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Recent Advances in the High-Value Conversion of Alkenes Induced by Electrochemistry [PDF]
MoleculesOver the past few decades, electrosynthesis has advanced significantly, enabling numerous valuable transformations for synthetic chemists. Olefins are inexpensive, readily available industrial feedstocks extensively used in organic synthesis.
Xing’an Liang +4 more
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Alkene Diversification through a Molecular Recasting Strategy Enabled by N-Heterocyclic Carbene and Photoredox Dual Catalysis [PDF]
ResearchAlkenes are fundamental structural motifs in organic synthesis, valued for their prevalence in natural products and their broad reactivity profile. While traditional de novo synthesis offers access to diverse alkene frameworks, strategies enabling the ...
Qing-Zhu Li +6 more
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Synthesis of a New α-Azidomethyl Styrene from Safrole via a Dearomative Rearrangement
Molbank, 2023 There is a growing interest in developing more efficient synthetic alternatives for the synthesis of nitrogen-containing allylic compounds. This article presents a straightforward two-step protocol to produce 5-(3-azidoprop-1-en-2-yl)benzo[d][1,3]dioxole
Stephen R. Isbel, Alejandro Bugarin
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Iodoaminations of Alkenes [PDF]
Synthesis, 2016 The activation of alkenes and their subsequent functionalization is a frequently used methodology in synthetic chemistry. This review highlights recent iodine-mediated aminations and elaborates on the various strategies to bring about regio- or stereoselective transformations.
Wirth, Thomas, Mizar, Pushpak
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Molecules, 2022 Asymmetric epoxidation of a series of olefinic substrates with sodium percarbonate oxidant in the presence of homogeneous catalysts based on Mn complexes with bis-amino-bis-pyridine ligands is reported.
Varvara A. Drozd +2 more
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Reactions, 2021 Fischer–Tropsch synthesis (FTS) produces hundreds of hydrocarbons and oxygenates by simple reactants (CO + H2) and the detailed chain propagation mechanism is still in dispute.
Liping Zhou +4 more
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Alkene-oxo and alkene-alkene coupling on Pt(II) [PDF]
, 2021 Tetranuclear Pt(II) oxo-complex [(COD)4Pt4([mu]3-O)2Cl2](BF4)2 (1) (COD = 1,5- cyclooctadiene) was found to readily react with a variety of alkenes (ethylene, norbornene, propylene and cyclopentene). The most significant discovery resulted from the norbornene reaction, which gave platinaoxetane [(COD)2Pt2(OC7H10)Cl]BF4 (4), the first metallaoxetane ...
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2-Alkylation of 3-Alkyindoles With Unactivated Alkenes
Frontiers in Chemistry, 2022 An acid-catalyzed 2-alkylation of indole molecules is developed. Only catalytic amount of the commercially available, inexpensive and traceless HI is used as the sole reaction promoter. 2,3-Disubstituted indole molecules bearing congested tertiary carbon
Xuling Pan, Qian Liu, Yingling Nong
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Metabolic Engineering Communications, 2018 Alkenes are industrially important platform chemicals with broad applications. In this study, we report a direct microbial biosynthesis of terminal alkenes from fermentable sugars by harnessing a P450 fatty acid (FA) decarboxylase from Macrococcus ...
Jong-Won Lee +2 more
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A mild and effective method for the conversion of alkenes into alcohols in subcritical water [PDF]
Journal of the Serbian Chemical Society, 2007 Alkenes were oxidized to alcohols in subcritical water. A number of alkenes were oxidized directly to their alcohols in excellent yields. The syntheses were performed in 215 cm3 stainless steel high pressure reactor at 120 ºC in 150 cm3 water. The yields
RECEP OZEN, NERMİN S. KUS
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