Results 21 to 30 of about 32,282 (298)

Reshaping Ullmann Amine Synthesis in Deep Eutectic Solvents: A Mild Approach for Cu-Catalyzed C–N Coupling Reactions With No Additional Ligands

open access: yesFrontiers in Chemistry, 2019
The CuI-catalyzed Ullmann amine cross-coupling between (hetero)aryl halides (Br, I) and aromatic and aliphatic amines has been accomplished in deep eutectic solvents as environmentally benign and recycling reaction media.
Andrea Francesca Quivelli   +3 more
doaj   +1 more source

Ligand controlled orthogonal selectivity between distal positions of fully unbiased aliphatic amines

open access: yes, 2023
Aliphatic C(sp3)‒H bonds are inherently difficult to activate owing to their inertness and chemical indistinguishability. This challenge has been overcome mostly by directing group approach however the regioselectivity in distal aliphatic positions has ...
Nupur, Goswami   +7 more
core   +1 more source

Spectrophotometric Determination of Microgram Amounts of Aliphatic Amines with Quinalizarin [PDF]

open access: yesمجلة التربية والعلم, 2009
A simple, rapid and sensitive spectrophotometric method for the determination of aliphatic amines was developed. The method is based on the proton transfer reaction with quinalizarin reagent in aqueous neutral solution to form violet product which shows ...
T. Al-Ghabsha, A. Al-Delymi
doaj   +1 more source

Ceria-Based Mixed Oxide Supported Nano-Gold as an Efficient and Durable Heterogeneous Catalyst for Oxidative Dehydrogenation of Amines to Imines Using Molecular Oxygen [PDF]

open access: yes, 2012
The present work is intended to determine the catalytic activity of Mixed Oxide supported gold for aerobic oxidative dehydrogenation of amines to imines using Ceria as a main constituent of the each support. The model catalysts Au/CeO2:TiO2 Au/CeO2:SiO2,
Sharma, Meena   +5 more
core   +1 more source

Synthesis of alpha,gamma-Chiral Trifluoromethylated Amines through the Stereospecific Isomerization of alpha-Chiral Allylic Amines

open access: yes, 2022
Chiral gamma-branched aliphatic amines are present in a large number of pharmaceuticals and natural products. However, enanti-oselective methods to access these compounds are scarce, and rely on the use of designed chiral transition-metal complexes ...
Victor, García-Vázquez   +4 more
core   +1 more source

Copper-Catalyzed Alkylation of Aliphatic Amines Induced by Visible Light. [PDF]

open access: yesJ Am Chem Soc, 2017
Although the alkylation of an amine by an alkyl halide serves as a “textbook example” of a nucleophilic substitution reaction, the selective mono-alkylation of aliphatic amines by unactivated, hindered halides persists as a largely unsolved challenge in ...
Matier CD, Schwaben J, Peters JC, Fu GC.
europepmc   +2 more sources

Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines [PDF]

open access: yes, 2015
Available in PMC 2016 July 03.Catalytic assembly of enantiopure aliphatic amines from abundant and readily available precursors has long been recognized as a paramount challenge in synthetic chemistry.
Niu, Dawen   +5 more
core   +1 more source

Electrochemical Synthesis of Allylic Amines from Alkenes and Amines

open access: yes, 2021
Allylic amines are valuable synthetic targets en route to diverse biologically active amine products. Current allylic C–H amination strate-gies remain limited with respect to the viable N-substituents.
Zachary, Wickens   +2 more
core   +1 more source

Michael addition of aromatic and aliphatic amines to unsaturated olefines in the presence of TMSCl under solvent free conditions [PDF]

open access: yesشیمی کاربردی روز, 2008
An operationally simple and highly fast protocol for TMSCl (10 mol%) catalyzed conjugate addition of aromatic and aliphatic amines derivatives to unsaturated carbonyl compounds in good to excellent yields has been developed.
Najmadin Azizi
doaj   +1 more source

Phthaloylation of amines, hydrazines, and hydrazides by N-substituted phthalimides using recyclable sulfated polyborate

open access: yesResults in Chemistry, 2022
An efficient, fast, and environmentally gentle protocol for phthaloylation of amines, hydrazines and hydrazides via transamidation is described. The current research focuses on the phthaloylation of alicyclic, aliphatic, aromatic, heterocyclic amines ...
Prerna Ganwir   +2 more
doaj   +1 more source

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