, 2011 2H-Azirines have shown an unusual potential to synthesise aziridines and other types of compounds. Many functionalized aziridines can be produced by addition of O-, S-,N-, C-nucleophiles and hydride to 2H-azirines. This review is designed to give an overview of the reactivity of 2H-azirines as electrophiles along the years and their usefulness in the ...
Alves, M. José, Costa, Flora Teixeira e
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Photocarboxylation of Arylated 2H‐Azirines Exploiting Continuous Flow Technology
European Journal of Organic Chemistry, Volume 28, Issue 18, May 23, 2025.An efficient continuous process for the synthesis of trisubstituted oxazoles is reported which links the photochemical opening of azirines and the subsequent trapping of the azomethine ylides with CO2 gas. This highlights challenges and solutions when incorporating CO2 as a feedstock material for the photochemical synthesis of small heterocyclic ...
Arlene Bonner +2 more
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A Review on the Photochemistry of 2H-Azirines [PDF]
HETEROCYCLES, 1977 Gilgen, Paul +3 more
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Synthesis and crystal structures of new chiral 3-amino-2H-azirines and the Pd complex of one of them. [PDF]
Acta Crystallogr C Struct Chem, 2023 Linden A +4 more
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Copper-Catalyzed Highly Enantioselective Addition of a Silicon Nucleophile to 3-Substituted 2H-Azirines Using an Si-B Reagent. [PDF]
Angew Chem Int Ed Engl, 2023 Zhao ZY, Cui M, Irran E, Oestreich M.
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Azirinium Ylides from Alkoxycarbonylcarbenoids and 2H‐Azirines: Generation and Transformations.
ChemInform, 2006 AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Khlebnikov, Alexander F. +5 more
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Copper(II)-Catalyzed (3+2) Cycloaddition of 2H-Azirines to Six-Membered Cyclic Enols as a Route to Pyrrolo[3,2-c]quinolone, Chromeno[3,4-b]pyrrole, and Naphtho[1,8-ef]indole Scaffolds. [PDF]
Molecules, 2022 Sakharov PA +3 more
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DFT and AFIR study on the copper(i)-catalyzed mechanism of 5-enamine-trisubstituted-1,2,3-triazole synthesis via C-N cross-coupling and the origin of ring-opening of 2H-azirines. [PDF]
RSC Adv, 2021 Yu F, Zhou Z, Song J, Zhao Y.
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Synthesis of α-Aminophosphonic Acid Derivatives Through the Addition of O- and S-Nucleophiles to 2H-Azirines and Their Antiproliferative Effect on A549 Human Lung Adenocarcinoma Cells. [PDF]
Molecules, 2020 Carramiñana V +3 more
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