Results 11 to 20 of about 29,164 (249)

A mild and effective method for the conversion of alkenes into alcohols in subcritical water [PDF]

open access: yesJournal of the Serbian Chemical Society, 2007
Alkenes were oxidized to alcohols in subcritical water. A number of alkenes were oxidized directly to their alcohols in excellent yields. The syntheses were performed in 215 cm3 stainless steel high pressure reactor at 120 ºC in 150 cm3 water. The yields
RECEP OZEN, NERMİN S. KUS
doaj   +3 more sources

Extraordinarily large kinetic isotope effect on alkene hydrogenation over Rh-based intermetallic compounds

open access: yesScience and Technology of Advanced Materials, 2019
A series of Rh-based intermetallic compounds supported on silica was prepared and tested in alkene hydrogenation at room temperature. H2 and D2 were used as the hydrogen sources and the kinetic isotope effect (KIE) in hydrogenation was studied.
Shinya Furukawa   +3 more
doaj   +1 more source

Synthetic Biology Approaches to Hydrocarbon Biosensors: A Review

open access: yesFrontiers in Bioengineering and Biotechnology, 2022
Monooxygenases are a class of enzymes that facilitate the bacterial degradation of alkanes and alkenes. The regulatory components associated with monooxygenases are nature’s own hydrocarbon sensors, and once functionally characterised, these components ...
Claudia F. Moratti   +3 more
doaj   +1 more source

Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes

open access: yesMolecules, 1997
Irradiation of pentafluoroiodobenzene and alkenes gave the corresponding adducts. The presence of single electron-transfer scavengers, (p-dinitrobenzene and t-Bu2NO) and the free radical inhibitor (hydroquinone) suppressed the reaction.
Qing-Yun Chen, Zheng-Yu Long, Ping Cao
doaj   +1 more source

Hydrocarbon Desaturation in Cyanobacterial Thylakoid Membranes Is Linked With Acclimation to Suboptimal Growth Temperatures

open access: yesFrontiers in Microbiology, 2021
The ability to produce medium chain length aliphatic hydrocarbons is strictly conserved in all photosynthetic cyanobacteria, but the molecular function and biological significance of these compounds still remain poorly understood.
Eerika Vuorio   +7 more
doaj   +1 more source

Recent developments in gold-catalyzed cycloaddition reactions

open access: yesBeilstein Journal of Organic Chemistry, 2011
In the last years there have been extraordinary advances in the development of gold-catalyzed cycloaddition processes. In this review we will summarize some of the most remarkable examples, and present the mechanistic rational underlying the ...
Fernando López, José L. Mascareñas
doaj   +1 more source

Impacts of Nutrients on Alkene Biodegradation Rates and Microbial Community Composition in Enriched Consortia from Natural Inocula

open access: yesMicrobiology Spectrum, 2023
There is a growing need for biological and chemical methods for upcycling plastic waste streams. Pyrolysis processes can accelerate plastic depolymerization by breaking polyethylene into smaller alkene components which may be more biodegradable than the ...
Emily Byrne   +3 more
doaj   +1 more source

Radical-Mediated Trifunctionalization Reactions

open access: yesMolecules
Synthetic radicals have intrinsic power for cascading and multifunctional reactions to construct diverse molecular scaffolds. In the previous review series, we covered 1,2-difunctionalizations, remote 1,3-, 1,4-, 1,5-, 1,6-, and 1,7-difunctionalizations,
Qiang Zhang   +3 more
doaj   +1 more source

Cyclization–endoperoxidation cascade reactions of dienes mediated by a pyrylium photoredox catalyst

open access: yesBeilstein Journal of Organic Chemistry, 2014
Triarylpyrylium salts were employed as single electron photooxidants to catalyze a cyclization–endoperoxidation cascade of dienes. The transformation is presumed to proceed via the intermediacy of diene cation radicals.
Nathan J. Gesmundo, David A. Nicewicz
doaj   +1 more source

Intrinsic Photoactive Star ZnPc–Poly(glutamate) Nanoplatforms for Multimodal Glioblastoma Therapy and Brain‐Targeted Delivery

open access: yesAdvanced Functional Materials, EarlyView.
An intrinsic photoactive star‐shaped zinc phtalocyanine‐poly(L‐glutamic acid) (ZnPc‐PGA) nanoplatform for multimodal glioblastoma (GBM) therapy and brain‐targeted elivery. A ZnPc‐PGA‐based multifunctional theranostic nanocarrier platform enables image‐guided, multimodal GBM therapy. ZnPc‐PGA nanocarriers support the integration of fluorescence imaging,
Amina Benaicha‐Fernández   +14 more
wiley   +1 more source

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