Results 81 to 90 of about 13,085 (246)

Determination of protonation constants and structural correlations for some tertiary formamides and acetamides in sulfuric acid with UV spectroscopy

Macedonian Journal of Chemistry and Chemical Engineering, 2015
The protonation of ten aliphatic amides in sulfuric acid media was studied by UV spectroscopy. The pKBH+ values and solvation parameters were calculated using Yates and McClelland Method, Excess Acidity Method and Bunnett and Olsen Method.
Goran Stojković, Elizabeta Dimitrieska-Stojković, Emil Popovski   +2 more
doaj   +1 more source

About the Direction of Selective Alkylation and Cyanoethylation of Benzimidazoles, Benzothiazoles and Benzopyrimidines

Journal of Basic and Applied Research in Biomedicine, 2022
Selective alkylation and cyanoethylation of 2H(methyl) benzimidazoles (1, 2),  benzimidazolin-2-one (3) and -2-thione (4), benzothiazolin-2-thione (5) and 2-methyl-benzopyrimidin-4-one (6, 2-methylquinazolin-4-one) have been studied.
M Olimova, B Elmuradov
doaj   +2 more sources

Synthesis of 6- or 8-Carboxamido Derivatives of Imidazo[1,2-a]pyridines via a Heterogeneous Catalytic Aminocarbonylation Reaction

Molecules
Imidazo[1,2-a]pyridines and especially their amide derivatives exhibit a wide range of favourable pharmacological properties. In this work, Pd-catalysed carbonylation was used for the first time for the introduction of the carboxamide moiety into ...
Enikő Nagy, Attila Máriás, Margit Kovács, Rita Skoda-Földes   +3 more
doaj   +1 more source

Unified metal-free intermolecular Heck-type sulfonylation, cyanation, amination, amidation of alkenes by thianthrenation

Nature Communications
Direct and site-selective C-H functionalization of alkenes under environmentally benign conditions represents a useful and attractive yet challenging transformation to access value-added molecules.
Ming-Shang Liu, Hai-Wu Du, Huan Meng, Ying Xie, Wei Shu   +4 more
doaj   +1 more source

Novel 6- and 7-Substituted Coumarins with Inhibitory Action against Lipoxygenase and Tumor-Associated Carbonic Anhydrase IX

Molecules, 2018
A series of carboxamide derivatives of 6- and 7-substituted coumarins have been prepared by an original procedure starting from the corresponding 6- or 7-hydroxycoumarins which were alkylated with ethyl iodoacetate, and the obtained ester was converted ...
Aikaterini Peperidou, Silvia Bua, Murat Bozdag, Dimitra Hadjipavlou-Litina, Claudiu T. Supuran   +4 more
doaj   +1 more source

Photochemical Allylation of Aldehydes or Alkanes with Vinyl Cyclopropanes

ChemistryEurope
Vinyl cyclopropanes are useful linchpins for the synthesis of more complex scaffolds. In this work, we present an acylation or alkylation protocol of donor–acceptor vinyl cyclopropanes, employing tetra‐n‐butylammonium decatungstate as the photocatalyst ...
Naya A. Stini, Christoforos G. Kokotos
doaj   +1 more source

Condensation of Bromal Hydrate with Aliphatic Amides.

, 1933
Condensation of Bromal Hydrate with Aliphatic Amides.
openaire   +2 more sources

Unified Synthesis of Unconventional α‐Polyhalogenated Amines Through Hydroaminoalkylation

Angewandte Chemie International Edition, EarlyView.
A unified, redox‐neutral method that transforms alkenes and alkynes into α‐polyhalomethyl amines using stable hemiaminal reagents is reported. This approach enables access to CF3, CF2H, CF2Cl, and CFClH motifs, expanding halogenated amine space with broad substrate scope, functional group tolerance, and applicability to late‐stage modification of drug ...
Angela K. Hofmeister, Giulia Iannelli, Péter Angyal, Augustin Malandain, Daniel Kaiser, Boris Maryasin, Hanspeter Kählig, Matteo Barel, Gaia Novarino, Nuno Maulide   +9 more
wiley   +1 more source

Amides of Aliphatic Selena-carboxylic Acids. [PDF]

Acta Chemica Scandinavica, 1963
Arne Fredga, J. Bremer, J. W. Stewart, Mark Takahashi   +3 more
openaire   +1 more source

Peptide Thioester and Triazole Derivatives Through On‐Resin Dual‐Modification of Peptide Thiosulfonates

Angewandte Chemie International Edition, EarlyView.
An on‐resin dual‐modification strategy for peptides is presented, comprising S‐alkynylation of peptide thiosulfonates and regioselective iridium‐catalyzed azide–thioalkyne cycloaddition. This method reliably provides access to peptides with intricate non‐canonical modifications, being compatible with complex peptides, alkynes and azides.
Marius Werner, Agnes Bergmann, Chenxi Liu, Mira Behnam, Christian Klein, Franziska Thomas   +5 more
wiley   +1 more source