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Dawn of photoredox catalysis [PDF]

open access: yesProceedings of the Japan Academy. Series B, Physical and Biological Sciences
Photoredox catalysis, which facilitates organic transformations under visible-light irradiation, including sunlight, has garnered considerable attention as a cornerstone of green chemistry.
Munetaka AKITA
doaj   +2 more sources

Eco-friendly synthesis of silver nanoparticles as an unexplored application of photoredox catalysis [PDF]

open access: yesNanoscale Advances
A novel and sustainable methodology that merges photoredox catalysis and nanotechnology for the synthesis of AgNPs is reported. This methodology employs eosin Y as an organic photoredox catalyst under mild, aqueous, and visible-light irradiation ...
Willber D. Castro-Godoy   +3 more
doaj   +2 more sources

Counterion-enabled divergent reactivity in dinuclear gold photoredox catalysis [PDF]

open access: yesNature Communications
Tuning the electronics of photocatalysts is crucial for controlling the reactivity pathways in photoredox catalysis. While the key approaches like ligand engineering and donor-acceptor modulation are crucial, they invariably require multistep synthesis ...
Mahesh Bhagwan Thoke   +4 more
doaj   +2 more sources

Modeling and Simulation of Reaction Environment in Photoredox Catalysis: A Critical Review

open access: yesFrontiers in Chemical Engineering, 2022
From the pharmaceutical industry’s point of view, photoredox catalysis has emerged as a powerful tool in the field of the synthesis of added-value compounds.
Gabriela Xavier de Oliveira   +4 more
doaj   +1 more source

Recent Synthetic Applications of the Hypervalent Iodine(III) Reagents in Visible-Light-Induced Photoredox Catalysis

open access: yesFrontiers in Chemistry, 2020
The synergistic combination of visible-light-induced photoredox catalysis with hypervalent iodine(III) reagents (HIRs) represents a particularly important achievement in the field of hypervalent iodine chemistry, and numerous notable organic ...
Chaoyue Chen   +3 more
doaj   +1 more source

Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations

open access: yesNature Communications, 2021
The generation of alkyl radicals through deoxygenation of abundant alcohols via photoredox catalysis is of interest. In this study, the authors report a one-pot strategy for visible-light-promoted photoredox coupling of alcohols with electron-deficient ...
Hong-Mei Guo, Xuesong Wu
doaj   +1 more source

Recent Advances in Visible-Light Photoredox Catalysis for the Thiol-Ene/Yne Reactions

open access: yesMolecules, 2022
Visible-light photoredox catalysis has been established as a popular and powerful tool for organic transformations owing to its inherent characterization of environmental friendliness and sustainability in the past decades.
Qian Xiao, Qing-Xiao Tong, Jian-Ji Zhong
doaj   +1 more source

Ketones from aldehydes via alkyl C(sp3)−H functionalization under photoredox cooperative NHC/palladium catalysis

open access: yesNature Communications, 2023
Direct synthesis of ketones from aldehydes features high atom- and step-economy. Yet, the coupling of aldehydes with unactivated alkyl C(sp3)-H remains challenging.
Hai-Ying Wang   +4 more
doaj   +1 more source

Combined Photoredox Catalysis for Value-Added Conversion of Contaminants at Spatially Separated Dual Active Sites

open access: yesResearch, 2023
As 2 indispensable counterparts in one catalysis system, the independent reduction and oxidation reactions require synergetic regulation for cooperatively promoting redox efficiency.
Jieyuan Li   +8 more
doaj   +1 more source

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