Emergent Spin‐Glass Behavior in an Iron(II)‐Based Metal–Organic Framework Glass
A one‐pot, solvent‐free synthesis yields an Fe2+‐based metal‐organic framework (MOF) glass featuring a continuous random network structure. The material exhibits spin‐glass freezing at 14 K, driven by topological‐disorder and short‐range magnetic frustration, showcasing the potential of MOF glasses as a plattform for cooperative magnetic phenomena in ...
Chinmoy Das +8 more
wiley +1 more source
Unraveling Lewis base substitution in <i>ansa</i>-type frustrated Lewis pairs: how N → P replacement redefines adduct stability and H<sub>2</sub> activation. [PDF]
Barrales-Martínez C +3 more
europepmc +1 more source
Electrochemical Formation of BiVO4/BiPO4 Photoanodes for Enhanced Selectivity toward H2O2 Generation
In acidic KPi, V dissolves from the BiVO4 lattice, while adsorbed phosphate reacts with the electrode under an external bias, forming a BiPO4 surface layer. This BiPO4 layer exhibits stronger bicarbonate adsorption, redirecting the water oxidation pathway toward two‐electron H2O2 production.
Kaijian Zhu +12 more
wiley +1 more source
Fibrous Mesoporous Silica KCC-1 Functionalized with 3,5-Di-tert-butylsalicylaldehyde as an Efficient Dispersive Solid-Phase Extraction Sorbent for Pb(II) and Co(II) from Water. [PDF]
Alharbi SK +7 more
europepmc +1 more source
Experimental Studies on the Relation between Adrenal Cortex and Acid-Base Equilibrium
Yoshihiro Matsumoto +6 more
openalex +2 more sources
Precursor Mineral Phases of Forming Mollusk Shell Nacre: A Study of Hydrated Samples
Mineral, organic phase, and water are the essential components in mollusk shell nacre formation. Their interplay is not well understood, because the hydrated material is difficult to observe at high resolution, under close to native conditions. Forming nacre is studied using environmental and cryo‐electron microscopy and hydrated ACC phases, together ...
Anna Kozell +4 more
wiley +1 more source
Bacterial gene 5' ends have unusual mutation rates that can mislead tests of selection. [PDF]
Radrizzani S +3 more
europepmc +1 more source
The acid‐base equilibrium in the cerebro‐spinal fluid
T. R. Parsons, Cresswell Shearer
openalex +2 more sources
Unusual Swelling Behavior of Hydrogels Modified with Spiropyran as Appendage or Crosslinker
Not so innocent after all—spiropyran crosslinkers in methylenebisacrylamide‐crosslinked poly(acrylamide‐co‐acrylic acid) hydrogels increase crosslinking density, but also, counterintuitively, increase swelling. Charge complexation, cooperative chemo‐mechanical effects, and aggregation may explain these observations.
Michael M. Lerch +7 more
wiley +1 more source

