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ACS Sustainable Chemistry and EngineeringDiverse methods have been reported for the synthesis of acyl fluorides; however, an environmentally benign synthesis method for acyl fluorides remains underdeveloped.
Norio Shibata, Yuji Sumii
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Preparation of Acyl Fluorides with Hydrogen Fluoride‐Pyridine and 1,3‐Dicyclohexylcarbodiimide.
ChemInform, 2002AbstractFor Abstract see ChemInform Abstract in Full Text.
Chinpiao Chen +2 more
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Recent Advances in the Synthesis of Acyl Fluorides
Synthesis, 2020AbstractAcyl fluorides are valuable intermediates in organic synthesis. They are increasingly employed in peptide synthesis, in challenging esterification and amidation reactions or in transition-metal-catalyzed transformations. This review summarizes recent advances in their preparation.1 Introduction2 Nucleophilic Fluorination2.1 α-Fluoroamine ...
Jean-François Paquin +2 more
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Preparations and reactions of acylated and partially acylated glycosyl fluorides
Carbohydrate Research, 1993Abstract Partial acylation of glycosyl fluorides in the galacto (2 and 3) and gluco series (8–10) is readily achieved. Attempts to further alkylate these acyl derivatives failed. Treatment of 2 with Lewis acid, however, provided a facile route to the 1,4-anhydro derivative 5 . Lewis acid-mediated glycosylation of 2-acetamido-3,4,6-tri- O -
Joachim Thiem, Matthias Wiesner
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Acyl Fluorides in Late‐Transition‐Metal Catalysis
Angewandte Chemie International Edition, 2019AbstractIn this Review, we summarize the current state of the art in late‐transition‐metal‐catalyzed reactions of acyl fluorides, covering both their synthesis and further transformations. In organic reactions, the relationship between stability and reactivity of the starting substrates is usually characterized by a trade‐off.
Yohei Ogiwara, Norio Sakai
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Enantioselective acyl-transfer catalysis by fluoride ions
Chemical Communications, 2018The asymmetric nucleophilic catalysis by fluoride ions at a carbon-based electrophile has been demonstrated for the first time.
Ryan Craig +3 more
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Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates
Organic Letters, 2020We report the transition metal-free decarboxylative cross-coupling reactions of acyl fluorides with potassium perfluorobenzoates. Compared with traditional transition metal-catalyzed cross-couplings, this protocol presents an extremely environmentally benign pathway to afford unsymmetrical diaryl ketones.
Liyan Fu, Qiang Chen, Yasushi Nishihara
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C&EN Global Enterprise, 2017
Tetramethylammonium trifluoromethylthiolate, [N(CH3)4]SCF3, is a mouthful to say, but the inexpensive, bench-stable, and easy-to-use salt has been impressing chemists over the past few years for its versatility in adding SCF3 groups to molecules and as a fluorinating reagent.
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Tetramethylammonium trifluoromethylthiolate, [N(CH3)4]SCF3, is a mouthful to say, but the inexpensive, bench-stable, and easy-to-use salt has been impressing chemists over the past few years for its versatility in adding SCF3 groups to molecules and as a fluorinating reagent.
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Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides
Chemical Communications, 2019A transformation of acyl fluorides with silylboron via nickel/copper-cocatalysed carbon–fluorine bond cleavage and a sequential decarbonylation, which provides an efficient protocol to functionalize arylsilanes, has been disclosed.
Xiu Wang +2 more
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1.1 Sulfonyl Fluorides and Acyl Fluorides
AbstractSulfonyl fluorides have numerous applications in both synthetic organic chemistry as fluorinating agents and as precursors to sulfur(VI) moieties, and in chemical biology as covalent inhibitors and chemical probes. The utility of sulfonyl fluorides arises from the properties of the S—F bond, as the high bond strength and polarization imparts ...J. Lai, B. J. Thomson, G. M. Sammis
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