Results 91 to 100 of about 149,288 (230)

Cysteine Thioaldehydes: Photolytic Generation, Reactivity, and Biological Implications

Angewandte Chemie, EarlyView.
Photolysis of cysteine phenacylsulfides bearing non‐conjugating electron‐withdrawing substituents leads to high conversions into cysteine thioaldehydes through a Norrish type‐II pathway. This methodology enabled the study of the aqueous reactivity of these important biosynthetic intermediates, which, depending on peptide sequence, pH and buffer ...
Ardra Karthika, Matthew Murray, Guillermo Palop, Lee‐Ann J. Keane, Patrick McArdle, Nicholas D. J. Yates, Christopher D. Spicer, Alison Parkin, Martin A. Fascione, Eddie L. Myers   +9 more
wiley   +2 more sources

Impact of 2,4-D Micro-Rates on non-2,4-D Tolerant Soybean

, 2020
Auxin type herbicides (eg. dicamba, 2,4-D) are an integral component of major cropping systems in North America. With the recent launching of Enlist E3 soybean in the U.S., in-season application of 2,4-D to soybean fields is expected to increase. This will enable use of Enlist One and Enlist Duo herbicides thus broadening farmers’ flexibility in ...
Cuvaca, Ivan, Jovanović, Darko, Scott, Jon   +2 more
openaire   +1 more source

Interpretability and Representability of Commutative Algebra, Algebraic Topology, and Topological Spectral Theory for Real‐World Data

Advanced Intelligent Discovery, EarlyView.
This article investigates how persistent homology, persistent Laplacians, and persistent commutative algebra reveal complementary geometric, topological, and algebraic invariants or signatures of real‐world data. By analyzing shapes, synthetic complexes, fullerenes, and biomolecules, the article shows how these mathematical frameworks enhance ...
Yiming Ren, Guo‐Wei Wei
wiley   +1 more source

Compact Modeling of Volatile‐Switching Electrochemical Metallization Memory Cells by Means of the Electromotive Force

Advanced Intelligent Systems, EarlyView.
A volatile‐switching compact model of electrochemical metallization memory cells for neuromorphic architecture is developed and validated by reliable reproduction of device characterization measurements: I−V sweeps, SET kinetics, relaxation dynamics.
Rana Walied Ahmad, Solomon Amsalu Chekol, Julius Rasbach, Susanne Hoffmann‐Eifert, Stephan Menzel   +4 more
wiley   +1 more source

Titanium‐Catalyzed Defluorination of Poly(Vinyl Fluoride) and Poly(Vinylidene Fluoride) Under Friedel–Crafts Conditions

Angewandte Chemie, EarlyView.
Cationic titanium sandwich catalysts display exceptional activity in the hydrodefluorination of Csp3─F bonds, in the presence of silanes and aromatic solvents (turnover numbers up to 3000). As a result, they can be used to defluorinate challenging fluoropolymers, such as poly(vinyl fluoride) (PVF) or poly(vinylidene fluoride) (PVDF).
Louis Le Moigne, Marie Sircoglou, Quentin Bonnin, Marie‐José Penouilh, Joan Vignolle, Etienne Grau, Cédric Le Coz, Mélanie Bousquet, Paul Fleurat‐Lessard, Adrien T. Normand   +9 more
wiley   +2 more sources

Uncovering renewable energy policy impact channels on land values, the local farm structure, and farmland heterogeneity

American Journal of Agricultural Economics, EarlyView.
Abstract Germany's Renewable Energy Sources Act (REA), enacted in 2000 and subsequently amended, subsidized national renewable energy production with fixed feed‐in tariffs for renewable energy sources (RE) from wind, solar, and biogas. Empirical studies suggest that the policy was creating windfall effects for landowners and attribute farmland use ...
Lars Isenhardt, Stefan Seifert, Saskia Wolff, Tobia Lakes, Marten Graubner, Axel Werwatz, Silke Hüttel   +6 more
wiley   +1 more source

Selective Degradation of Polyurethanes in Mixed Plastic Wastes via Ir‐Catalyzed Hydrogenolysis

Angewandte Chemie, EarlyView.
The selective degradation of polyurethanes in mixed plastic wastes with polyesters and polyamides was achieved using H2 as a reactant, enabling simultaneous recovery of diformamides and polyols arising from polyurethanes and separation of polyesters and polyamides without any degradation.
Yuto Yamada, Takanori Iwasaki, Shinji Tanaka, Kyoko Nozaki   +3 more
wiley   +2 more sources

The potency of native postbiotics and paraprobiotics in modulating inflammation by affecting the gut–kidney axis

Animal Models and Experimental Medicine, EarlyView.
Native postbiotics and paraprobiotics derived from Lactobacillus and Bifidobacterium strains were administered to dextran sulfate sodium–treated C57BL/6 mice to evaluate their impact on kidney inflammation via the gut–kidney axis. Histological analysis and quantitative polymerase chain reaction of autophagy‐related genes (atg5, atg7, atg12, atg13 ...
Fatemeh Haririzadeh Jouriani, Mahnaz Torfeh, Fatemeh Ashrafian, Niloofar Rezaie, Mohsen Mohammadi, Shadi Aghamohammad, Mahdi Rohani   +6 more
wiley   +1 more source

Au(I) Complex With an Abnormal Carbene Ligand Shows Anti‐Kasha Dual Photoluminescence Emission

Angewandte Chemie, EarlyView.
Incorporation of an abnormal N‐heterocyclic carbene into a heteroleptic linear Au(I) complex induces anti‐Kasha dual emission responsive to biologically relevant phenyl sulfate. ABSTRACT We report the first photoactive linear Au(I) complex with an abnormal N‐heterocyclic carbene (aNHC) ligand, Au(aIm)(Cz).
Natesan Mannangatti Rajendran, Seung Beom Cheon, Jungbin Shin, Ye Bin Jang, Taeyoon Kim, Youngmin You   +5 more
wiley   +2 more sources

Nullwertige Nickelatome stabilisiert in oberflächengestützten metallorganischen Ketten

Angewandte Chemie, EarlyView.
Mit 9,10‐Dicyanoanthracen koordinierte nullwertige Ni(0) d10‐Zentren auf Ag(100), die eine metallorganische Kette mit quasi‐eindimensionaler Metall‐Ligand‐Wechselwirkung bilden. ZUSAMMENFASSUNG Die Stabilisierung von nullwertigen Ni(0)‐Zentren in ausgedehnten Koordinationsnetzwerken bleibt aufgrund ihrer ausgeprägten Reaktivität und Anfälligkeit für ...
Simone Mearini, Dominik Brandstetter, Mira S. Arndt, Olga Resel, Daniel Baranowski, Yan Yan Grisan Qiu, Peter Puschnig, Martin Sterrer, Giovanni Zamborlini, Vitaliy Feyer, Claus M. Schneider   +10 more
wiley   +1 more source