Coinage Metal Complexes as Chiral Catalysts for 1,3-Dipolar Cycloadditions [PDF]
In this account, we describe the experience of our research group in the implementation of chiral coinage metal complexes into the efficient enantioselective 1,3-DC of azomethine ylides derived from α-amino acids and azlactones with different ...
Nájera, Carmen, Sansano, Jose M.
core +2 more sources
Bis‐Furans: A Sustainable Source of Diverse Molecular Architectures
A concise synthetic route to diverse acyclic and heterocyclic compounds has been developed by combining hetero‐Diels–Alder reactions, DBU‐promoted ring openings, and Lewis base‐catalyzed annulations. Nitrosoalkenes reacted with furan derivatives to form 4a,7a‐dihydro‐4H‐furo[2,3‐e][1,2]oxazines, which underwent DBU‐promoted rearrangements to 6H‐1,2 ...
Ana L. Cardoso +2 more
wiley +1 more source
Fused 1,5-benzothiazepines from o-aminothiophenol and its derivatives as versatile synthons
This review describes the reactions of o-aminothiophenol and its derivatives as building blocks for the synthesis of polyfunctionalised 1,5-benzothiazipines with pharmacological interest.
Batchu Chandra Sekhar
doaj
Kinetic and Thermodynamic Approaches for the Efficient Formation of Mechanical Bonds [PDF]
Among the growing collection of molecular systems under consideration for nanoscale device applications, mechanically interlocked compounds derived from electrochemically switchable bistable [2]rotaxanes and [2]catenanes show great promise. These systems
Aprahamian, Ivan +7 more
core +1 more source
Synthesis of 2- and 3-indolylpyrroles via 1,3-dipolar cycloadditions of munchnones and nitroalkenes
– A series of 2-and 3-indolylpyrroles were generated via 1,3-dipolar cycloadditions between (2-nitrovinyl)indoles and symmetrical and unsymmetrical 1,3-oxazolium-5-olates (münchnones)
J. Lopchuk, G. Gribble
semanticscholar +1 more source
Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis
Mechanochemistry offers a sustainable, solvent‐free alternative to traditional synthesis, often enhanced by additives in a process known as additive‐assisted grinding. This review discusses how various additives, including liquids, ionic solids, and advanced materials like ionic liquids and piezoelectric compounds, improve reaction efficiency ...
Johanna Breinsperger +3 more
wiley +1 more source
Recent Progress on Giant Molecules: Synthesis, Assembly, and Applications
Giant molecules are molecules constructed by molecular nanoparticles with precise, rigid structure, have similar structures with small molecules and a large size as macromolecules. In this review, the constituent modules of giant molecules, as well as their synthesis, self‐assembly, applications in various fields and future developing prospect are ...
Haoyu Chen +7 more
wiley +1 more source
Binap-silver-catalyzed enantioselective multicomponent 1,3-dipolar cycloaddition of azomethines ylides derived from ethyl glyoxylate [PDF]
The enantioselective binap–silver catalyzed multicomponent 1,3-dipolar cycloaddition using ethyl glyoxylate, phenylalanine ethyl ester, and maleimides is described. The employment of basic silver carbonate allows the reaction to take place in the absence
Mancebo Aracil, Juan +2 more
core +2 more sources
Sulfur Ylides in Skeletal‐Editing—Ring Expansion Reactions
Sulfur ylides (S‐ylides) are emergent diazo surrogates that enable skeletal editing and ring expansion with safer handling and broad functional group tolerance. This perspective covers pioneer works and highlights recent advances in the field, while outlining key challenges and future directions that may redefine the role of S‐ylides in modern ...
Arsala Kamal +3 more
wiley +1 more source
Synthesis of 3,5-Disubstituted Isoxazoles and Isoxazolines in Deep Eutectic Solvents [PDF]
The synthesis of different 3,5-disubstituted isoxazoles and related isoxazolines using choline chloride:urea as deep eutectic solvent (DES) in a one-pot three step reaction has been accomplished successfully. The use of highly nucleophilic functionalized
Pérez Galera, Juana María +1 more
core +3 more sources

