Results 81 to 90 of about 14,155 (281)

Cobalt‐Catalyzed Radical Ligand Transfer (RLT) Enables Remote‐Markovnikov Hydroamination of Alkenes

open access: yesAngewandte Chemie, EarlyView.
A cobalt‐catalyzed remote‐Markovnikov 1,3‐hydroamination of allyl carboxylates proceeds through MHAT, 1,2‐radical acyloxy migration (1,2‐RAM), and radical ligand transfer (RLT) from a Co‐N intermediate, providing protected amino alcohols. ABSTRACT Amino alcohols are prevalent in pharmaceuticals, agrochemicals, and functional materials, yet ...
Arman Khosravi   +7 more
wiley   +2 more sources

Computational Study of Mechanism and Thermodynamics of Ni/IPr-Catalyzed Amidation of Esters

open access: yesMolecules, 2018
Nickel catalysis has shown remarkable potential in amide C–N bond activation and functionalization. Particularly for the transformation between ester and amide, nickel catalysis has realized both the forward (ester to amide) and reverse (amide to ...
Chong-Lei Ji, Pei-Pei Xie, Xin Hong
doaj   +1 more source

Nickel-Catalyzed Electro-Reductive Cross-Coupling of Aliphatic Amides with Alkyl Halides as a Strategy for Dialkyl Ketone Synthesis: Scope and Mechanistic Investigations

open access: yes, 2022
The development and in-depth study of a novel catalytic method relying on the combination of nickel catalysis and electrochemistry for the cross-electrophile coupling of alkyl amides with alkyl halides is described.
Guillaume, Pilet   +6 more
core   +1 more source

Advances in BODIPY Derivatives for Antibacterial Phototherapy

open access: yesAngewandte Chemie, EarlyView.
This review systematically summarizes the design strategies and structure‐activity relationships of BODIPY‐based antibacterial phototherapy, covering molecular engineering of small‐molecule photosensitizers and nanoplatforms, bacterial targeting and carrier design, and discussing the challenges and future perspectives associated with clinical ...
Li Lv   +9 more
wiley   +2 more sources

A facile synthesis of α,β-unsaturated imines via palladium-catalyzed dehydrogenation

open access: yesNature Communications
The dehydrogenation adjacent to an electron-withdrawing group provides an efficient access to α,β-unsaturated compounds that serving as versatile synthons in organic chemistry.
Chunyang Zhao   +7 more
doaj   +1 more source

pH Sensitive Anticancer Prodrug: Amide of Kemp's Acid

open access: yes, 2009
Solid tumours are characterised by lower extracellular pH (as low as 5.8 pH) compared to normal healthy cellular pH (actively regulated at pH 7.3). This difference may be exploited with an acid-sensitive anti-tumour prodrug which releases a cytotoxin ...
Brooks, Robert Turongo
core  

Research of chemical and toxic properties of humic acids of low-moor woody-grassy type of a peat in Tomsk Region

open access: yesБюллетень сибирской медицины, 2009
In article results of research of a chemical structure of humic acids of low-moor woody-grassy type of peat of Tomsk Region are resulted by methods of the elemental analysis and infra-red spectroscopy.
M. V. Belousov   +4 more
doaj   +1 more source

The crystal structure of an aliphatic amidase from Geobacillus pallidus RAPc8

open access: yes, 2007
Includes bibliographical references (leaves 123-136).Amidases are a group of carbon-nitrogen hydrolysing enzymes that catalyze the conversion of amides to corresponding carboxylic acids and ammonia.
Kimani, Serah
core  

Isobutylhydroxyamides from Zanthoxylum bungeanum and Their Suppression of NO Production

open access: yesMolecules, 2016
Four new unsaturated aliphatic acid amides, named zanthoamides A–D (1–4), and eight known ones—tetrahydrobungeanool (5), ZP-amide A (6), ZP-amide B (7), ZP-amide C (8), ZP-amide D (9), ZP-amide E (10), bugeanumamide A (11), and (2E,7E,9E)-N-(2-hydroxy-2 ...
Yuan Wang   +6 more
doaj   +1 more source

Solid-state NMR Spectroscopic Analysis of Sweet Cherry Leaves under Different Cultivation Patterns

open access: yesHortScience, 2020
Solid-state 1H-NMR and 13C-NMR spectroscopy were used to investigate the chemical components of sweet cherry tree leaves under rain-shelter cultivation (RS) and open-field cultivation (CK).
Huimin Zhang   +4 more
doaj   +1 more source

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