Solving acid-base equilibria: Some concerns [PDF]
The simplest way to solve the problem of pH calculation related to c mol/L solutions of certain weak acids and salts.
openaire +1 more source
Concentration dependent tautomerism in green [Cu(HL1)(L2)] and brown [Cu(L1)(HL2)] with H2L1 = (E)-N’-(2-hydroxy-3-methoxybenzylidene)- benzoylhydrazone and HL2 = pyridine-4-carboxylic (isonicotinic) acid [PDF]
The in situ formed hydrazone Schiff base ligand (E)-N’-(2-hydroxy-3-methoxybenzylidene)-benzoylhydrazone (H2L1) reacts with copper(II) acetate in ethanol in the presence of pyridine-4-carboxylic acid (isonicotinic acid, HL2) to green-[Cu(HL1)(L2)]・H2O ...
Ghorbanloo, Massomeh +5 more
core +1 more source
Enzymatic degradation of biopolymers in amorphous and molten states: mechanisms and applications
This review explains how polymer morphology and thermal state shape enzymatic degradation pathways, comparing amorphous and molten biopolymer structures. By integrating structure–reactivity principles with insights from thermodynamics and enzyme engineering, it highlights mechanisms that enable efficient polymer breakdown.
Anđela Pustak, Aleksandra Maršavelski
wiley +1 more source
Influence of Temperature, Hypercapnia, and Development on the Relative Expression of Different Hemocyanin Isoforms in the Common Cuttlefish Sepia officinalis [PDF]
The cuttlefish Sepia officinalis expresses several hemocyanin isoforms with potentially different pH optima, indicating their reliance on efficient pH regulation in the blood.
Gutowska, Magdalena A. +7 more
core +1 more source
Mouse pre‐implantation development involves a transition from totipotency to pluripotency. Integrating transcriptomics, epigenetic profiling, low‐input proteomics and functional assays, we show that eight‐cell embryos retain residual totipotency features, whereas cytoskeletal remodeling regulated by the ubiquitin‐proteasome system drives progression ...
Wanqiong Li +8 more
wiley +1 more source
STUDY OF ELECTROCHEMICAL BEHAVIOR OF VI-B GROUP METAL OXIDES IN TUNGSTATE MELT
Thermodynamic assessment of the probability of interaction of metal oxides of group VI-B with tungstate melts, the results of the study of the acid-base properties of tungstate melt by potentiometric method.
Victor MALYSHEV +3 more
doaj +1 more source
A regulatory axis involving APE1, AUF1, and miR‐221 is proposed. Pri‐miR‐221 is processed by DROSHA and DICER to generate mature miR‐221, which targets p27Kip1 mRNA. APE1 and AUF1 compete for pre‐miR‐221 binding. Reduced APE1/AUF1 levels impair miR‐221 biogenesis, decrease p27Kip1 mRNA degradation, and promote cell cycle progression, chemoresistance ...
Matilde Clarissa Malfatti +3 more
wiley +1 more source
Potentiometric investigation of acid-base equilibria of two newv pyrimidine derivatives in various methanol–water media [PDF]
The acid-base properties of 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one (L1) and 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-thione (L2) were investigated potentiometrically at an ionic strength of 0.10M(LiCl) in 19.8, 33.6 and 55.9 % (v/v) methanolâ ...
HASAN KILIÇ, BİROL ER
doaj
The interaction of solutes with β-cyclodextrin leads to apparent changes in their chemical properties, such as shifts in their absorption spectra and acid-base equilibrium.
Amir H. M. Sarrafi +2 more
doaj +1 more source
Dynamical effects induced by long range activation in a nonequilibrium reaction-diffusion system
We both show experimentally and numerically that the time scales separation introduced by long range activation can induce oscillations and excitability in nonequilibrium reaction-diffusion systems that would otherwise only exhibit bistability.
A.R. Gourlay +30 more
core +1 more source

