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Dissociation constants of some organic acids
Talanta, 1984Dissociation constants of di(nonylphenyl)dithiophosphoric acid, di(nonylphenyl)phosphoric acid and 9-phenyltetracosansulphuric acid, determined by two methods, are reported.
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Dissociation constants of hydropseudohalic acids
Journal of Inorganic and Nuclear Chemistry, 1966Abstract By means of potentiometric titration with hydrochloric acid of solutions of pseudohalide salts at several ionic strengths and temperatures, p Q a and K a o values have been obtained for HCN, HN 3 , HOCN and HSCN. From pH studies HSeCN is shown to be a very stong acid.
J.H. Boughton, R.N. Keller
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Thermodynamic acid dissociation constants of aromatic thiols
Journal of the Chemical Society, Perkin Transactions 2, 1973The thermodynamic acid dissociation constants of thiophenol and a series of meta- and para-substituted thiophenols have been measured in water at 25°C by the e.m.f.–spectrophotometric method. The results and the significance of the linear free energy relationship for thiophenols are discussed and compared with the limited data available in the ...
DE MARIA, Paolo, Fini A., Hall F. M.
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Temperature Dependence of the Acid Dissociation Constants of Chloroquine
Journal of Pharmaceutical Sciences, 1987The pKa values of the conjugate acids of the antimalarial drug chloroquine were determined at various temperatures using fluorescence spectrophotometry and nonlinear regression in the data analysis. Both pKa values decreased by approximately one unit with increasing temperature over the range 0-37 degrees C with enthalpy changes of 46 and 49 kJ X mol-1.
V, Ferrari, D J, Cutler
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Determination of acid dissociation constants by capillary electrophoresis
Journal of Chromatography A, 2004Capillary electrophoresis affords a simple, automated approach for the measurement of pKa values in the range 2-11 at a throughput of less than 1 h per sample per instrument. Agreement with literature values is usually within 0.20 log units with a precision better than 0.07 log units.
Salwa K, Poole +4 more
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Theoretical calculations of acid-dissociation constants of proteins
Biochemistry and Cell Biology, 1998The purpose of this review is to introduce several computational procedures for the determination of acid-dissociation constants (pKa) of titratable groups in proteins. Several concepts, such as continuum electrostatics and the exact meaning of intrinsic and apparent pKas, will be explained in some detail.
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The dissociation constants of acids
Journal of the Society of Chemical Industry, 1933openaire +2 more sources
The acidic dissociation constants of mandelic acid
Die Naturwissenschaften, 1961B. Csisz�r, M. Halmos, M. T. Beck
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