butylimidazolium bromide (compound 2) was synthesized with 1-bromobutane and 1-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl) imidazole (compound 1), which is a glucose-derived chiral N-heterocyclic carbene ...
ZHOU Zhong-gao   +4 more
doaj   +1 more source

Positive allosteric binding behavior of pyrene-appended triazole-modified thiacalix[4]arene-based fluorescent receptors [PDF]

open access: yes, 2014
The novel heteroditopic receptors 5a∼c have been synthesized, which bear a thiacalix[4]arene in the 1,3-alternate conformation. Two urea moieties possessing various aryl groups with either electron-donating or -withdrawing groups at their p-positions ...
Ni, Xin-Long   +5 more
core   +2 more sources

Modulating Two‐Photon Absorption in a Pyrene‐Based MOF Series: An In‐Depth Investigation of Structure–Property Relationships

open access: yesAdvanced Functional Materials, EarlyView.
This study investigates H4TBAPy‐based metal–organic frameworks (MOFs) ‐ NU‐1000, NU‐901, SrTBAPy, and BaTBAPy ‐ for multiphoton absorption (MPA) performance. It observes topology‐dependent variations in the 2PA cross‐section, with BaTBAPy exhibiting the highest activity.
Simon N. Deger   +10 more
wiley   +1 more source

A Wide-Line Solid-State 1H NMR Study of Phase Structures of Semi-Crystalline Polymers

open access: yesChinese Journal of Magnetic Resonance, 2019
Wide-line solid-state proton nuclear magnetic resonance (1H NMR) spectrometry is a classical technique to study the phase structures of semi-crystalline polymers.
WU Jin-ze   +3 more
doaj   +1 more source

Dinickel Bisphenoxyiminato Complexes for the Polymerization of Ethylene and α-Olefins [PDF]

open access: yes, 2012
Dinuclear nickel phenoxyiminato olefin polymerization catalysts based on rigid p-terphenyl frameworks are reported. Permethylation of the central arene of the terphenyl unit and oxygen substitution of the peripheral rings ortho to the aryl–aryl linkages ...
Agapie, Theodor   +2 more
core   +1 more source

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