N-(2-Nitrophenylcarbamothioyl)acetamide [PDF]
Dans le composé du titre, C(9)H(9)N(3)O(3)S, le cycle benzénique et l'unité N-carbamothio-ylacétamide sont orientés selon un angle dièdre de 54,82 (4) °. L'angle dièdre entre le cycle et son groupe nitro attaché est de 28,54 (12) °. Une liaison hydrogène N-H (O,O) bifurquée intramoléculaire génère deux cycles S(6).
Durre Shahwar +4 more
openaire +3 more sources
Hydrogen bond based noncovalent association in the semi-fluorous solvent perfluorobutyl-methyl ether: Host-host and host-guest association of the host 1-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluoro-decyl)-3-pyridin-2-yl-urea [PDF]
A fluorous pyridyl-urea, 1-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decyl)-3-pyridin-2-yl-urea, was prepared to act as a host and analyzed by 1H NMR inCD2Cl2 and perfluorobutyl-methyl ether (HFE7100).
McGowan, Candace
core +1 more source
Coordination chemistry of amide-functionalised tetraazamacrocycles: structural, relaxometric and cytotoxicity studies [PDF]
Three different tetraazamacrocyclic ligands containing four amide substituents that feature groups (namely allyl, styryl and propargyl groups) suitable for polymerisation have been synthesised.
Aime +54 more
core +1 more source
Microwave Accelerated Aza-Claisen Rearrangement
A study of microwave-induced and standard thermal Overman rearrangement of selected allylic trichloroacetimidates 1a-1f, 6-8 to the corresponding acetamides 2a-2f, 9-11 is reported.
Eva GajdoÅ¡ÃÂková +3 more
doaj +1 more source
N-(2-Methylphenylsulfonyl)acetamide [PDF]
In the mol-ecular structure of the title compound, C(9)H(11)NO(3)S, the N-H and C=O bonds are anti to each other, while the amide H atom is syn with respect to the ortho-methyl group in the benzene ring. The C-S-N-C torsion angle is -58.2 (2)°, indicating a twist in the mol-ecule.
K. Shakuntala +2 more
openaire +3 more sources
Synthesis of highly substituted diphenylacetamides and diphenylsulfonamides by the goldberg coupling reaction [PDF]
We report the synthesis and characterisation of multisubstituted diphenylacetamides, diphenylsulfonamides and diphenylamines (and some observations on cyclisation of the last).Fundação para a Ciência e a Tecnologia (FCT)ICCTI and CRUP (Portugal) and the ...
Campos, Ana M. F. Oliveira +3 more
core +1 more source
ABSTRACT The UV/chlorine process, a promising advanced oxidation process, demonstrates remarkable synergism and radical dynamics for the efficient degradation of Basic Blue 41 (BB41). This study investigates the effects of processing conditions, including solution temperature (25°C–45°C), pollutant dose (10–40 mg/L), chlorine concentration (100–1000 μM)
Mounia Tidjani +4 more
wiley +1 more source
First Synthesis of 3-Acetyl-2-aminothiophenes Using the Gewald Reaction
Novel 3-acetyl-2-aminothiophenes were prepared from cyanoacetone and1,4-dithianyl-2,5-diols using a modified Gewald reaction. The syntheses of thecorresponding acetamides, as well as that of 3-acetyl-2-amino-5-nitrothiophene – aninteresting building-
Wolfgang Holzer, Gernot A. Eller
doaj +1 more source
Polylimonene Improves the In Vivo Wound Healing Performance of Sodium Alginate‐Based Hydrogels
An oligomer derived from orange peel essential oil incorporated into an alginate hydrogel was shown to be biocompatible and to exhibit a high capacity for in vivo incisional wound healing, as confirmed by experimental assays and mathematical models fitted to the data describing wound area reduction as a function of the dressing‐tissue contact time ...
Roniérik Pioli Vieira +5 more
wiley +1 more source
Eschenmoser coupling reactions starting from primary thioamides. When do they work and when not?
Reactions of thiobenzamide or thioacetamide with 4-bromo-1,1-dimethyl-1,4-dihydroisoquinoline-3(2H)-one, 4-bromoisoquinoline-1,3(2H,4H)-dione and two α-bromo(phenyl)acetamides were examined under various conditions (base, solvent, thiophile, temperature)
Lukáš Marek +3 more
doaj +1 more source

