Results 11 to 20 of about 30,672 (247)

Synthetic Biology Approaches to Hydrocarbon Biosensors: A Review

open access: yesFrontiers in Bioengineering and Biotechnology, 2022
Monooxygenases are a class of enzymes that facilitate the bacterial degradation of alkanes and alkenes. The regulatory components associated with monooxygenases are nature’s own hydrocarbon sensors, and once functionally characterised, these components ...
Claudia F. Moratti   +3 more
doaj   +1 more source

A mild and effective method for the conversion of alkenes into alcohols in subcritical water [PDF]

open access: yesJournal of the Serbian Chemical Society, 2007
Alkenes were oxidized to alcohols in subcritical water. A number of alkenes were oxidized directly to their alcohols in excellent yields. The syntheses were performed in 215 cm3 stainless steel high pressure reactor at 120 ºC in 150 cm3 water. The yields
RECEP OZEN, NERMİN S. KUS
doaj   +3 more sources

Study on the total synthesis of velbanamine: Chemoselective dioxygenation of alkenes with PIFA via a stop-and-flow strategy

open access: yesBeilstein Journal of Organic Chemistry, 2013
A “stop-and-flow” strategy was developed for the chemoselective dioxygenation of alkenes with a PIFA-initiated cyclization. This method is conceived for the desymmetrization of seco-diene, and a series of substituted 5-hydroxymethyl-γ-lactones were ...
Huili Liu   +4 more
doaj   +1 more source

Hydrocarbon Desaturation in Cyanobacterial Thylakoid Membranes Is Linked With Acclimation to Suboptimal Growth Temperatures

open access: yesFrontiers in Microbiology, 2021
The ability to produce medium chain length aliphatic hydrocarbons is strictly conserved in all photosynthetic cyanobacteria, but the molecular function and biological significance of these compounds still remain poorly understood.
Eerika Vuorio   +7 more
doaj   +1 more source

Photoelectrocatalytic Diazidation of Olefins via Synergistic Dual Iron Species. [PDF]

open access: yesAdv Sci (Weinh)
We report a simple and general approach for 1,2‐diazidation of alkenes by a photoelectrochemical strategy using TMSN3 as an azide source. This transformation proceeds using earth‐abundant iron under mild reaction conditions. It displays broad functional group compatibility and accommodates diverse alkene types‐including unactivated, activated, electron‐
Guan ZP   +6 more
europepmc   +2 more sources

Recent advances in transition-metal-catalyzed intermolecular carbomagnesiation and carbozincation

open access: yesBeilstein Journal of Organic Chemistry, 2013
Carbomagnesiation and carbozincation reactions are efficient and direct routes to prepare complex and stereodefined organomagnesium and organozinc reagents.
Kei Murakami, Hideki Yorimitsu
doaj   +1 more source

Impacts of Nutrients on Alkene Biodegradation Rates and Microbial Community Composition in Enriched Consortia from Natural Inocula

open access: yesMicrobiology Spectrum, 2023
There is a growing need for biological and chemical methods for upcycling plastic waste streams. Pyrolysis processes can accelerate plastic depolymerization by breaking polyethylene into smaller alkene components which may be more biodegradable than the ...
Emily Byrne   +3 more
doaj   +1 more source

Anomeric Amide‐Enabled Alkene‐Arene and Alkene‐Alkene Aminative Coupling

open access: yesAngewandte Chemie International Edition
AbstractDespite the prominence of C−N bond forming cross‐coupling reactions as a strategy to assemble molecular fragments, aminative coupling approaches, in which two fragments are assembled directly at the heteroatom, represents a rarely exploited retrosynthetic strategy. Herein, we report the design, synthesis, and implementation of an anomeric amide
Colin Stein   +5 more
openaire   +2 more sources

Radical-Mediated Trifunctionalization Reactions

open access: yesMolecules
Synthetic radicals have intrinsic power for cascading and multifunctional reactions to construct diverse molecular scaffolds. In the previous review series, we covered 1,2-difunctionalizations, remote 1,3-, 1,4-, 1,5-, 1,6-, and 1,7-difunctionalizations,
Qiang Zhang   +3 more
doaj   +1 more source

Effect of terahertz irradiation on DNA damage repair in living cells

open access: yesFEBS Open Bio, EarlyView.
We investigated the effect of terahertz (THz) wave irradiation on DNA double‐strand break (DSB) repair in living cells. We found that THz irradiation enhanced DSB repair at specific frequencies, whereas heat treatment inhibited it, indicating that this effect is nonthermal and frequency‐specific.
Yuya Ueno   +3 more
wiley   +1 more source

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