Results 71 to 80 of about 258,318 (261)
Iron(III)-catalyzed chlorination of activated arenes [PDF]
, 2017 A general and regioselective method for the chlorination of activated arenes has been developed. The transformation uses iron(III) triflimide as a powerful Lewis acid for the activation of N-chlorosuccinimide and the subsequent chlorination of a wide ...
Andrew Sutherland +8 more
core +1 more source
2-(4-Chlorophenyl)acetamide [PDF]
Acta Crystallographica Section E Structure Reports Online, 2011 In the title compound, C(8)H(8)ClNO, the acetamide group is twisted out the benzene plane with a dihedral angle of 83.08 (1)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming layers parallel to the ab plane.
Dong-Sheng Ma +3 more
openaire +3 more sources
Chemistry – A European Journal, EarlyView.The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve +4 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.A modular Rh‐catalyzed synthetic approach enabled the preparation of diverse reactive fragments from available substrates. The reactive fragments modified Aurora A kinase via several distinct modification reaction classes. In a complex biological environment, the constellation of modified proteins depended critically on the reactive fragment structure.
Julian Chesti +8 more
wiley +1 more source
2,2-Dichloro-N-(3,5-dimethylphenyl)acetamide
Acta Crystallographica Section E, 2008 The structure of the title compound, C10H11Cl2NO, resembles those of 2,2-dichloro-N-phenylacetamide, 2,2-dichloro-N-(2-methylphenyl)acetamide, 2,2-dichloro-N-(3-methylphenyl)acetamide, 2,2-dichloro-N-(4-methylphenyl)acetamide, N-(3,5-dimethylphenyl ...
B. Thimme Gowda +4 more
doaj +1 more source
N-(2,3-Dimethylphenyl)acetamide [PDF]
Acta Crystallographica Section E Structure Reports Online, 2009 The conformation of the N-H bond in the structure of the title compound, C(10)H(13)NO, is syn to both the 2- and 3-methyl substituents on the aromatic ring, and is anti to the C=O bond. N-H⋯O hydrogen bonds link the mol-ecules into supra-molecular chains.
Hartmut Fuess +3 more
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Chemistry – A European Journal, EarlyView.An iridium‐catalyzed linear‐selective sp3 C─H alkylation of N‐methylamides with alkenes is described. This method tolerates various N‐methylacetamide derivatives and has a broad alkene scope. Mechanistic studies were also conducted. Internal alkenes can also be used through in situ consecutive alkene isomerization.
Haluhi Takahashi, Takanori Shibata
wiley +1 more source
Acta Crystallographica Section E: Crystallographic CommunicationsTwo new [1-(phenylsulfonyl)-1H-indol-2-yl]methanamine derivatives, namely, N-(3-methoxyphenyl)-N-{[1-(phenylsulfonyl)-1H-indol-2-yl]methyl}acetamide, C24H22N2O4S, (I), and N-(2,5-dimethoxyphenyl)-N-{[1-(phenylsulfonyl)-1H-indol-2-yl]methyl ...
S. Madhan +3 more
doaj +1 more source
N-(3,4-Diethoxyphenyl)acetamide [PDF]
Acta Crystallographica Section E Structure Reports Online, 2009 In the title compound, C12H17NO3, the conformations of the N—H and C=O bonds areantito each other. In the crystal structure, N—H...O hydrogen-bond interactions help to establish the packing.
Pei-Hua Ma +4 more
openaire +3 more sources