Results 41 to 50 of about 167 (134)
A mechanically interlocked polyrotaxane hydrogel integrates sliding macrocycles within a covalent network, yielding skin‑like softness, high stretchability, robust adhesion, and stable ionic conductivity. This multifunctional interface enables simultaneous high‑fidelity monitoring of human motion and epidermal electrophysiological signals (ECG/EMG ...
Hao‐Zheng Huang +9 more
wiley +1 more source
SnCl4 Promoted Efficient Cleavage of Acetal/Ketal Groups with the Assistance of Water in CH2Cl2
Acetalization and deacetalation are a pair of routine manipulations to protect and deprotect the 4- and 6-hydroxyl groups of glycosides in the synthesis of glycosyl building blocks.
Tao Luo +3 more
doaj +1 more source
The first microwave‐assistance‐free heterogeneous catalytic upcycling of polyoxymethylene (POM) into valuable cyclic acetals is achieved with a reusable proton‐exchanged montmorillonite (H‐Mont) catalyst. Combining interlayer accessibility with strong acidity, H‐Mont enables efficient, regenerable, and versatile transformations with potentially biomass‐
José F. Noboa +3 more
wiley +1 more source
Glycerol to Solketal for Fuel Additive: Recent Progress in Heterogeneous Catalysts
Biodiesel has been successfully commercialized in numerous countries. Glycerol, as a byproduct in biodiesel production plant, has been explored recently for fuel additive production.
Is Fatimah +5 more
doaj +1 more source
A gas‐phase electrolyzer with a Pt‐impregnated Nafion membrane anode was used for selectively oxidizing methanol to formaldehyde (FA) with low water content. However, maintaining the cell temperature at 100 °C for extended periods led to membrane dehydration and low water content in the effluent, causing most FA to react with methanol to form ...
Sebastian Lechler +5 more
wiley +1 more source
The presence of PET (polyethylene terephthalate) in the environment is a global problem due to soil and water microplastic contamination. There is a constant demand for new technologies that expand the possibilities of PET disposal or recycling while ...
Maciej Kapkowski +9 more
doaj +1 more source
Heteropolyacids@Silica Heterogeneous Catalysts to Produce Solketal from Glycerol Acetalization
The composites of heteropolyacids (H3PW12, H3PMo12) incorporated into amine-functionalized silica materials were used for the first time as heterogeneous catalysts in the valorization of glycerol (a major waste from the biodiesel industry) through ...
Catarina N. Dias +4 more
doaj +1 more source
Application of polyaluminium chloride (PAC) as a Heterogeneous catalyst for glycerol formal synthesis [PDF]
Acetalization of glycerol with formaldehyde is one approach to produce glycerol formal compounds that have the potential to be used as fuel additives and environmentally friendly solvents.
Julianto Tatang Shabur +2 more
doaj +1 more source
Phthalidyl esters, commonly used prodrug moieties, are mostly prepared as a racemate. Here, the authors report an N-heterocylcic carbene-catalysed enantioselective acetalization of carboxylic acids and dialdehydes to give phthalidyl esters in high yields
Yingguo Liu +10 more
doaj +1 more source
Mo‐Catalyzed Synthesis of N‐Polyheterocycles From Functionalized Nitroarenes and Aldehydes
Mo(VI)‐catalyzed one‐pot conversion of readily available functionalized nitroarenes and aldehydes yielded fused N‐polyheterocycles by sequential nitro reduction, imine formation, and cyclization. Using pinacol as a benign reductant, this sustainable tandem strategy suppresses side reactions and grants rapid access to diverse pharmacologically relevant ...
Raúl Martínez‐González +4 more
wiley +1 more source

