Results 21 to 30 of about 96,389 (286)
Science and Technology of Advanced Materials, 2019 A series of Rh-based intermetallic compounds supported on silica was prepared and tested in alkene hydrogenation at room temperature. H2 and D2 were used as the hydrogen sources and the kinetic isotope effect (KIE) in hydrogenation was studied.
Shinya Furukawa +3 more
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Alkyne–Alkene [2 + 2] cycloaddition based on visible light photocatalysis
Nature Communications, 2020 UV-activated alkyne–alkene [2 + 2] cycloaddition has served as an important tool to access cyclobutenes. Although broadly adopted, the limitations with UV light as an energy source prompted us to explore an alternative method.
Sujin Ha +6 more
semanticscholar +1 more source
Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes
Molecules, 1997 Irradiation of pentafluoroiodobenzene and alkenes gave the corresponding adducts. The presence of single electron-transfer scavengers, (p-dinitrobenzene and t-Bu2NO) and the free radical inhibitor (hydroquinone) suppressed the reaction.
Qing-Yun Chen, Zheng-Yu Long, Ping Cao
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Frontiers in Microbiology, 2021 The ability to produce medium chain length aliphatic hydrocarbons is strictly conserved in all photosynthetic cyanobacteria, but the molecular function and biological significance of these compounds still remain poorly understood.
Eerika Vuorio +7 more
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Recent developments in gold-catalyzed cycloaddition reactions
Beilstein Journal of Organic Chemistry, 2011 In the last years there have been extraordinary advances in the development of gold-catalyzed cycloaddition processes. In this review we will summarize some of the most remarkable examples, and present the mechanistic rational underlying the ...
Fernando López, José L. Mascareñas
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Microbiology Spectrum, 2023 There is a growing need for biological and chemical methods for upcycling plastic waste streams. Pyrolysis processes can accelerate plastic depolymerization by breaking polyethylene into smaller alkene components which may be more biodegradable than the ...
Emily Byrne +3 more
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Nature CatalysisThe development of novel strategies to rapidly construct complex chiral molecules from readily available feedstocks is a long-term pursuit in the chemistry community.
Xia Hu +4 more
semanticscholar +1 more source
Arylsulfonylacetamides as bifunctional reagents for alkene aminoarylation
Science, 2018 Arenes and amides from a single source Pharmaceutical synthesis often requires the formation of adjacent carbon-carbon and carbon-nitrogen bonds. Monos et al.
Timothy M Monos +2 more
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Alkene Isomerization through Allylmetals as a Strategic Tool in Stereoselective Synthesis
, 2020 The positional isomerization of alkenes is a well-known process mediated by various transition metal complexes.
Itai Massad, I. Marek
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Cyclization–endoperoxidation cascade reactions of dienes mediated by a pyrylium photoredox catalyst
Beilstein Journal of Organic Chemistry, 2014 Triarylpyrylium salts were employed as single electron photooxidants to catalyze a cyclization–endoperoxidation cascade of dienes. The transformation is presumed to proceed via the intermediacy of diene cation radicals.
Nathan J. Gesmundo, David A. Nicewicz
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