2,2-Dichloro-N-(2,3-dimethylphenyl)acetamide
The conformation of the N—H bond in the title compound, C10H11Cl2NO, is syn to both the 2- and 3-methyl substituents in the aromatic ring, similar to that of the 2-chloro and 3-chloro substituents in 2,2-dichloro-N-(2,3-dichlorophenyl)acetamide and
B. Thimme Gowda +4 more
doaj +1 more source
Cp*Co(III)-Catalyzed coupling of benzamides with α,β-unsaturated carbonyl compounds: Preparation of aliphatic ketones and azepinones [PDF]
A Cp*Co(III)-catalyzed C-H functionalization of benzamide substrates with α,β-unsaturated ketones has been optimized, providing a facile route towards aliphatic ketone products.
Ackermann +43 more
core +1 more source
Synthesis, Characterization, and Antibacterial Activity Evaluation of Some New Benzoxazepindiones Obtained from Diphenylacrylimidamides [PDF]
This study reports the synthesis of new 1,3-oxazepine derivatives (S21-S30) by reacting hydrazones (Schiff bases) (S11-S20) with phthalic anhydride in dry benzene as the solvent.
Jawdat Hilmi Abdulwahid +2 more
doaj +1 more source
Electrocatalytic C─N Coupling in Aqueous Solutions for High‐Value Product Synthesis
Electrocatalytic C–N coupling offers a sustainable route to synthesize crucial organic nitrogen compounds from abundant feedstocks under mild conditions. This review examines recent progress in overcoming key challenges, like slow kinetics and competing reactions through advanced catalysts and novel mechanisms, paving the way for transforming chemical ...
Yunpeng Zuo +3 more
wiley +1 more source
Pd(II)-Catalyzed C-H Acylation of (Hetero)arenes. Recent Advances [PDF]
Di(hetero)aryl ketones are important motifs present in natural products, pharmaceuticals or agrochemicals. In recent years, Pd(II)-catalyzed acylation of (hetero)arenes in the presence of an oxidant has emerged as a catalytic alternative to classical ...
Lete Expósito, María Esther +2 more
core +1 more source
Synthesis of an Enzyme‐Triggered Chitosan‐Based Drug Delivery System for Peri‐Implantitis Prevention
ABSTRACT Dental implants have become a leading solution for tooth loss, yet bacterial infections remain a major complication. Antibacterial implant coatings are an important approach to reduce or prevent bacterial infections at the implant. Given the oral cavity's complex microbiome and the importance of some commensal bacteria, it is crucial to ...
Nelly Senze Nnane +7 more
wiley +1 more source
Palladium-Catalyzed Decarboxylative Alkoxycarbonylation of Potassium Aryltrifluoroborates with Potassium Oxalate Monoesters [PDF]
Palladium-catalyzed decarboxylative alkoxycarbonylation of potassium aryltrifluoroborates with potassium oxalate monoesters in the presence of potassium persulfate was performed under mild conditions.
Fang, Ping +3 more
core +1 more source
Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview
The graphical abstract summarizes the review “Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview”, highlighting representative Pd(II)‐catalyzed methods for the β‐arylation of α‐amino acids. Key mechanistic features, substrate diversity, and synthetic relevance of these transformations are showcased. Abstract Metal‐catalyzed C─
Davide Illuminati +4 more
wiley +1 more source
Many studies have reported an elevated risk of specific cancers including lymphoid malignancies (LM) in farmers, particularly those exposed to pesticides. Acetanilides are among the most widely sold herbicides in France. This study evaluated the risk for
Shiméa M Agossou +8 more
doaj +1 more source
Investigating the Ligand‐Binding Properties of N‐arylbenzimidazoles as Novel Elastase Inhibitors
A series of novel N‐[(3,5‐dimethylphenyl)methyl]‐1H‐benzimidazole derivatives is designed, synthesized, and evaluated for inhibitory activity against elastase. Several compounds demonstrate an antielastase activity, including the N‐(2‐bromophenyl)‐2‐(6‐chloro‐1‐(3,5‐dimethylbenzyl)‐1H‐benzo[d]imidazol‐2‐ylthio)acetamide, showing the greatest potency ...
Giovanna Pitasi +6 more
wiley +1 more source

