Results 81 to 90 of about 456 (163)

Grafting Nanolayers of Ni and Co Catalysts Around the Edges of Hierarchical Zeolite 13X by Leveraging the Crystal's Defects for CO2 Methanation

open access: yesCarbon Energy, EarlyView.
The deactivation of nickel‐based catalysts at high temperatures poses a significant challenge in CO2 methanation processes. To address this, a strong metal–support interaction between nickel and the support was engineered by exploiting the crystal defects present in hierarchical porous zeolite 13X.
Nasir Shezad   +7 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview

open access: yesChemistry – A European Journal, EarlyView.
The graphical abstract summarizes the review “Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview”, highlighting representative Pd(II)‐catalyzed methods for the β‐arylation of α‐amino acids. Key mechanistic features, substrate diversity, and synthetic relevance of these transformations are showcased. Abstract Metal‐catalyzed C─
Davide Illuminati   +4 more
wiley   +1 more source

Supramolecular Host‐Guest Complexation Dynamics by Cost‐Efficient Electronic Structure Methods

open access: yesChemistry – A European Journal, EarlyView.
We present a cost‐effective multilevel workflow for the kinetic profiling of host–guest systems, illustrated with cucurbit[6]uril and alkylammonium cations. The method combines rapid docking and reaction path searches at the semi‐empirical level, with refinement of the results using modern density functional theory, accurately reproducing experiment ...
Thomas Gasevic   +6 more
wiley   +1 more source

Hole‐Selective Self‐Assembled Monolayers Overlaid on NiOx or PEDOT:PSS for Tin‐Based Perovskite Solar Cells – An Overview of Recent Characterization Methods

open access: yesChemistry – A European Journal, EarlyView.
Successfully applying self‐assembled monolayers with hole‐selectivity for lead‐free tin perovskite solar cells requires judicious investigation with appropriately powerful characterization methods, in addition to efforts in the development of new materials and processing.
Donghoon Song   +3 more
wiley   +1 more source

Interaction between pheophorbide a and primary aliphatic amines.

open access: yesТонкие химические технологии, 2008
The effect of primary aliphatic amine structure and conditions (solvent, the presence of tertiary amine) in course of its reaction with pheophorbide a and methylpheophorbide a on the yield of the final product – chlorine е6-13-alkylamide has been shown.
Е. А. Larkina   +3 more
doaj  

Self‐Assembled Luminescent Au(I)–Adamantylamine Coordination Polymer Needles With Thermoresponsive Optical Properties

open access: yesChemistry – A European Journal, EarlyView.
A self‐assembled hydrophobic and red phosphorescent Au(I) coordination polymer (CP) was synthesized under mild conditions. Single‐crystal X‐ray diffraction (XRD) demonstrated linear Au(I) chains stabilized by aurophilic and hydrogen bonding interactions.
Miguel Justo‐Tirado   +4 more
wiley   +1 more source

Synthesis of 1‐Alkynylboronates, 1,1‐Diborylalkenes, and 1,1,1‐Triborylalkanes: Challenges and Opportunities

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT In the field of organoboron chemistry, multi(boronate) esters have emerged as crucial intermediates, with various applications in synthetic chemistry, material technology, and life sciences. This mini‐review discusses recent advancement in the synthesis of these versatile compounds, particularly alkynylboronates, 1,1‐diborylalkenes, and 1,1,1 ...
Son Hoai Doan   +2 more
wiley   +1 more source

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