Results 61 to 70 of about 96,389 (286)

Gold-Catalyzed Hydrothiolation of Alkenes and Allenes with Thiols

Chemistry
The reaction mechanism of the gold-catalyzed hydrothiolation of alkenes (1) with thiols (2) has been investigated in detail. The tetranuclear gold complex, (PPh3)4Au4(SPh)2(NTf)2 (A), is a key intermediate in the catalytic hydrothiolation of alkenes.
Akiya Ogawa, Taichi Tamai, Keiko Fujiwara, Ryo Tanaka, Daichi Kurata, Yuki Yamamoto   +5 more
doaj   +1 more source

Palladium-catalyzed regio- and enantioselective migratory allylic C(sp3)-H functionalization

Nature Communications, 2021
Alkene isomerizations and asymmetric C–H functionalizations have been independently studied, but their combination in one protocol is uncommon. Here the authors show a palladium-catalyzed method to iteratively “walk” a terminal alkene along a carbon ...
Ye-Wei Chen, Yang Liu, Han-Yu Lu, Guo-Qiang Lin, Zhi-Tao He   +4 more
doaj   +1 more source

Layered Nanoporous Platforms for SERS Sensing

Advanced Materials Interfaces, EarlyView.
Here, we present a detailed investigation of the SERS performance of layered nanoporous metals. The controlled deposition of well‐defined, stacked porous layers enabled a systematic analysis of the effects of multimetallic systems in SERS experiments. Numerical models are also used to support the experimental findings.
Yanqiu Zou, Anastasiia Sapunova, Tommaso Giovannini, Chen Wang, Huaizhou Jin, Vincenzo Caligiuri, Sergio Marras, Andrea Schirato, Luca Bursi, Alessandro Alabastri, Shukun Weng, Ali Douaki, German Lanzavecchia, Ivan Marri, Roman Krahne, Nicolò Maccaferri, Zhenrong Zheng, Shangzhong Jin, Denis Garoli   +18 more
wiley   +1 more source

Surface‐Ligand‐Dependent Excited‐State Dynamics in Aqueous CuInSe2/ZnS Quantum Dot–Chlorophyll Assemblies

Advanced Materials Interfaces, EarlyView.
CuInSe2/ZnS quantum dots are synthesized in water and coupled with chlorophyll to probe ligand‐controlled excited‐state interactions. Broad visible–NIR emission and high PLQY are observed. Time‐resolved measurements reveal shortened chlorophyll lifetimes, indicating dynamic quenching via Förster energy and/or charge transfer, highlighting surface ...
Özge İbiş, Hadi Jahangiri, Elif Çeltek, Caner Ünlü   +3 more
wiley   +1 more source

Organophosphates as Versatile Substrates in Organic Synthesis

Molecules
This review summarizes the applications of organophosphates in organic synthesis. After a brief introduction, it discusses cross-coupling reactions, including both transition-metal-catalyzed and transition-metal-free substitution reactions. Subsequently,
Petr Oeser, Tomáš Tobrman
doaj   +1 more source

Catalytic Alkene Difunctionalization via Imidate Radicals

Journal of the American Chemical Society, 2018
The first catalytic strategy to harness imidate radicals has been developed. This approach enables alkene difunctionalization of allyl alcohols by photocatalytic reduction of their oxime imidates.
K. Nakafuku, Stacy C. Fosu, David A. Nagib   +2 more
semanticscholar   +1 more source

Femtosecond‐Laser Mould Texturing Enables Tunable Biointerfaces in COC Microfluidics

Advanced Materials Interfaces, EarlyView.
Femtosecond‐laser texturing of injection‐mould inserts enables scalable engineering of biointerfaces in cyclic olefin copolymer microfluidics. Replicated micro‐ and nano‐topographies modulate surface roughness and wettability, leading to texture‐dependent protein adsorption and cell adhesion without chemical post‐processing.
Irene Varela‐Leniz, Nora Larreategi, Laura Gemini, Taieb Bakouche, Florent Husson, Leire Gartzia‐Rivero, Eider Bilbao Castellanos, Ane Miren Zaldua, José Luis Vilas‐Vilela, Leire Etxeberria   +9 more
wiley   +1 more source

ALKENES

, 2014
Citation: 'alkenes' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.A00224 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms. Requests for commercial usage
Robert J. Ouellette, J. David Rawn
  +4 more sources

Copper-Catalyzed Alkene Aminoazidation as a Rapid Entry to 1,2-Diamines and Installation of an Azide Reporter onto Azahetereocycles

Journal of the American Chemical Society, 2017
A copper-catalyzed aminoazidation of unactivated alkenes is achieved for the synthesis of versatile unsymmetrical 1,2-diamine derivatives. This transformation offers an effective approach to installing an amide and an azide from two diffenent amino ...
Kun Shen, Qiu Wang
semanticscholar   +1 more source

Functional Fibers in Soft Robotics: Advances in Material, Structural, and Systemic Tactics

Advanced Robotics Research, EarlyView.
Fiber‐form robotic systems offer a scalable pathway toward embodied intelligence in soft robotics. This review surveys functional fibers as material, structural, and systemic elements, highlighting advances in responsive materials, architectural programing, and fabrication strategies.
Joonhee Won, Jaehyun Jang, Hyeonseo Kim, Inyoung Choi, Steve Park, Seongjun Park   +5 more
wiley   +1 more source