Aliphatic Amines Unlocked for Selective Transformations through Diazotization [PDF]
Angewandte Chemie - International EditionWhile aromatic diazonium salts are important reagents in organic synthesis, ‘Diazonium ions generated from ordinary aliphatic primary amines are usually useless for preparative purposes, since they lead to a mixture of products giving not only ...
Dorota Gryko
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Catalytic asymmetric reductive hydroalkylation of enamides and enecarbamates to chiral aliphatic amines [PDF]
Nature Communications, 2021 Enantiopure aliphatic amines are frequently encountered as chiral auxiliaries and synthetic intermediates for bioactive compounds. Here, the authors report a mild nickel-catalysed asymmetric reductive hydroalkylation to convert enamides and enecarbamates
Jia-Wang Wang +7 more
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Enantioselective access to chiral aliphatic amines and alcohols via Ni-catalyzed hydroalkylations [PDF]
Nature Communications, 2021 Chiral aliphatic amine and alcohol derivatives are difficult to access due to the challenge to differentiate between spatially and electronically similar alkyl groups.
Shan Wang +5 more
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From amines to (form)amides: a simple and successful mechanochemical approach
Beilstein Journal of Organic Chemistry, 2022 Two easily accessible routes for preparing an array of formylated and acetylated amines under mechanochemical conditions are presented. The two methodologies exhibit complementary features as they enable the derivatization of aliphatic and aromatic ...
Federico Casti +2 more
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Computationally aided design of defect-appended aliphatic amines for CO2 activation within UiO-66
, 2022 We report CO2 adsorption and subsequent formation of carbamic acid within defective UiO-66 functionalised with aliphatic amines. Periodic Density Functional Theory (DFT) calculations confirm the activation of CO2 with the aliphatic amines and the ...
Marco, Taddei +2 more
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Nature Communications, 2023 The selective enzymatic reduction of nitroaliphatic and nitroaromatic compounds to aliphatic amines and amino-, azoxy- and azo-aromatics, respectively, remains a persisting challenge for biocatalysis.
Alejandro Prats Luján +5 more
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Cu-Catalysed Coupling of Aliphatic Amines with Alkylboronic Esters
, 2023 We report a Cu-catalysed oxidative coupling of aliphatic amines with benzylic and aliphatic boronic esters to give high value alkyl amines, products found widely in applications from medicinal chemistry to materials science.
Antonio, Romero Arenas +6 more
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Cloud condensation nuclei (CCN) activity of aliphatic amine secondary aerosol [PDF]
Atmospheric Chemistry and Physics, 2014 Aliphatic amines can form secondary aerosol via oxidation with atmospheric radicals (e.g., hydroxyl radical and nitrate radical). The particle can contain both secondary organic aerosol (SOA) and inorganic salts.
X. Tang +7 more
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Thermodynamic Study on Reaction of Tetra Sulfona to Phenyl Porphyrin Iron (II) Complex With Different Nitrogenous Ligands [PDF]
مجلة جامعة الانبار للعلوم الصرفة, 2015 The binding characteristics of number of axial aliphatic amines ligands were studied with Fe(ll)TPPS4 complex in aqueous solutions at hiqh PHs > 12.5 . All formed low spin octahedral complexes . Electronic absorption , ΔH , ΔG , and ΔS of these complexes
Jihad A. Taies, Riyath M. Dalaf
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Scientific Opinion on Flavouring Group Evaluation 86, Revision 2 (FGE.86Rev2): Consideration of aliphatic and arylalkyl amines and amides evaluated by JECFA (65th meeting) [PDF]
EFSA Journal, 2015 The Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids of the European Food Safety Authority was requested to consider evaluations of flavouring substances assessed since 2000 by the Joint FAO/WHO Expert Committee on Food Additives
EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF)
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