Results 41 to 50 of about 125,219 (261)

Keggin-Type Heteropolyacids-Catalyzed One Pot Oxidation-Trimerization of Alcohols into 2,4,6-Trisubstituted-1,3,5-Trioxanes [PDF]

Iranian Journal of Chemistry & Chemical Engineering, 2009
The catalytic air oxidation-trimerization of alcohols was carried out with hetropolyacids. In the presence of hetropolyacid formation of cyclotrimers of alcohols and aldol condensation products was observed.
M. Majid Heravi, Sodeh Sadjadi, Rahim Hekmatshoar, Hossein Abdi Oskooie, Fatemeh Bamoharram   +4 more
doaj  

A Simple Iron-Catalyst for Alkenylation of Ketones Using Primary Alcohols

Molecules, 2020
Herein, we developed a simple iron-catalyzed system for the α-alkenylation of ketones using primary alcohols. Such acceptor-less dehydrogenative coupling (ADC) of alcohols resulted in the synthesis of a series of important α,β-unsaturated functionalized ...
Motahar Sk, Ashish Kumar, Jagadish Das, Debasis Banerjee   +3 more
doaj   +1 more source

KLK7 overexpression promotes an aggressive phenotype and facilitates peritoneal dissemination in colorectal cancer cells

FEBS Open Bio, EarlyView.
KLK7, a tissue kallikrein‐related peptidase, is elevated in advanced colorectal cancer and associated with shorter survival. High KLK7 levels in ascites correlate with peritoneal metastasis. In mice, KLK7 overexpression increases metastasis. In vitro, KLK7 enhances cancer cell proliferation, migration, adhesion, and spheroid formation, driving ...
Yosr Z. Haffani, Tobias Dreyer, Meriem Naim, Rea Lo Dico, Natalia A. Ignatenko, Viktor Magdolen, Dalila Darmoul   +6 more
wiley   +1 more source

Gas Phase Hydrogenation of Furaldehydes via Coupling with Alcohol Dehydrogenation over Ceria Supported Au-Cu

Molecules, 2018
We have investigated the synthesis and application of Au-Cu/CeO2 (Cu: Au = 2) in the continuous gas phase (P = 1 atm; T = 498 K) coupled hydrogenation of 5-hydroxymethyl-2-furaldehyde (HMF) with 2-butanol dehydrogenation.
Chiara Pischetola, Laura Collado, Mark A. Keane, Fernando Cárdenas-Lizana   +3 more
doaj   +1 more source

Differential regulation of ZFAS1 splice variants by endoplasmic reticulum stress in hepatocyte cell lines

FEBS Open Bio, EarlyView.
ZFAS1 is a lncRNA promoting cell proliferation and migration, exhibiting high expression in various cancers. It is conserved, widely expressed, and produces multiple splice variants with unclear roles. We identified several splice variants in hepatocyte models, and found that inhibiting or suppressing regulators of the unfolded protein response (PERK ...
Sébastien Soubeyrand, Paulina Lau, Ruth McPherson   +2 more
wiley   +1 more source

Exploring the Effects of Synergistic Combustion of Alcohols and Biodiesel on Combustion Performance and Emissions of Diesel Engines: A Review

Energies
Diesel engines are extensively employed in transportation, agriculture, and industry due to their high thermal efficiency and fuel economy. However, the combustion of conventional diesel fuel is accompanied by substantial emissions of pollutants ...
Fangyuan Zheng, Haeng Muk Cho
doaj   +1 more source

Alcohol‐induced altered glycans in human tracheal epithelial cells promote bacterial adhesion

FEBS Open Bio, EarlyView.
Alcohol induces altered glycans to promote bacteria adhesion. Heavy alcohol drinking is known to increase the risk of bacterial pneumonia. However, the link between alcohol levels and risk of infection remains underexplored. Recently, we found that alcohol induced α2‐6sialo mucin O‐glycans in human tracheobronchial epithelial cells, which mediated the ...
Pi‐Wan Cheng, Souvik Datta, Derrick R. Samuelson   +2 more
wiley   +1 more source

A gas-phase “top-down” chemical link between aldehydes and alcohols

Frontiers in Astronomy and Space Sciences
IntroductionAlcohols and aldehydes represent two key classes of interstellar complex organic molecules (COMs). This work seeks to better understand their possible chemical connections, with a focus on such molecules in the sources of the star-forming ...
Christopher N. Shingledecker, Germán Molpeceres, A. Mackenzie Flowers, Deaton Warren, Emma Stanley, Anthony Remijan   +5 more
doaj   +1 more source

A Green Approach for Allylations of Aldehydes and Ketones: Combining Allylborate, Mechanochemistry and Lanthanide Catalyst

Molecules, 2016
Secondary and tertiary alcohols synthesized via allylation of aldehydes and ketones are important compounds in bioactive natural products and industry, including pharmaceuticals.
Viviane P. de Souza, Cristiane K. Oliveira, Thiago M. de Souza, Paulo H. Menezes, Severino Alves, Ricardo L. Longo, Ivani Malvestiti   +6 more
doaj   +1 more source

C2α‐carbanion‐protonating glutamate discloses tradeoffs between substrate accommodation and reaction rate in actinobacterial 2‐hydroxyacyl‐CoA lyase

FEBS Open Bio, EarlyView.
Enzymes of the 2‐hydroxyacyl‐CoA lyase group catalyze the condensation of formyl‐CoA with aldehydes or ketones. Thus, by structural adaptation of active sites, practically any pharmaceutically and industrially important 2‐hydroxyacid could be biotechnologically synthesized. Combining crystal structure analysis, active site mutations and kinetic assays,
Michael Zahn, Barbara Seroka, Ryszard Lazny, Zenon Lotowski, Thore Rohwerder   +4 more
wiley   +1 more source