Complexation of 1-Hydroxyethylidene-1,1-Diphosphonic Acid (HEDP) and Manganese(II) in Aqueous Solution [PDF]
Based on pH-potentiometric titration, it was found that the system Mn2+ – HEDP accumulates mono- and binuclear complexes of 1 : 1 and 2 : 2 composition, as well as mononuclear biscomplexes. Equilibrium and stability constants were obtained.
О.V. Bogatyrev +2 more
doaj
We propose herein a theoretical model describing the effect of fatal ethanol poisoning on the equilibria between cell membranes and the surrounding ions.
Aneta D. Petelska +3 more
doaj +1 more source
Structural insights into an engineered feruloyl esterase with improved MHET degrading properties
A feruloyl esterase was engineered to mimic key features of MHETase, enhancing the degradation of PET oligomers. Structural and computational analysis reveal how a point mutation stabilizes the active site and reshapes the binding cleft, expading substrate scope.
Panagiota Karampa +5 more
wiley +1 more source
Protolytic equilibria in homogeneous and heterogeneous systems of ketoconazole and its direct spectrophotometric determination in tablets [PDF]
The acid-base equilibria of a diprotic, slightly hydrosoluble base ketoconazole were studied in homogeneous and heterogeneous water systems. The determinations were performed at 25 ºC at a constant ionic strength of 0.1M(NaCl).
MIRJANA P. VOJIC +3 more
doaj +3 more sources
Acid-Base Equilibria in Aqueous Solutions [PDF]
Explore buffers, titrations, and the principal species in other acid–base solutions. You have a wide range of control over the species used to prepare the solutions. Calculations may be performed using simplifying approximations or with more rigorous charge and mass balance. Titrations are plotted with JavaScript.
Randall J. Wildman, William F. Coleman
openaire +1 more source
Proton Availability at the Air/Water Interface [PDF]
The acidity of the water surface sensed by a colliding gas is determined in experiments in which the protonation of gaseous trimethylamine (TMA) on aqueous microjets is monitored by online electrospray mass spectrometry as a function of the pH of the ...
Colussi, A. J. +2 more
core +2 more sources
Gut microbiome and aging—A dynamic interplay of microbes, metabolites, and the immune system
Age‐dependent shifts in microbial communities engender shifts in microbial metabolite profiles. These in turn drive shifts in barrier surface permeability of the gut and brain and induce immune activation. When paired with preexisting age‐related chronic inflammation this increases the risk of neuroinflammation and neurodegenerative diseases.
Aaron Mehl, Eran Blacher
wiley +1 more source
This study reveals a unique active site enriched in methionine residues and demonstrates that these residues play a critical role by stabilizing carbocation intermediates through novel sulfur–cation interactions. Structure‐guided mutagenesis further revealed variants with significantly altered product profiles, enhancing pseudopterosin formation. These
Marion Ringel +13 more
wiley +1 more source
Absorber design in sour natural gas treatment plants: Impact of process variables on operation and economics = Absorberentwurf für Anlagen zur Behandlung von sauren Erdgasen: Einfluss Prozessparameter auf Betriebsführung und Prozesswirtschaftlichkeit [PDF]
Two models of absorber have been developed which describe the absorption of H2S and CO2 from natural gases by aqueous di-isopropanolamine (DIPA) or methyl-di-ethanolamine (MDEA) solutions. In these models mass transfer, reaction and equilibrium processes
Blauwhoff, P.M.M. +3 more
core +2 more sources
Potential therapeutic targeting of BKCa channels in glioblastoma treatment
This review summarizes current insights into the role of BKCa and mitoBKCa channels in glioblastoma biology, their potential classification as oncochannels, and the emerging pharmacological strategies targeting these channels, emphasizing the translational challenges in developing BKCa‐directed therapies for glioblastoma treatment.
Kamila Maliszewska‐Olejniczak +4 more
wiley +1 more source

