Quantum Chemical Studies on the Prototropic and Acid/Base Equilibria for 2-Aminopyrrole in Vacuo—Role of CH Tautomers in the Design of Strong Brønsted Imino N-Bases [PDF]
In the quest of the pivotal origin of the very strong gas-phase proton basicity for some iminopyrrole derivatives, proposed in the literature on the basis of quantum chemical calculations, the full tautomeric and acid/base equilibria were investigated in
Ewa Daniela Raczyńska +2 more
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Acid Yellow 9 Azo Dye Gets the Blues: An Optical Spectroscopy and DFT Study of Unusual Photochemistry in Multilayer Films with PAH and Chitosan [PDF]
Multilayer and free-standing films self-assembled from water-soluble anionic azo dye acid yellow 9 (AY9) and both poly(allylamine hydrochloride) (PAH) and chitosan (CS) cationic polyelectrolytes were fabricated from water solution using a layer-by-layer (
Mikhail Kim +3 more
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Physicochemical Characterization of Kynurenine Pathway Metabolites [PDF]
The kynurenine pathway is a significant metabolic route involved in the catabolism of tryptophan, producing various bioactive metabolites with crucial roles as antioxidants in immune regulation and neurobiology.
Luca Buzásy +7 more
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Teaching Acid-Base Equilibria by Using Log-log Diagrams
The purpose of this column consists in illustrating the utility of log-log diagrams for the graphical determination of the pH value of acid-base systems in dilute aqueous solution.
Antonio Togni
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A study of the behaviour of some substituted 1,2,4-triazoline-3-thiones in different media [PDF]
The acid-base behaviour of 4-phenyl-5-(4-R-benzyl)-1,2,4-triazoline-3-thione (1(R = OH); 2(R = OC2H5)) was studied in aqueous sulfuric acid and sodium hydroxide solutions.
MARIJA LAZAREVIC +2 more
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Chemical equilibria, including acid-base equilibria, play a significant role in the learning of general chemistry. Acid-base reactions as well as acidity and basicity concepts and their relationship to titrations are an important part of any general ...
Issa I. Salame +2 more
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Acid-base equilibria of 2,4-diiodo-6-methylphenylcarbamoylmethyl iminodiacetic acid and its labeling with technetium-99m [PDF]
The acid-base equilibria of a novel hepatobiliary imaging agent, 2,4-diiodo-6-methylphenylcarbamoylmethyl iminodiacetic acid (DIIODIDA) were studied.
S. VLADIMIROV +4 more
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Species-Specific, pH-Independent, Standard Redox Potential of Selenocysteine and Selenocysteamine
Microscopic redox equilibrium constants and standard redox potential values were determined to quantify selenolate-diselenide equilibria of biological significance.
Tamás Pálla +2 more
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Acid–base equilibria of the Zn(II) and Fe(III) complexes with condensation products of 2-acetylpyridine and the dihydrazide of oxalic and malonic acid [PDF]
Acid–base equilibria of Zn(II) and Fe(III) complexes with N',N'2-bis[(1E)-1-(2-pyridyl)ethylidene]ethanedihydrazide (ligand L1) and N',N'2-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide (ligand L2), i.e., [Fe(L1)Cl2(H2O)], [Fe(L2)Cl(H2O)]2+, [Zn(L1)(
DUŠAN SLADIĆ +6 more
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Protonation of maleic and fumaric acid in aqueous sulfuric acid solutions [PDF]
The protonations of maleic and fumaric acid in an acidic medium (aqueous solutions of sulfuric acid) were followed spectrophotometrically at room temperature. The acid-base equilibria were characterised qualitatively and quantitatively. The pKBH+
Jankovska Katica +2 more
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