Copper-Catalyzed Amino-alkoxycarbonylation of Unactivated Alkenes: Synthesis of β-Amino Esters via Primary Tosyl Amidyl Radical. [PDF]
Mao X, Hou M, Wang Y, Miao RG, Wu XF.
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Palladium-catalyzed asymmetric migratory diarylation of unactivated directing-group-free internal alkenes. [PDF]
Fan L +6 more
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Additives Promote Divergent Reactivity in Photolytic Deoxygenation and Lactonization Reactions of Cobalt Alkoxycarbonyls. [PDF]
Hackbarth JN +4 more
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Coking is the central source of deactivation of zeolite catalysts. Using in situ XPS along with complementary methods, we identify differences in the formation kinetics and composition of surface coke on industrially relevant ZSM‐5 catalysts during MTH conversion, demonstrating the strong potential of this technique for studying catalyst deactivation ...
Luca Artiglia +6 more
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Nickel-Catalyzed Twofold Conjunctive Coupling via Philicity-Alternating Radical Relay. [PDF]
Jeon JH +7 more
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Synthesis and stereochemical analysis of dynamic planar chiral oxa[7]orthocyclophene. [PDF]
Hashimoto Y +3 more
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Aziridination of a Single Carbon Atom in Alkenes via Energy Transfer Catalysis
Contrary to traditional alkene aziridination via (formal) nitrene transfer, we herein report a strategy that achieves intermolecular aziridination of a single alkene carbon atom and installs an additional group at the other. Enabled by metal‐free energy transfer (EnT) catalysis, alkenyl boronates and silanes are transformed into reactive intermediates ...
Fritz Paulus +7 more
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Shining light on the mechanism of photochemical alkene formation in vitamin B<sub>12</sub>. [PDF]
Mukherjee A +6 more
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Overcoming the Barrier to Intermolecular Alkoxy Radical Reactivity: Proton-Coupled Electron Transfer-Mediated Alkene Hydroetherification. [PDF]
Delgutte LC +5 more
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Radical docking-migration: a powerful strategy for difunctionalization of alkenes and alkynes. [PDF]
Cao Z, Chen F, Zhu C.
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