Results 11 to 20 of about 115,096 (255)

Acid dissociation constants of glycopeptides [PDF]

open access: yesBiochemical Journal, 1977
Glycopeptides containing mainly four amino acid residues in the sequence Asn-Leu-Thr-Ser, with small amounts of additional amino acid residues, were isolated from enzymic hydrolysates of hen's-egg albumin. Heterogeneity of the carbohydrate moiety was confirmed. Acid-base titrations showed that the alpha-amino group has a pKa value of 6.43 at 25 degrees
B M, Austen, R D, Marshall
openaire   +2 more sources

Protolytic equilibria in homogeneous and heterogeneous systems of ketoconazole and its direct spectrophotometric determination in tablets [PDF]

open access: yesJournal of the Serbian Chemical Society, 2005
The acid-base equilibria of a diprotic, slightly hydrosoluble base ketoconazole were studied in homogeneous and heterogeneous water systems. The determinations were performed at 25 ºC at a constant ionic strength of 0.1M(NaCl).
MIRJANA P. VOJIC   +3 more
doaj   +3 more sources

Development of Dynamic Model for Real-Time Monitoring of Ripening Changes of Kimchi during Distribution

open access: yesFoods, 2020
This study describes the development of a method for predicting the ripening of Kimchi according to temperature to provide information on how the ripening of Kimchi changes during distribution.
Ji-Young Kim   +4 more
doaj   +1 more source

Influence of pH and sequence in peptide aggregation via molecular simulation [PDF]

open access: yes, 2015
We employ a recently developed coarse-grained model for peptides and proteins where the effect of pH is automatically included. We explore the effect of pH in the aggregation process of the amyloidogenic peptide KTVIIE and two related sequences, using ...
Enciso, Marta   +2 more
core   +4 more sources

The Dissociation Constants of Tetrahydrofolic Acid

open access: yesJournal of Biological Chemistry, 1966
Six dissociable groups exist in tetrahydrofolic acid in the range H0 -3.0 to pH 14. The assignments in tetrahydrofolic acid by titrimetric and spectrophotometric comparisons with model compounds, p-aminobenzoylglutamic acid and 2-amino-6,7-dimethyl-5,6,7,8-tetrahydro-4-pteridinone, are as follows: acidic ionization of amide, pK' 10.5; N5, pK' 4.82; γ ...
R G, Kallen, W P, Jencks
openaire   +2 more sources

An Experimental Validated Computational Method for pKa Determination of Substituted 1,2-Dihydroxybenzenes

open access: yesFrontiers in Chemistry, 2018
1,2-dihydroxybenzenes (DHBs) are organic compounds which are widely studied as they are applied to advanced oxidation processes (AOPs). These compounds are also related to the development of oxidative stress, wood biodegradation, and neuronal disease in ...
Romina Romero   +5 more
doaj   +1 more source

pH-Mediated Regulation of Polymer Transport Through SiN Pores [PDF]

open access: yes, 2018
We characterize the pH controlled polymer capture and transport thorough silicon nitride (SiN) pores subject to protonation. A charge regulation model able to reproduce the experimental zeta potential of SiN pores is coupled with electrohydrodynamic ...
Ala-Nissila, Tapio, Buyukdagli, Sahin
core   +2 more sources

Binary nucleation in acid–water systems. I. Methanesulfonic acid–water [PDF]

open access: yes, 1991
Experimental measurements of binary nucleation between methanesulfonic acid and water vapor were carried out for relative acidities (Ra), 0 ...
Flagan, R. C.   +3 more
core   +1 more source

Acidity constants and redox potentials of uranyl ions in hydrothermal solutions [PDF]

open access: yes, 2016
Acknowledgements We thank Matthias Krack for supplying us with the pseudopotential and basis sets for U. We acknowledge the National Science Foundation of China (No.
Cheng, Jun   +4 more
core   +1 more source

The dissociation constant and acid hydrolysis rate of hydroxysulfamic acid [PDF]

open access: yesCanadian Journal of Chemistry, 1989
The acid dissociation constant and hydrolysis rate of hydroxysulfamic acid (HSA) in acid aqueous solutions have been studied. The acid dissociation constant was determined to be K = 1.5 ± 0.5 M at 298 K. The hydrolysis rate, R, was found to be R = k[H+][HSA], where k = 6.2 × 1012 exp (−26 300/RT) M−1 s−1 at (μ = 1.0 M and [HSA] is the concentration of
Littlejohn, D.   +2 more
openaire   +2 more sources

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