Results 171 to 180 of about 52,647 (305)

Remote Desaturation of Unprotected Amines and C─H Amination of Alkanes by Polarity‐Matched N‐Radical Cations

Angewandte Chemie, EarlyView.
Highly electrophilic N‐radical cations enable efficient and selective H‐atom transfer (HAT) of unprotected amines. In this exceedingly practical strategy, simple CuCl catalyzes an interrupted Hofmann–Löffler–Freytag (HLF) reaction to afford δ desaturated amines, aza‐heterocycles, and C─H aminated alkanes without protecting groups.
Pavitra Laohapaisan, Ross M. Dare, Meredith L. Rudich, Jacob J. A. Garwood, Siyuan Gong, R. Thomas Simons, David A. Nagib   +6 more
wiley   +1 more source

Photo-Stitching of Nitroalkanes via Cross-Denitrative Olefination. [PDF]

J Am Chem Soc
Mitchell JK, Desai SP, Bergen JM, Reyes A, McLean MS, Ghosh P, Bansode AH, Parasram M.   +7 more
europepmc   +1 more source

Photoswitchable Ambiphilicity: Light‐Gated Frustrated Lewis Pair Reactivity and Z‐Type Interaction

Angewandte Chemie, EarlyView.
Light‐controlled ambiphilicity is realized in photoswitchable intramolecular phosphorus/boron Lewis pairs. Reversible switching modulates both the thermodynamics and kinetics of frustrated Lewis‐pair reactivity, enabling light‐gated CO2 binding and release.
Lennart Stoess, Emil L. M. Paulin, Fabian Michel, Lutz Greb   +3 more
wiley   +1 more source

Spontaneous Long‐Range Order and Alignment in Phase‐Separated Dynamic Covalent Networks Using Discrete Siloxanes

Angewandte Chemie, EarlyView.
Spontaneously aligned, long‐range hexagonal columnar ordering is obtained in phase‐separated dynamic covalent networks by combining discrete siloxanes and dynamic acylsemicarbazide bonds. The ordered network shows improved (thermo)mechanical properties and creep resistance compared to the disordered network.
Stefan J. D. Maessen, Tymen M. L. van der Leede, Anne B. Spoelstra, Bart W. L. van den Bersselaar, Bas F. M. de Waal, Johan P. A. Heuts, Anja R. A. Palmans   +6 more
wiley   +1 more source

Silylium-Ion-Initiated Disulfidation of Unactivated Alkenes with Disulfides: Methodology and Isolation of the Sulfenium-Ion Carriers. [PDF]

J Org Chem
Xu B, Liu X, Morgan DM, Irran E, Oestreich M.   +4 more
europepmc   +1 more source

Iron‐Photocatalyzed Alkene Chloroaminoxylation: A Platform for Orthogonally Activatable Building Blocks

Angewandte Chemie, EarlyView.
An iron‐photocatalyzed unsymmetrical 1,2‐hetero(atom)difunctionalization of alkenes enables to install orthogonal C–Cl and C–O (alkoxyamine) handles which provides access to diverse nucleophiles via complementary reactivity (SN and photoredox) at two distinct sites. Detailed mechanistic studies elucidate interesting features of the iron catalytic cycle.
Amrita Chaudhuri, Meghana Aladahalli Shekar, Mohammad Zafar, Marianne Engeser, Gregor Schnakenburg, Ala Bunescu   +5 more
wiley   +1 more source

Synergistic effects in s- and d-block heterometallic compounds: small molecule activation and catalysis. [PDF]

Chem Sci
Gawron M, Wolf R.
europepmc   +1 more source

Acetylene Semi‐Hydrogenation by Photocatalysis

Angewandte Chemie, EarlyView.
Photocatalytic acetylene semi‐hydrogenation is an emerging light‐driven route to polymer‐grade ethylene, offering a mild alternative to energy‐intensive thermocatalysis. By replacing H2 co‐feed with water or other proton sources, these systems can achieve high selectivity under ambient conditions.
Anna Fortunato, Brando Adranno, Sharon Silloni, Marianna Barbieri, Claudia Masia, Francesca Arcudi, Luka Đorđević   +6 more
wiley   +1 more source

Nickel-catalyzed hydro- and deuteroacylation of acrylates using water as the hydrogen source. [PDF]

Chem Sci
Lindenmaier IH, Bölzle F, Fleischer I.
europepmc   +1 more source

Synergistic Silylium‐Ion and Palladium Catalysis Enables Migratory Alkene Silylation With Allylsilanes by Formal C–H/C–Si Metathesis

Angewandte Chemie, EarlyView.
Merging silylium‐ion and palladium catalysis provides a mechanistically distinct route to allylsilanes by formal C–H/Si–H metathesis. Using allylsilanes as silicon proelectrophiles, various allylarenes undergo migrative silylation, selectively yielding (E)‐allylsilanes.
Longhui Duan, Zheng‐Wang Qu, Stefan Grimme, Elisabeth Irran, Hendrik F. T. Klare, Martin Oestreich   +5 more
wiley   +1 more source