Results 161 to 170 of about 513,204 (270)

Monitoring Lead-Phosphorus Interactions Through <sup>31</sup>P-NMR Used as a Sensor in Phosphine Functionalized Silica Gel Adsorbent. [PDF]

open access: yesGels
Badillo-Camacho J   +4 more
europepmc   +1 more source

Upcycling Industrial Lignin Into Cationic Hydrogels With Potential for Sustainable Plant Protection

open access: yesChemSusChem, Volume 19, Issue 20, 28 October 2026.
Industrial lignin is upcycled into cationic lignin (CL) and embedded within chitosan–genipin (CH–GPN) hydrogels to form bioactive hydrogel networks with potential for antimicrobial plant protection. The CL‐embedded CH–GPN hydrogels retain porous, gel‐like properties and show enhanced in vitro inhibition of the plant pathogen Pseudomonas syringae.
Darindra Sandya Thanos   +7 more
wiley   +1 more source

Synergistic Silylium‐Ion and Palladium Catalysis Enables Migratory Alkene Silylation With Allylsilanes by Formal C–H/C–Si Metathesis

open access: yesAngewandte Chemie, Volume 138, Issue 44, 26 October 2026.
Merging silylium‐ion and palladium catalysis provides a mechanistically distinct route to allylsilanes by formal C–H/Si–H metathesis. Using allylsilanes as silicon proelectrophiles, various allylarenes undergo migrative silylation, selectively yielding (E)‐allylsilanes.
Longhui Duan   +5 more
wiley   +2 more sources

Quantitative Analysis of the Human Semen Phosphorometabolome by 31P-NMR. [PDF]

open access: yesInt J Mol Sci
Serrano R   +6 more
europepmc   +1 more source

New Insights into Poly(Dichlorophosphazene) Synthesis via Me3Si─N═PCl3 Polymerization: An Experimental and Theoretical Study

open access: yesChemistry – A European Journal, Volume 32, Issue 40, 27 October 2026.
Poly(dichlorophosphazene) synthesis via Me3Si─N═PCl3 polymerization was reinvestigated using quantum chemical calculations and experiments. A cationic initiator (Ph3PCl2) enables ambient‐temperature polymerization through chloride‐catalyzed cationic pathways involving dissociation, nucleophilic chloride attack, and chain‐propagating species formation ...
Cornelius Knuth   +6 more
wiley   +1 more source

Luminescence Vapochromism of a Cu(I)/Na Phosphane Iodide Assembly Based on a Secondary‐Sphere Sodium Response

open access: yesAngewandte Chemie, Volume 138, Issue 44, 26 October 2026.
The luminescence of a heterometallic d‐s {Cu2I2Na2} phosphane‐phosphinate aggregate is regulated by an interplay of Na+–π/I– contacts and reversible coordination of oxygen‐containing organic molecules to Na ions. Structural variations caused by the incoming guest lead to a wide and selective variation of the emission color and illustrate a new approach
Henna Korhonen   +10 more
wiley   +2 more sources

Solid-state <sup>31</sup>P NMR reveals the biological organophosphorus compounds as the dominant phosphorus species in Saharan dust aerosols. [PDF]

open access: yesCommun Earth Environ
Violaki K   +6 more
europepmc   +1 more source

Bis(2‐Adamantyl)Magnesium: Synthesis, Structure, and Applications of a Versatile and Shelf‐Stable 2‐Adamantyl Anion Equivalent

open access: yesChemistry – A European Journal, Volume 32, Issue 40, 27 October 2026.
At last, the long‐sought bis(2‐adamantyl)magnesium reagent has been prepared in high yield as a stable tetrahydrofuran/dioxane adduct and fully characterized by x‐ray crystallography. This potent nucleophile outperforms the corresponding Grignard in transmetallation and carbonyl addition reactions, opening new avenues in adamantyl organometallic and ...
Matthew V. DaCosta   +3 more
wiley   +1 more source

Induction of Methuosis in Breast Cancer Stem Cells by a Cobalt(III) Complex Evokes Immunotherapeutic Response

open access: yesAngewandte Chemie, Volume 138, Issue 44, 26 October 2026.
Cancer stem cells (CSCs) drive metastasis, relapse and resist conventional apoptosis‐inducing chemotherapies. We report a cobalt(III)‐cyclam complex with pyrene and diflunisal moieties that reduces the viability of breast CSCs at low micromolar concentrations.
Jiaxin Fang   +7 more
wiley   +2 more sources

Isolable ArInH2: Double Hydroindation Agent

open access: yesChemistry – A European Journal, Volume 32, Issue 40, 27 October 2026.
Stable crystalline monomeric indium dihydride ArInH2 was isolated and completely characterized using effective support of the P,C,P‐pincer ligand (Ar = 2,6‐(tBu2PO)2C6H3). It serves as unparalleled hydroindation agent, thereby extending the family of known hydrometallation process relying on heavy p‐block metals.
Adam Hochmal   +5 more
wiley   +1 more source

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