Results 41 to 50 of about 456 (163)

Homochiral Self‐Sorting During Macrocycle Formation and their Chiroptical Properties

ChemistryOpen
Several BINOL‐derived C2‐symmetric aldehydes were synthesized to investigate chiral self‐sorting phenomena during macrocycle formation in the presence of aliphatic and aromatic bisamines.
Diptiprava Sahoo, Dr. Soumen De
doaj   +1 more source

Turning Unpredictable Biomolecule Adsorption to Controlled Corona Formation: Focus on Carbon Nanomaterials

Advanced Materials, EarlyView.
Controlling the protein corona formation onto carbon nanomaterials (CNMs) enhances their functionalities as platforms for cancer theranostics. Here, we reviewed the effects of the intrinsic and acquired properties of CNMs on protein corona formation, the consequent biological and toxicological outcomes, and the strategies to reshape corona formation ...
Yajuan Zou, Yalei Hu, Jie Yu, Naoki Komatsu, Yuta Nishina, Alberto Bianco   +5 more
wiley   +1 more source

Merging Biocatalysis and Chemocatalysis in Flow: State‐of‐the‐Art and Future Directions for Sustainable Synthesis

Angewandte Chemie, EarlyView.
This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis, Matteo Damian, Francesco G. Mutti   +2 more
wiley   +2 more sources

Ammonia for post-healing of formamidinium-based Perovskite films

Nature Communications, 2022
Solvents used for perovskite film fabrication not only dissolve the precursors but also play a role in the crystallization process. Here, authors study the role of transamination reactions in the underlying degradation mechanism of formamidinium ...
Zhipeng Li, Xiao Wang, Zaiwei Wang, Zhipeng Shao, Lianzheng Hao, Yi Rao, Chen Chen, Dachang Liu, Qiangqiang Zhao, Xiuhong Sun, Caiyun Gao, Bingqian Zhang, Xianzhao Wang, Li Wang, Guanglei Cui, Shuping Pang   +15 more
doaj   +1 more source

Engineered Heparinized GQDS/HPEI–Polyamide Membrane for Bilirubin Removal via One Step Anti Coagulation

Advanced Materials Interfaces, EarlyView.
A multifunctional heparinized polyamide membrane embedded with graphene quantum dots (GQDs) and hyperbranched polyethyleneimine (HPEI) is engineered for efficient bilirubin removal via a one‐step anticoagulation–adsorption process. The membrane demonstrates enhanced hemocompatibility, prolonged clotting times, and high bilirubin adsorption capacity ...
Abdur Rehman Mushtaq Ahmad, Maria Wasim, Aneela Sabir, Muhammad Shafiq, Syed Abdul Basit Shah, Maoz Maoz, Vanni Lughi   +6 more
wiley   +1 more source

Stereoselective Biotransformation: Transfer of Learning to Advance Drug Metabolism and Biocatalysis

Angewandte Chemie, EarlyView.
Understanding stereoselective biotransformations has implications for predicting drug disposition and response and may also inspire novel biocatalytic and biomimetic strategies to address challenges in metabolite and API synthesis. ABSTRACT Chirality is an important determinant of drug action, as enantiomers can exhibit markedly different ...
Grace A. Okunlola, Godwin A. Aleku
wiley   +2 more sources

Chameleonic Color‐Variable Microbead Emitters for Multilevel Spectroscopic Encryption from Visible to Infrared Wavelengths

Advanced Optical Materials, EarlyView.
Whispering‐gallery‐mode microresonators with sharp resonant peaks enable photonic barcoding. Similar to a chameleon, a rare‐earth‐free microcavity with π‐conjugated PAHs enables visibleto‐near infrared color generation from a single microbead. The unique resonat emission (spectral barcode) can be dynamically transformed via excitation wavelength change,
Barun Kumar Barman, Keisuke Watanabe, Kenzo Deguchi, Shinobu Ohki, Kenjiro Hashi, Atsushi Goto, Tadaaki Nagao   +6 more
wiley   +1 more source

One-pot preparation of spherical polycyclic aromatic polymer particles using various aliphatic amines

Next Materials
The synthesis of nano- to microsized spherical polymer particles can be achieved via various methods, however, particle formation methods involving consecutive reactions are scarce.
Nanami Hano, Mai Fukunaga, Hirotaka Ihara, Makoto Takafuji   +3 more
doaj   +1 more source

Continuous-flow synthesis of primary amines: Metal-free reduction of aliphatic and aromatic nitro derivatives with trichlorosilane

Beilstein Journal of Organic Chemistry, 2016
The metal-free reduction of nitro compounds to amines mediated by trichlorosilane was successfully performed for the first time under continuous-flow conditions.
Riccardo Porta, Alessandra Puglisi, Giacomo Colombo, Sergio Rossi, Maurizio Benaglia   +4 more
doaj   +1 more source

Biolipid Film‐Fused Electrochemiluminescence for Multipurpose In Situ Bioassays

Advanced Science, EarlyView.
An ECL‐emissive, membrane‐interactive scaffold was fabricated, and facilely fused with natural and non‐native phospholipids into multifactorial mimicries of cytomembranes and vesicles for in vitro representative membrane‐process probing. Such a biointerface‐based, state‐sensitive ECL paradigm not only pinpointed proximal phenomena, including channeling
Jialiang Chen, Bin Li, Yingying Wang, Fulin Zhu, Wenxuan Yang, Xuanyu Fu, Tiantian Man, Qiuyue Wu, Kewei Ren, Shengyuan Deng   +9 more
wiley   +1 more source