Results 161 to 170 of about 513,204 (270)
Monitoring Lead-Phosphorus Interactions Through <sup>31</sup>P-NMR Used as a Sensor in Phosphine Functionalized Silica Gel Adsorbent. [PDF]
Badillo-Camacho J +4 more
europepmc +1 more source
Upcycling Industrial Lignin Into Cationic Hydrogels With Potential for Sustainable Plant Protection
Industrial lignin is upcycled into cationic lignin (CL) and embedded within chitosan–genipin (CH–GPN) hydrogels to form bioactive hydrogel networks with potential for antimicrobial plant protection. The CL‐embedded CH–GPN hydrogels retain porous, gel‐like properties and show enhanced in vitro inhibition of the plant pathogen Pseudomonas syringae.
Darindra Sandya Thanos +7 more
wiley +1 more source
Merging silylium‐ion and palladium catalysis provides a mechanistically distinct route to allylsilanes by formal C–H/Si–H metathesis. Using allylsilanes as silicon proelectrophiles, various allylarenes undergo migrative silylation, selectively yielding (E)‐allylsilanes.
Longhui Duan +5 more
wiley +2 more sources
Quantitative Analysis of the Human Semen Phosphorometabolome by 31P-NMR. [PDF]
Serrano R +6 more
europepmc +1 more source
Poly(dichlorophosphazene) synthesis via Me3Si─N═PCl3 polymerization was reinvestigated using quantum chemical calculations and experiments. A cationic initiator (Ph3PCl2) enables ambient‐temperature polymerization through chloride‐catalyzed cationic pathways involving dissociation, nucleophilic chloride attack, and chain‐propagating species formation ...
Cornelius Knuth +6 more
wiley +1 more source
The luminescence of a heterometallic d‐s {Cu2I2Na2} phosphane‐phosphinate aggregate is regulated by an interplay of Na+–π/I– contacts and reversible coordination of oxygen‐containing organic molecules to Na ions. Structural variations caused by the incoming guest lead to a wide and selective variation of the emission color and illustrate a new approach
Henna Korhonen +10 more
wiley +2 more sources
Solid-state <sup>31</sup>P NMR reveals the biological organophosphorus compounds as the dominant phosphorus species in Saharan dust aerosols. [PDF]
Violaki K +6 more
europepmc +1 more source
At last, the long‐sought bis(2‐adamantyl)magnesium reagent has been prepared in high yield as a stable tetrahydrofuran/dioxane adduct and fully characterized by x‐ray crystallography. This potent nucleophile outperforms the corresponding Grignard in transmetallation and carbonyl addition reactions, opening new avenues in adamantyl organometallic and ...
Matthew V. DaCosta +3 more
wiley +1 more source
Cancer stem cells (CSCs) drive metastasis, relapse and resist conventional apoptosis‐inducing chemotherapies. We report a cobalt(III)‐cyclam complex with pyrene and diflunisal moieties that reduces the viability of breast CSCs at low micromolar concentrations.
Jiaxin Fang +7 more
wiley +2 more sources
Isolable ArInH2: Double Hydroindation Agent
Stable crystalline monomeric indium dihydride ArInH2 was isolated and completely characterized using effective support of the P,C,P‐pincer ligand (Ar = 2,6‐(tBu2PO)2C6H3). It serves as unparalleled hydroindation agent, thereby extending the family of known hydrometallation process relying on heavy p‐block metals.
Adam Hochmal +5 more
wiley +1 more source

