Results 1 to 10 of about 12,697 (123)

Synthesis and Properties of Novel Reactive Dyes Comprising Acyl Fluoride Group on Cotton Fabrics [PDF]

Molecules, 2022
Novel reactive dyes with mono- and bi-acyl fluoride reactive groups have been designed and synthesized, which are obtained by using 2-amino-8-naphthol-6-sulfonic acid or 1-amino-8-naphthol-3,6-disulfonicacid as the coupling component and 4-aminobenzoyl ...
Guolin Tong, Penghui Li
exaly   +4 more sources

Selective O-Acylation of Enol Silyl Ethers with Acyl Fluorides Catalyzed by Fluoride Ions Derived from Potassium Fluoride and 18-Crown-6

ChemistryOpen
The fluoride ion‐catalyzed selective O‐acylation of enol silyl ethers with acyl fluorides using KF and 18‐Crown‐6 is described herein. This catalytic system facilitated the practical and facile reaction of a variety of enol silyl ethers derived from ...
Norio Sakai, Yohei Ogiwara, Kento Ishida
exaly   +4 more sources

Direct Fluoroformylation of the C3‐Position of Indoles with 2,4‐Dinitro(trifluoromethoxy)benzene as Fluorocarbonyl Source [PDF]

ChemistryOpen
We herein report the direct fluoroformylation of indoles and other heteroaromatic cycles. Acyl fluorides are very useful moieties in coupling reactions with or without metal.
Lilian Wisson, Gilles Hanquet, Fabien Toulgoat, Thierry Billard, Frédéric R. Leroux, Armen Panossian   +5 more
doaj   +2 more sources

Photoinduced Cleavage of Alkenyl Fluorides for Nucleophilic Acyl Substitution via In Situ Generated Acyl Fluorides. [PDF]

Org Lett
Acyl fluorides are valuable intermediates due to their stability and unique reactivity with amines, enabling selective acyl substitution. We report a mild, one-pot method to access amides, esters, and thioesters from alkenyl fluorides. Visible-light photoexcitation of 4-nitrophthalonitrile promotes cleavage of the alkenyl fluoride, forming acyl ...
Gogarnoiu ES, Griffin MS, Bansode AH, Paolillo JM, Bergen JM, Parasram M.   +5 more
europepmc   +3 more sources

Recycling fluoropolymers to acyl fluorides through shuttle catalysis. [PDF]

Chem Sci
The chemical recycling of a small array of fluoropolymers including poly(vinylidene difluoride) is reported.
Farley SES, Fogh AA, Crimmin MR.
europepmc   +2 more sources

Palladium-Catalyzed Decarbonylative Alkylation of Acyl Fluorides [PDF]

Organic Letters, 2020
Palladium-catalyzed decarbonylative alkylation reactions of acyl fluorides have been developed using alkylboranes having β-hydrogens. A wide range of functional groups were well tolerated, even at the high temperature required for decarbonylation. This protocol provides a diverse C(sp2)-C(sp3) bond formation via a highly efficient decarbonylative ...
Liyan Fu, Qiang Chen, Zhenhua Wang, Yasushi Nishihara   +3 more
openaire   +3 more sources

Functionalized porphyrins from meso-poly-halogeno-alkyl-dipyrromethanes: synthesis and characterization

Comptes Rendus. Chimie, 2021
Starting from pyrrole-carbinol derivatives, a set of three optimized experimental conditions was used to prepare six dipyrromethanes (DPM) bearing meso-poly-halogeno-alkyl chains. On the one hand, the condensation of $p$-anisaldehyde and the DPMs bearing
Julliard, Paul-Gabriel, Pascal, Simon, Siri, Olivier, Cortés-Arriagada, Diego, Sanhueza, Luis, Canard, Gabriel   +5 more
doaj   +1 more source

Synthesis of Bis(Carboranyl)amides 1,1′-μ-(CH₂NH(O)C(CH₂)_n-1,2-C₂B₁₀H₁₁)₂ (n = 0, 1) and Attempt of Synthesis of Gadolinium Bis(Dicarbollide)

Molecules, 2021
Bis(carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) were prepared by the reactions of the corresponding carboranyl acyl chlorides with ethylenediamine.
Yasunobu Asawa, Aleksandra V. Arsent’eva, Sergey A. Anufriev, Alexei A. Anisimov, Kyrill Yu. Suponitsky, Oleg A. Filippov, Hiroyuki Nakamura, Igor B. Sivaev   +7 more
doaj   +1 more source

Nickel-Catalyzed Decarbonylative Stannylation of Acyl Fluorides under Ligand-Free Conditions

Molecules, 2019
Nickel-catalyzed decarbonylative stannylation of acyl fluorides under ligand-free conditions was disclosed. A variety of aromatic acyl fluorides are capable of reacting with silylstannanes in the presence of cesium fluoride.
Xiu Wang, Zhenhua Wang, Li Liu, Yuya Asanuma, Yasushi Nishihara   +4 more
doaj   +1 more source

Application of Liquid-Phase Direct Fluorination: Novel Synthetic Methods for a Polyfluorinated Coating Material and a Monomer of a Perfluorinated Polymer Electrolyte Membrane

Applied Sciences, 2012
A new polyfluorinated anti-staining coating material CF3O(CF2CF2O)xCF2-CONHCH2CH2CH2Si(OCH3)3 has been developed by utilizing the PERFECT method, which employs a liquid-phase direct fluorination reaction with elemental fluorine as a key step.
Takashi Okazoe, Daisuke Shirakawa, Koichi Murata   +2 more
doaj   +1 more source