Results 31 to 40 of about 9,299,574 (208)

Metal‐Free Active Template: A Straightforward Route to 4‐Aminopyridinium‐Based Rotaxane Molecular Shuttles

open access: yesAngewandte Chemie, EarlyView.
Leigh's metal‐free active template‐based SNAr of an amine on halogenopyridiniums, in the presence of a crown ether, successfully afforded 4‐aminopyridinium‐containing rotaxanes. Further molecular machinery was carried out by deprotonation‐then‐carbamoylation of the conjugated amino moiety.
Ivaylo Stoyanov   +2 more
wiley   +2 more sources

rac-2-Methyl-3,4,5,6-tetrahydro-2H-2,6-methano-1,3-benzoxazocin-4-one

open access: yesActa Crystallographica Section E, 2010
The title compound, C12H13NO2, represents a conformationally restricted 2-pyridone analogue of 1,4-dihydropyridine-type calcium antagonists and was selected for a crystal structure determination in order to explore some aspects of drug-receptor ...
Viktor Kettmann   +2 more
doaj   +1 more source

Enzymatic synthesis of vitamin B6 precursor [PDF]

open access: yesJournal of the Serbian Chemical Society, 2013
3-Cyano-4-ethoxymethyl-6-methyl-2-pyridone is an important precursor in the synthesis of vitamin B6, obtained in the addition reaction between 2-cyanoacetamide and 1-ethoxy-2,4-pentanedione catalyzed by lipase from Candida rugosa ...
Prlainović Nevena Ž.   +4 more
doaj   +1 more source

Novel Reaction Pathways for 2-Pyridone [4+4] Photoadducts

open access: yes, 2016
Transannular ring closure of a pyridone−furan [4+4] photoadduct has been evaluated in a model system. A combination of nitrogen substitution and an isopropyl group gave full control of the four new stereogenic centers.
Scott McN. Sieburth (1538176)   +3 more
core   +3 more sources

Synthesis, Structure, and Hydroboration Reactivity of Anionic Nickel(0) Complexes Supported by Bidentate NHC-Pyridone Ligands

open access: yes, 2022
A family of anionic, formally nickel(0) complexes supported by bidentate NHC–pyridone ligands is described. The unsymmetric chelating environment and capping [K(18-crown-6)]+ countercation allow isolation of single-component, monometallic complexes in ...
C. Rose, Kennedy   +4 more
core   +1 more source

Two New 4-Hydroxy-2-pyridone Alkaloids with Antimicrobial and Cytotoxic Activities from Arthrinium sp. GZWMJZ-606 Endophytic with Houttuynia cordata Thunb

open access: yesMolecules, 2023
Two new 4-hydroxy-2-pyridone alkaloids furanpydone A and B (1 and 2), along with two known compounds N-hydroxyapiosporamide (3) and apiosporamide (4) were isolated from the endophytic fungus Arthrinium sp.
Ying Yin   +7 more
doaj   +1 more source

Synthesis of Some New Enaminoketones, Analogous of Milrinone, 4,Pyrones and Related 4-Pyridones [PDF]

open access: yesIranian Journal of Chemistry & Chemical Engineering, 1996
Synthesis of 4-(N,N- dimethylamino)-3-aryl-3-butene-2-one, ethyl-5-aryl-4-oxo-4H-pyran-2-carboxylate, ethyl-5-aryl-4-pyridones-2-carboxylate and 5-aryl-3-cyano-5-methyl-2-pyridones (aryl=3-thienyl, 2-furyl) are described.
Aziz Shahrisa, Salar Hemmati
doaj  

Crystal structures of three hydrogen-bonded 1:2 compounds of chloranilic acid with 2-pyridone, 3-hydroxypyridine and 4-hyroxypyridine

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2017
The crystal structures of the 1:2 compounds of chloranilic acid (systematic name: 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone) with 2-pyridone, 3-hydroxypyridine and 4-hyroxypyridine, namely, bis(2-pyridone) chloranilic acid, 2C5H5NO·C6H2Cl2O4, (I), bis ...
Kazuma Gotoh, Hiroyuki Ishida
doaj   +1 more source

Ambident Reactivities of Pyridone Anions

open access: yes, 2016
The kinetics of the reactions of the ambident 2- and 4-pyridone anions with benzhydrylium ions (diarylcarbenium ions) and structurally related Michael acceptors have been studied in DMSO, CH3CN, and water.
Herbert Mayr (1353507)   +1 more
core   +2 more sources

Unusual coordination behavior by a hydroxypyridine/pyridone ligand: Synthesis and structure of [(2-bromo-4-hydroxypyridine)2(2-bromo-1(H)-4-pyridone)2copper(II)] perchlorate • 2(2-bromo-4-hydroxypyridine) • 2(2-bromo-1(H)-4-pyridone)

open access: yes, 2019
The synthesis and structure of [Cu(2-Br-4-HOpy)2(2-Br-4-pyone)2](ClO4)2 • 2(2-Br-4-HOpy) • 2(2-Br-4-pyone) is reported [2-Br-4-HOpy = 2-bromo-4-hydroxypyridine; 2-Br-4-pyone = 2-bromo-(1H)4-pyridone]. The compound forms as a co-crystal in the triclinic P-
Jeffrey C. Monroe (5673371)   +1 more
core   +1 more source

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