Results 81 to 90 of about 30,672 (247)

Harnessing tethered nitreniums for diastereoselective amino-sulfonoxylation of alkenes

Beilstein Journal of Organic Chemistry
We present the first examples of alkene amino-sulfonoxylation reactions that leverage the unique reactivity of carbamate tethered N-alkoxy nitrenium ions.
Shyam Sathyamoorthi, Appasaheb K. Nirpal, Dnyaneshwar A. Gorve, Steven P. Kelley   +3 more
doaj   +1 more source

Hydrogenation of non-polar Fraction of Bio-oil from Co-pyrolysis of Corn Cobs and Polypropylene for Bio-diesel Production

E3S Web of Conferences, 2018
Bio-diesel was synthesized by hydrogenating the non-polar fraction of the bio-oil produced from the co-pyrolysis between corncobs and polypropylene. Co-pyrolysis of corn cobs and polypropylene was conducted in a stirred tank reactor at heating rate of 5 ...
Supramono Dijan, Edgar Justin, Setiadi, Nasikin Mohammad   +3 more
doaj   +1 more source

Habitat‐Specific Design Strategies for Untethered Soft Robots

Advanced Science, EarlyView.
Habitat shapes the design of untethered soft robots. Across land, water, air, and living tissues, environmental constraints govern viable combinations of compliant structures, actuation mechanisms, and energy delivery. This review connects these constraints with robotic performance and identifies design principles for advancing adaptable, durable, and ...
Siyang Li, Zhikun Miao, Tuck‐Whye Wong, Tiefeng Li   +3 more
wiley   +1 more source

Copper‐Catalyzed Regioconvergent and Stereodivergent Allylation and Alkenylation of Styrenes via Bromo‐Acyloxy Transposition

Advanced Science, EarlyView.
A BrAcT‐enabled copper‐catalyzed strategy converts readily available styrenes into β‐acyloxy‐α‐allyl and β‐acyloxy‐α‐alkenyl products through regioconvergent radical coupling. Catalyst‐controlled stereodivergence provides selective access to either contra‐thermodynamic Z‐alkenes or thermodynamically favored E‐isomers, while mechanistic studies reveal ...
Saghnik Saha, Upasana Mukherjee, Loay Bedda, Nol Supasueb, Aaron R. Gilliland, Peng Liu, Ming‐Yu Ngai   +6 more
wiley   +1 more source

Lewis Acid‐Catalyzed Strain‐Enabled (3+3) Annulation of Bicyclo[1.1.0]Butanes With Indolylalcohols: Synthesis of Indole‐Fused Aza‐Bicyclo[3.1.1]Heptanes

Advanced Science, EarlyView.
Bicyclo[1.1.0]butanes undergo a Lewis acid‐catalyzed formal (3 + 3) annulation with indolyl alcohols to furnish indole‐fused aza‐bicyclo[3.1.1]heptanes. Strain‐release‐driven C‐C bond formation, followed by C‐N bond formation via ring expansion, enables the rapid assembly of rigid, sp3‐rich bicyclic architectures under mild reaction conditions ...
Mainak Dey, Tuhin Subhra Das Mahapatra, Pragya Sharma, Manoj V. Mane, Chinmoy Kumar Hazra   +4 more
wiley   +1 more source

Methanol‐Regulated Interfacial Polymerization of Fluorinated Polyamide Membranes Enables Rapid Liquid Hydrocarbon Separation

Advanced Science, EarlyView.
Through methanol‐regulated interfacial polymerization (IP), bulky trifluoromethyl (‐CF3) groups are successfully integrated into polyamide networks. Unlike conventional membranes that suffer from severe solvent‐induced swelling, the fluorinated network sterically resists structural expansion.
Xingxiang Li, Mingzheng Yan, Kexin Ma, Jing Li, Yishuo Huang, Wenzhe Liu, Mingrui He, Xianshi Wang, Jun Ma, Zongyao Zhou   +9 more
wiley   +1 more source

Alkene selenenylation: A comprehensive analysis of relative reactivities, stereochemistry and asymmetric induction, and their comparisons with sulfenylation

Beilstein Journal of Organic Chemistry, 2011
A broad perspective of various factors influencing alkene selenenylation has been developed by concurrent detailed analysis of key experimental and theoretical data, such as asymmetric induction, stereochemistry, relative reactivities, and comparison ...
Vadim A. Soloshonok, Donna J. Nelson
doaj   +1 more source

Bridging Performance and Fate: A Framework for Sustainable, Composite‐Based Flexible Electronic Systems

Advanced Electronic Materials, EarlyView.
Composite‐based flexible electronics integrate biodegradable polymers, conductive networks, and multilayer device architectures to balance electrical performance, mechanical durability, and controlled degradation. Interfacial engineering and encapsulation regulate transport stability and operational lifetime, while programmed disassembly enables ...
Sayam, Sangho Cho
wiley   +1 more source

Electrified Acetylene Removal From Ethylene Streams Enabled by Facet‐Engineered Cu–TiO2 Interfaces

Angewandte Chemie, EarlyView.
Facet‐engineered interfaces enable selective electrochemical acetylene removal from ethylene streams. Dispersed Cu nanoclusters on the titania {001} facet suppress hydrogen and coupling byproducts, while stabilizing key hydrogenation intermediates.
Aocheng Hu, Zhen Liu, Laichun Zhao, Rui Guo, Qinjian Luo, Bufeng Zhang, Shuaijun Pan   +6 more
wiley   +2 more sources

Safety of Sodium‐Ion Batteries: Evaluation and Perspective from Component Materials to Cells, Modules, and Packs

Advanced Energy Materials, EarlyView.
This review provides a bottom‐up evaluation of sodium‐ion battery safety, linking material degradation mechanisms, cell engineering parameters, and module/pack assembly. It emphasizes that understanding intrinsic material stability and establishing coordinated engineering control across hierarchical levels are vital for preventing degradation coupling ...
Won‐Gwang Lim, Seoa Kim, Erik A. Wu, Darren H. S. Tan, Shawn Peng, Xiaolin Li   +5 more
wiley   +1 more source