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Monoprotonated species of 2-aminomalonyl difluoride, [C3H4F2NO2][H2F3]. [PDF]

open access: yesActa Crystallogr C Struct Chem
Hollenwäger D   +3 more
europepmc   +1 more source

Benzoyl Fluorides as Fluorination Reagents: Reconstruction of Acyl Fluorides via Reversible Acyl C–F Bond Cleavage/Formation in Palladium Catalysis

open access: yesOrganometallics, 2020
This report describes the formation of value-added acyl fluorides by means of palladium-catalyzed acyl-exchange reactions between acyl fluorides and acid anhydrides.
Yohei Ogiwara   +2 more
openaire   +2 more sources

Recent Progress in Acyl Fluoride Synthesis

open access: yesSynthesis
Abstract Acyl fluorides have garnered considerable interest in synthetic organic chemistry owing to their distinctive balance of stability and reactivity. Recent efforts toward their preparation have focused on the development of novel reaction modalities and milder, safer, and more efficient fluorinating reagents.
Cuining Liu, Xinzhu Li, Li-Jie Cheng
openaire   +2 more sources
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Catalytic Synthesis of Carbonyl Compounds Using Acyl Fluorides, Carbamoyl Fluorides, and Fluoroformates: An Overview

Asian Journal of Organic Chemistry
AbstractAcyl fluorides, carbamoyl fluorides and fluoroformates have been employed as efficient reagents in a number of organic syntheses. Their application in catalytic transformations, however, began to be explored in the early 2000s. Recently, these reagents have increasingly gained attention owing to their unique reactivity in diverse catalytic ...
Kwangmin Shin, Yoonho Lee
exaly   +2 more sources

Halide-Accelerated Acyl Fluoride Formation Using Sulfuryl Fluoride

Organic Letters, 2020
Herein, we report a new one-pot sequential method for SO2F2-mediated nucleophilic acyl substitution reactions starting from carboxylic acids. A mechanistic study revealed that SO2F2-mediated acid activation proceeds via the anhydride, which is then converted to the corresponding acyl fluoride.
Paul J. Foth   +5 more
openaire   +2 more sources

Synthesis of acyl fluorides through deoxyfluorination of carboxylic acids

Organic & Biomolecular Chemistry, 2023
A direct deoxyfluorination of carboxylic acids by utilizing KF as fluoride source has been developed. Scale-up reaction could be carried out under the solvent-free conditions, which exhibited the practicability of this reaction in organic synthesis.
Mengjie Cen   +5 more
openaire   +2 more sources

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