Results 141 to 150 of about 195,903 (365)

Skeletal Editing of Alkenes with Nitroarenes via Photoinduced Rearrangement of N─O═C Dipoles Forms Lactams and Amides

Advanced Science, EarlyView.
Skeletal editing of alkenes via the cascade cleavage of C(sp2)═C(sp2) and C(sp3)─C(sp3) bonds, enabling the insertion of the nitrogen atom and thereby the synthesis of lactam and amide derivatives using nitroarenes as nitrogen atom insertion reagents under light irradiation.
Hongyun Qin, Zemin Wang, Cong Shi, Jiashu Chen, Chao Liu, Xiangqian Li, Ruihua Liu, Dayong Shi   +7 more
wiley   +1 more source

Estimates of Cl atom concentrations and hydrocarbon kinetic reactivity in surface air at Appledore Island, Maine (USA), during International Consortium for Atmospheric Research on Transport and Transformation/Chemistry of Halogens at the Isles of Shoals [PDF]

, 2007
Average hydroxyl radical (OH) to chlorine atom (Cl·) ratios ranging from 45 to 119 were determined from variability‐lifetime relationships for selected nonmethane hydrocarbons (NMHC) in surface air from six different transport sectors arriving at ...
Fischer, Emily V., Pszenny, Alexander A. P., Russo, Rachel S., Sive, Barkley C., Varner, Ruth K.   +4 more
core   +1 more source

Nanozymes Integrated Biochips Toward Smart Detection System

Advanced Science, EarlyView.
This review systematically outlines the integration of nanozymes, biochips, and artificial intelligence (AI) for intelligent biosensing. It details how their convergence enhances signal amplification, enables portable detection, and improves data interpretation.
Dongyu Chen, Wang Zheng, Zhihui Zhang, Shenping Yu, Xinxin Hang, Han Wu, Xiao‐Wei Xiang, Wei Mu, Yanli Jiao, Zaizai Dong, Lingqian Chang   +10 more
wiley   +1 more source

The autoignition of cyclopentane and cyclohexane in a shock tube

, 2007
Ignition delay times of cyclohexane-oxygen-argon and cyclopentane-oxygen-argon mixtures have been measured in a shock tube, the onset of ignition being detected by OH radical emission.
Battin-Leclerc, Frédérique, Buda, Frédéric, Fournet, René, Glaude, Pierre-Alexandre, Hakka, Hichem, Sirjean, Baptiste, Warth, Valérie   +6 more
core   +1 more source

Beyond Traditional RAFT Polymerization: Emerging Strategies and Future Perspectives; A Third Update

Advanced Science, EarlyView.
This review explores recent advances in the past five years for non‐traditional RAFT polymerization, focusing on new activation strategies, sustainable depolymerization, and integration with automated and AI‐driven synthesis. Together, these innovations advance polymer chemistry and reveal how the pieces of the non‐traditional RAFT puzzle are steadily ...
Vianna F. Jafari, James L. Grace, Jiajia Li, Joji Tanaka, Glen R. Jones, Athina Anastasaki, Wei You, Jian Zhu, Masami Kamigaito, Cyrille Boyer, Greg G. Qiao   +10 more
wiley   +1 more source

Rewriting Alkene Frameworks: A Practical Strategy for Nitrogen Incorporation

ChemistryEurope
Expanding the reach of skeletal editing to unactivated hydrocarbons presents a formidable challenge in nitrogen incorporation chemistry. In a recent advance, Morandi and coworkers have developed a direct, metal‐free strategy to insert nitrogen into ...
Ranjini Laskar, Frank Glorius
doaj   +1 more source

Experimental and Theoretical Evidence for the Promotional Effect of Acid Sites on the Diffusion of Alkenes through Small‐Pore Zeolites

, 2021
Pieter Cnudde, E. Redekop, Weili Dai, Natale G. Porcaro, Michel Waroquier, Silvia Bordiga, Michael Hunger, Landong Li, Unni Olsbye, Véronique Van Speybroeck   +9 more
openalex   +1 more source

Radical Thiocyano(Selenocyano)trifluoromethylations of Alkenes on Water [PDF]

, 2023
Chi Gao, Yang Liu, Hongye Zhu, Mang Wang
openalex   +1 more source

Analog Signal Summation for Reinforcement Learning via Simultaneous Light–Voltage Modulation in a Synaptic Device

Advanced Science, EarlyView.
To overcome limitations of conventional AI hardware, a light‐voltage dual‐modulating synaptic (LVDS) transistor using an IGZO/InAs quantum dot hybrid structure is proposed. LVDS transistor enables analog summation for Dueling Deep Q‐Networks by independently modulating memory via optical and electrical stimuli.
Dong Gue Roe, Sungjoon Cheon, Seongil Im, Sinil Choi, Meeree Kim, Subeen Kim, Youngjae Yoo, Jeong Won Kim, Hyunsu Ju, Sohee Jeong, Jeong Ho Cho   +10 more
wiley   +1 more source

Triaminoalkenes Derived from Cyclic (Alkyl)(amino)carbenes with a 1,1′‐Ferrocenylene Backbone and N‐Heterocyclic Carbenes: fcCAAC–NHC Heterodimers

ChemistryOpen
The study addresses triaminoalkenes derived from [3]ferrocenophane‐type cyclic (alkyl)(amino)carbenes (fcCAACs) fc(CPh2CNR) (fc = 1,1′‐ferrocenylene) and N‐heterocyclic carbenes (NHCs). Stable target compounds are obtained in good yields as crystalline
Suman Yadav, Clemens Bruhn, Clemens Lücke, Richard Rudolf, Tabea Pfister, Biprajit Sarkar, Ulrich Siemeling   +6 more
doaj   +1 more source