Results 71 to 80 of about 33,029 (246)

Aldehyde–Olefin Couplings by Photoinduced Reduction of Electron‐Deficient Olefins with Hantzsch Ester Anions

Angewandte Chemie, EarlyView.
Single‐electron transfer‐mediated reductive carbonyl–olefin couplings are valuable carbon–carbon bond forming reactions. However, limitations persist for couplings of aliphatic aldehydes with electron‐deficient olefins. Here, we report a simple, photocatalyst‐free protocol that overcomes these limitations by using a Hantzsch ester anion as a ...
Zhihang Li, Adam Noble
wiley   +2 more sources

Decoupling Intrinsic Molecular Efficacy From Platform Effects: An Interpretable Machine Learning Framework for Unbiased Perovskite Passivator Discovery

Advanced Science, EarlyView.
This study establishes an interpretable machine learning framework that disentangles the intrinsic molecular efficacy of passivators from experimental platform effects—enabling unbiased, high‐throughput discovery of effective perovskite surface modifiers.
Jing Zhang, Ziyuan Li, Shan Gao, Zhen Zhu, Jing Wang, Xiangmei Duan   +5 more
wiley   +1 more source

Rectal glands and tergal glands as sources of volatile pheromones in cucumber fruit fly, Zeugodacus Cucumis

Scientific Reports
Male tephritid fruit flies typically emit pheromones from rectal glands to attract mates. Consistent with this, virgin females of the cucumber fruit fly, Zeugodacus cucumis (French), were found to be attracted to volatiles emitted by crushed male rectal ...
Soo J Park, Jeanneth Pérez, Vivian Mendez, Phillip W Taylor   +3 more
doaj   +1 more source

Gold amides as anticancer drugs: synthesis and activity studies [PDF]

, 2013
Modular gold amide chemotherapeutics: Access to modern chemotherapeutics with robust and flexible synthetic routes that are amenable to extensive customisation is a key requirement in drug synthesis and discovery.
Amagai, Amruta Shrikhande, Bjornstedt, Chen, Chris Gallop, Cox, Davis, Eddy M. E. Viseux, Eva Hoffmann, Fricker, Gabbiani, Helen Yong, Hickey, Hill, Lemke, Lima, Mariusz Bobin, Mark Roe, Mezailles, Modica-Napolitano, Omata, Orvig, Ott, Patra, Poole, Rebecca Gates, Shuvashri Chaudhuri, Sonya Newcombe, Stallings-Mann, Thaqi, Wetzel, Yan, Yannick Pace, Zhang, Zhang   +34 more
core   +1 more source

Molecular Design and Interfacial Functions of Self‐Assembled Monolayers for Perovskite and Tandem Solar Cells

Advanced Energy Materials, EarlyView.
We identify two decisive levers for SAM interfaces: molecular design (carboxylic acid‐based, phosphonic acid, other anchoring chemistries, and polymeric SAMs) and mixing routes (co‐assembly, in situ assembly, pre‐ and post‐treatment). Coordinated tuning of headgroups and assembly pathways optimises energy alignment and film formation, suppresses ...
Jiaxu Zhang, Bochun Kang, Feng Yan
wiley   +1 more source

A facile synthesis of α,β-unsaturated imines via palladium-catalyzed dehydrogenation

Nature Communications
The dehydrogenation adjacent to an electron-withdrawing group provides an efficient access to α,β-unsaturated compounds that serving as versatile synthons in organic chemistry.
Chunyang Zhao, Rongwan Gao, Wenxuan Ma, Miao Li, Yifei Li, Qian Zhang, Wei Guan, Junkai Fu   +7 more
doaj   +1 more source

Computational Study of Mechanism and Thermodynamics of Ni/IPr-Catalyzed Amidation of Esters

Molecules, 2018
Nickel catalysis has shown remarkable potential in amide C–N bond activation and functionalization. Particularly for the transformation between ester and amide, nickel catalysis has realized both the forward (ester to amide) and reverse (amide to ...
Chong-Lei Ji, Pei-Pei Xie, Xin Hong
doaj   +1 more source

Glucosinolate and Isothiocyanate Profiles in Different Varieties of Raphanus sativus Seed via Multivariate Data Analysis

AgriFood: Journal of Agricultural Products for Food, EarlyView.
Through HPLC–MS/MS analysis and multivariate statistics, raphani semen (RS) varieties with high functional components were screened. The white raphani semen “Xuebawang” was identified as ideal for further study due to its high bioactive content: glucoraphenin (9010.27 mg/100 g), glucoraphanin (1027.76 mg/100 g), sulforaphane (66.14 mg/100 g), and ...
Yonghua Li, Dongmei Lin, Peng Wu, Rui Gao, Jingxiu Bi, Yuying Jiang, Tong Zhao, Xuexia Yuan, Jianhan Xu, Pingxiang Liu, Yutao Wang   +10 more
wiley   +1 more source

Amide-modified poly(butylene terepthalate): thermal stability [PDF]

, 1996
The thermal stability of a poly(ester amide) copolymer (PBTA) based on poly(butylene terephthalate) (PBT) and nylon-4,T with the diamide of butanediamine and dimethyl terephthalate (N,N′-bis(p-carbomethoxybenzoyl)butanediamine) and homopolymer PBT was ...
Bennekom, A.C.M. van, Gaymans, R.J., Willemsen, P.A.A.T.   +2 more
core   +2 more sources

Natural Aging of Biomaterials in Ambient and Physiological Environments

Advanced NanoBiomed Research, EarlyView.
Biomaterials used in biomedical applications can change their physical properties over time, even under ambient and physiological conditions. This review highlights key studies on the natural aging of materials ranging from soft hydrogels to metals and ceramics, emphasizing how time‐dependent changes influence function and performance.
Shuyu Zhang, Anne E. Staples
wiley   +1 more source