Results 171 to 180 of about 96,389 (286)

Asymmetric Reduction of Unactivated Alkenes. [PDF]

open access: yesChemistry
Fessner ND, Roth S, Niese R, Müller M.
europepmc   +1 more source

Unlocking Catalyst Activation as a Critical Bottleneck in Cross‐Coupling Reactions: Room‐Temperature Couplings of Weak Nucleophiles Enabled by [Pd(1‐MeNAP)TFA]2 Precatalysts

open access: yesAngewandte Chemie International Edition, EarlyView.
In many Pd‐catalyzed cross‐couplings, catalyst performance has been found to be limited by catalyst activation. Methylnaphthyl (MeNAP) palladium trifluoroacetate dimers are presented as easy‐to‐store and easy‐to‐handle precursors, which rapidly activate under reaction conditions, even when only weakly coordinating, non‐reducing nucleophiles are present.
Sourav Manna   +6 more
wiley   +1 more source

Cation Sampling Enables Regiodivergent Distal Functionalization of Ketones. [PDF]

open access: yesJ Am Chem Soc
Spieß P   +5 more
europepmc   +1 more source

High-Fidelity Transfer of Chiral Sulfonimidoyl Radicals. [PDF]

open access: yesJ Am Chem Soc
Li R   +10 more
europepmc   +1 more source

Late‐Stage Functionalization of Peptides on the Solid Phase

open access: yesAngewandte Chemie International Edition, EarlyView.
Peptide modifications are essential to control pharmacodynamic and pharmacokinetic properties of peptide drugs. Consequently, strategies that allow for efficient and rapid incorporation of non‐canonical modifications into peptides in parallel formats are highly sought after.
Marius Werner   +2 more
wiley   +1 more source

Synthesis, Functionalization, and Reactivity of Vinyl Sulfondiimidamides. [PDF]

open access: yesAngew Chem Int Ed Engl
Rodden KG   +4 more
europepmc   +1 more source

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