Results 31 to 40 of about 32,282 (298)

Site-specific Deaminative Trifluoromethylation of Aliphatic Primary Amines

open access: yes, 2023
The introduction of trifluoromethyl groups into organic molecules is of paramount importance in modern synthetic chemistry and medicinal chemistry. While methods for constructing C(sp2)-CF3 bonds have been well established, the advancement of practical ...
Yin , Li   +4 more
core   +1 more source

Exogenous Directing Group Free, Ligand-Enabled gamma-C(sp3)–H Arylation of Free Primary Aliphatic Amines and α-Amino Esters

open access: yes, 2019
A Pdᴵᴵ-catalyzed, ligand-enabled gamma-C(sp3)–H arylation of free primary aliphatic amines and amino esters without using an exogenous directing group is reported.
Gang, Li   +4 more
core   +1 more source

Mild Biamidine-Transfer Conditions for the Synthesis of Aliphatic Biguanides

open access: yesSynOpen, 2021
This study focuses on the development of new synthetic pathways to monosubstituted biguanides from amines. An exhaustive comparison of the conditions and reagents used for biamidine transfer was performed.
Rostyslav Bardovskyi   +3 more
doaj   +1 more source

Thermal oxidation kinetics of additive free polyamide 6-6 [PDF]

open access: yes, 2013
Thermal aging of an additive free PA 6-6 has been elucidated at 90, 100, 120, 140, 150 and 160 C in airventiled ovens by Fourier transform infrared spectrophotometry, viscosimetry in molten state and uniaxial tensile testing.
BEN HASSINE, Mouna   +3 more
core   +1 more source

Designed Lewis Acid–Base Passivation for High Performance Perovskite Solar Cells

open access: yesAdvanced Functional Materials, EarlyView.
ABSTRACT Silicon's high cost and long energy payback time remain major barriers to the global expansion of solar power. In contrast, metal–halide perovskites offer abundant, solution‐processable absorbers, and have achieved efficiencies of 25%–30%, positioning them as strong competitors to silicon.
Afna Manaf   +4 more
wiley   +1 more source

Deaminative bromination, chlorination, and iodination of primary amines

open access: yesiScience, 2023
Summary: The primary amino group has been seldom utilized as a transformable functionality in organic synthesis. Reported herein is a deaminative halogenation of primary amines using N-anomeric amide as the nitrogen-deletion reagent.
Jiang-Hao Xue   +6 more
doaj   +1 more source

Luminescent complexes of iridium(iii) with aliphatic amines and detection of biogenic amines [PDF]

open access: yes, 2020
The straightforward reaction of [Ir2(ppy)4(µ-Cl)2] with an excess of aliphatic amines yields luminescent iridium complexes of general formula [IrCl(ppy)2(amine)] [amine = n-octylamine (1), t-butylamine (2), piperidine (3)].
Torroba Pérez, Tomás   +8 more
core   +1 more source

Dual Acidic pH‐Responsive Post‐Crosslinked E‐Spun Nanofibrous Scaffolds Exhibiting Enhanced Disassembly and Release for Localized Cancer Treatment

open access: yesAdvanced Healthcare Materials, EarlyView.
Dual acidic pH‐responsive degradable e‐spun nanofibrous mats crosslinked with acid‐labile imine and boronic ester linkages that exhibit rapid degradation and enhanced release of encapsulated anticancer drugs through their acid‐catalyzed hydrolysis and their doxorubicin‐loaded mats having desired antitumoral activity and hemocompatibility, as promising ...
Sofia Nieves Casillas‐Popova   +4 more
wiley   +1 more source

The effect of iodo substituents in bis(phenoxyimine) zirconium complexes on the catalytic performance of homogeneous ethylene polymerization reactions [PDF]

open access: yesPolyolefins Journal, 2018
Eight different zirconium phenoxyimine complexes were synthesized, characterized and tested as catalysts for ethylene polymerization. The phenoxyimine compounds were prepared by condensation of substituted salicylaldehydes with aliphatic and aromatic ...
Andrea Rimkus, Helmut Alt
doaj   +1 more source

Photocatalytic hydrogen atom transfer-induced Arbuzov-type -C(sp3)-H phosphonylation of aliphatic amines

open access: yes, 2023
Despite remarkable progress in photocatalytic hydrogen atom transfer (HAT)-induced C(sp3)-H functionalization, achieving C(sp3)-H to C(sp3)-P transformation by the HAT process remains highly challenging due to P-reagents’ compatibility issues.
Weigang, Zhang, Jie, Wu, Zhexuan, Lei
core   +1 more source

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