Protonated decafluorobenzophenone and the decafluorobenzophenone–arsenic pentafluoride adduct
Protonated decafluorobenzophenone (perfluorobenzophenone) and its corresponding AsF5 adduct were synthesized by reaction of the ketone with AsF5 using anhydrous HF and liquid SO2, respectively, as solvents, and their crystal structures were determined.The reaction of decafluorobenzophenone [perfluorobenzophenone, (C6F5)2CO] with AsF5 in anhydrous HF ...
Erik Uran, Matic Lozinšek
wiley +1 more source
Abstract As an ecological unit, the rhizosphere microbiome preserves an enormous and largely unexplored diversity of microbes that play essential roles in plant health and soil functions. Omics technologies encompassing high‐throughput approaches such as metagenomics, metatranscriptomics, and metaproteomics provide helpful tools to unravel the ...
Chinenyenwa Fortune Chukwuneme +1 more
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This study presents a phosgene‐ and isocyanate‐free route to terpene‐based polyurethanes using (R)‐limonene as a bio‐based feedstock. Through ring‐opening polymerization (ROP), limonene carbamate (LU) is converted into polyurethane (PLU) with high efficiency.
Jonas Futter +4 more
wiley +1 more source
Advances in Ligand‐Driven Pd‐Catalyzed C─H Functionalizations: Recent Insights and Updates
The most significant advances in ligand‐driven Pd‐catalyzed organic synthesis over the past two years are presented. Processes involving C─H activation of substrates, avoiding their prefunctionalization are illustrated. Both the activity and selectivity of the catalyst depend on the design of the ligands (pyridones, pyridines, amino acids, phosphines ...
Jesús Moradell +3 more
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Bacterial Diversity in Deep‐Sea Sediments of the North Atlantic Ocean and Their Biosynthesis of Secondary Metabolites [PDF]
In this study, we isolated culturable bacteria associated with oceanic sediments and studied their production of secondary metabolites using metabolomics and genetic screening. Bacteria were cultivated from depths as great as 2000 m below sea level, with the majority of culturable taxa from all sampling sites belonging to the Pseudomonadota phylum. Our
Marchese P +8 more
europepmc +2 more sources
Stereocontrolled synthesis of 3-hydroxy-2-piperidinone carboxamides by catalytic ring-opening aminolysis of bridged <i>δ</i>-lactam-γ-lactones. [PDF]
Beng TK +4 more
europepmc +1 more source
Identification of γ-butyrolactone signalling molecules in diverse actinomycetes using resin-assisted isolation and chemoenzymatic synthesis. [PDF]
Kudo Y, Konoki K, Yotsu-Yamashita M.
europepmc +1 more source
Engineering N-acyl-homoserine lactone-based quorum-sensing circuit for dynamic regulatory control in Saccharomyces cerevisiae. [PDF]
van Aalst ACA +7 more
europepmc +1 more source
Quorum-quenching halotolerant bacteria as biocontrol agents against potato phytopathogens. [PDF]
Sánchez P +4 more
europepmc +1 more source
Quorum sensing in the <i>Burkholderia cepacia</i> complex: biosynthesis, functions, and signaling pathways. [PDF]
Kong X +5 more
europepmc +1 more source

