Results 81 to 90 of about 51,592 (230)

Coinage Metal Complexes as Chiral Catalysts for 1,3-Dipolar Cycloadditions [PDF]

open access: yes, 2014
In this account, we describe the experience of our research group in the implementation of chiral coinage metal complexes into the efficient enantioselective 1,3-DC of azomethine ylides derived from α-amino acids and azlactones with different ...
Nájera, Carmen, Sansano, Jose M.
core   +2 more sources

Bis‐Furans: A Sustainable Source of Diverse Molecular Architectures

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 10, 9 March 2026.
A concise synthetic route to diverse acyclic and heterocyclic compounds has been developed by combining hetero‐Diels–Alder reactions, DBU‐promoted ring openings, and Lewis base‐catalyzed annulations. Nitrosoalkenes reacted with furan derivatives to form 4a,7a‐dihydro‐4H‐furo[2,3‐e][1,2]oxazines, which underwent DBU‐promoted rearrangements to 6H‐1,2 ...
Ana L. Cardoso   +2 more
wiley   +1 more source

Fused 1,5-benzothiazepines from o-aminothiophenol and its derivatives as versatile synthons

open access: yesActa Chimica Slovenica, 2014
This review describes the reactions of o-aminothiophenol and its derivatives as building blocks for the synthesis of polyfunctionalised 1,5-benzothiazipines with pharmacological interest.
Batchu Chandra Sekhar
doaj  

Kinetic and Thermodynamic Approaches for the Efficient Formation of Mechanical Bonds [PDF]

open access: yes, 2008
Among the growing collection of molecular systems under consideration for nanoscale device applications, mechanically interlocked compounds derived from electrochemically switchable bistable [2]rotaxanes and [2]catenanes show great promise. These systems
Aprahamian, Ivan   +7 more
core   +1 more source

Synthesis of 2- and 3-indolylpyrroles via 1,3-dipolar cycloadditions of munchnones and nitroalkenes

open access: yes, 2010
– A series of 2-and 3-indolylpyrroles were generated via 1,3-dipolar cycloadditions between (2-nitrovinyl)indoles and symmetrical and unsymmetrical 1,3-oxazolium-5-olates (münchnones)
J. Lopchuk, G. Gribble
semanticscholar   +1 more source

Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis

open access: yesChemistry – A European Journal, Volume 32, Issue 9, 2 March 2026.
Mechanochemistry offers a sustainable, solvent‐free alternative to traditional synthesis, often enhanced by additives in a process known as additive‐assisted grinding. This review discusses how various additives, including liquids, ionic solids, and advanced materials like ionic liquids and piezoelectric compounds, improve reaction efficiency ...
Johanna Breinsperger   +3 more
wiley   +1 more source

Recent Progress on Giant Molecules: Synthesis, Assembly, and Applications

open access: yesChemistry–Methods, Volume 6, Issue 3, March 2026.
Giant molecules are molecules constructed by molecular nanoparticles with precise, rigid structure, have similar structures with small molecules and a large size as macromolecules. In this review, the constituent modules of giant molecules, as well as their synthesis, self‐assembly, applications in various fields and future developing prospect are ...
Haoyu Chen   +7 more
wiley   +1 more source

Binap-silver-catalyzed enantioselective multicomponent 1,3-dipolar cycloaddition of azomethines ylides derived from ethyl glyoxylate [PDF]

open access: yes, 2015
The enantioselective binap–silver catalyzed multicomponent 1,3-dipolar cycloaddition using ethyl glyoxylate, phenylalanine ethyl ester, and maleimides is described. The employment of basic silver carbonate allows the reaction to take place in the absence
Mancebo Aracil, Juan   +2 more
core   +2 more sources

Sulfur Ylides in Skeletal‐Editing—Ring Expansion Reactions

open access: yesHelvetica Chimica Acta, Volume 109, Issue 3, March 2026.
Sulfur ylides (S‐ylides) are emergent diazo surrogates that enable skeletal editing and ring expansion with safer handling and broad functional group tolerance. This perspective covers pioneer works and highlights recent advances in the field, while outlining key challenges and future directions that may redefine the role of S‐ylides in modern ...
Arsala Kamal   +3 more
wiley   +1 more source

Synthesis of 3,5-Disubstituted Isoxazoles and Isoxazolines in Deep Eutectic Solvents [PDF]

open access: yes, 2015
The synthesis of different 3,5-disubstituted isoxazoles and related isoxazolines using choline chloride:urea as deep eutectic solvent (DES) in a one-pot three step reaction has been accomplished successfully. The use of highly nucleophilic functionalized
Pérez Galera, Juana María   +1 more
core   +3 more sources

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