Results 31 to 40 of about 291 (140)
Journal of Physical Organic Chemistry, Volume 39, Issue 7, July 2026.Irradiation of 4‐azido‐2,6‐dichlorophenol in cryogenic matrices generates triplet 2,6‐dichloro‐4‐hydroxyphenylnitrene. Vibronically structured absorption enables extension of a formally forbidden transition into the visible region (up to 500 nm). Analyses based on NICS(1.7)zz, ACID, HOMA, MCI, and spin density reveal magnetically induced ring currents ...
Dharma Raj Joshi +5 more
wiley +1 more source
European Journal of Organic Chemistry, Volume 29, Issue 23, 16 June 2026.1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer +6 more
wiley +1 more source
Angewandte Chemie, Volume 137, Issue 23, June 2, 2025.Stable imino‐substituted Au(III) carbenes are easily and efficiently prepared by trapping the transient (N^C^C)Au←:CH(dmp)+ carbene with nitriles. The corresponding free species are readily generated and display dual carbene / nitrile‐ylide reactivities. The diazo decomposition, nitrile insertion, and carbene transfer can be combined in three‐component
Rui Wei +4 more
wiley +2 more sources
Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application
European Journal of Organic Chemistry, Volume 29, Issue 19, 22 May 2026.Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley +1 more source
Journal of Physical Organic Chemistry, Volume 39, Issue 4, April 2026.New calculations have been applied to the pyrolysis of pyrrole under shock‐tube conditions and to the radical‐radical reaction between allyl and •CN at low temperature and pressure, using the same mechanistic scheme for both. ABSTRACT The pyrolysis of pyrrole has previously been studied in shock‐tube experiments and in jet‐stirred reactors. The results
Barry K. Carpenter
wiley +1 more source
Beilstein Journal of Organic Chemistry, 2015 The reaction of α-azidochalcones with carboxylic acids has been investigated resulting in the formation of α-amido-1,3-diketones under microwave irradiation via in situ formation of 2H-azirine intermediates.
Kandasamy Rajaguru +4 more
doaj +1 more source
Recent Contributions of Organic Synthesis to Forensic Science
ChemPlusChem, Volume 91, Issue 2, February 2026.Forensic science is a multidisciplinary field that plays a vital role in providing scientific evidence for criminal investigations. This review highlights advances and opportunities at the interface between organic synthesis and forensic science, with applications in drug identification, forensic toxicology, and latent fingerprint detection and ...
Gustavo dos Santos Martins +3 more
wiley +1 more source
Polymerization‐Induced Direct Photolithography of Quantum Dots
Macromolecular Rapid Communications, Volume 46, Issue 18, September 19, 2025.We present a comprehensive overview of photochemical polymerization strategies for direct lithographic patterning of colloidal quantum dots (QDs). Reaction mechanisms are categorized by functional group type, and their application is discussed in terms of pattern fidelity, photostability, and environmental robustness, highlighting the potential of ...
Taehyung Kim +3 more
wiley +1 more source
ChemistryOpen, Volume 14, Issue 7, July 2025.Quinazoline represents an important class of heterocycles with diverse medicinal and pharmacological significance. This review systematically examines scholarly efforts toward understanding different synthetic pathways emphasizing the role of metal and non‐metal catalysts including some miscellaneous reagents employed in the synthesis of quinazoline ...
Neha Manhas +4 more
wiley +1 more source
Continuous-Flow Synthesis of 2H-Azirines and Their Diastereoselective Transformation to Aziridines [PDF]
Synlett, 2015 Using continuous-flow techniques, a small collection of 2H-azirines was prepared from oxime precursors via mesylation and base-promoted cyclisation. The 2H-azirines were either isolated after in-line purification or derivatised into a selection of 2-substituted aziridines through a telescoped reaction sequence involving nitrile, trifluoromethyl, or ...
Baumann, Marcus, Baxendale, Ian R.
openaire +3 more sources