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Dawn of photoredox catalysis [PDF]
Proceedings of the Japan Academy. Series B, Physical and Biological SciencesPhotoredox catalysis, which facilitates organic transformations under visible-light irradiation, including sunlight, has garnered considerable attention as a cornerstone of green chemistry.
Munetaka AKITA
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Cooperative Photoredox and Asymmetric Catalysis [PDF]
CHIMIA, 2016 Chemical processes combining visible-light-activated redox catalysis with asymmetric catalysis are reviewed, including enamine catalysis in the presence or absence of an additional photoredox sensitizer, phase transfer catalysis exploiting an in
Haohua Huo, Eric Meggersa
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Photoredox Catalysis Using Heterogenized Iridium Complexes** [PDF]
Chemistry – A European Journal, 2021 Abstract Heterogenized photoredox catalysts provide a path for sustainable chemical synthesis using highly tunable, reusable constructs. Here, heterogenized iridium complexes as photoredox catalysts were assembled via covalent attachment to metal oxide surfaces (ITO, ZrO 2 ,
Kelly L. Materna, Leif Hammarström
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Molecular Rubies in Photoredox Catalysis
Frontiers in Chemistry, 2022 The molecular ruby [Cr(tpe)2]3+ and the tris(bipyridine) chromium(III) complex [Cr(dmcbpy)3]3+ as well as the tris(bipyrazine)ruthenium(II) complex [Ru(bpz)3]2+ were employed in the visible light-induced radical cation [4+2] cycloaddition (tpe = 1,1,1 ...
Steven Sittel +2 more
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Asymmetric counteranion-directed photoredox catalysis [PDF]
Science, 2023 Photoredox catalysis enables distinctive and broadly applicable chemical reactions, but controlling their selectivity has proven to be difficult. The pursuit of enantioselectivity is a particularly daunting challenge, arguably because of the high energy of the activated radical (ion) intermediates, and previous approaches have invariably required ...
Sayantani Das +5 more
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Aromatic Chlorosulfonylation by Photoredox Catalysis [PDF]
ChemSusChem, 2016 AbstractVisible‐light photoredox catalysis enables the efficient synthesis of arenesulfonyl chlorides from anilines. The new protocol involves the convenient in situ preparation of arenediazonium salts (from anilines) and the reactive gases SO2 and HCl (from aqueous SOCl2).
Michal Májek +2 more
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Photoredox Catalysis for Polymerization Reactions
CHIMIA, 2012 Photoredox catalysis is now well-known in organic synthesis for the formation of free radicals under very soft irradiations conditions (e.g. sunlight, household fluorescence or LED bulbs, Xe lamp).
Jacques Lalevée +7 more
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Chemistry glows green with photoredox catalysis [PDF]
Nature Communications, 2020 Can organic chemistry mimic nature in efficiency and sustainability? Not yet, but recent developments in photoredox catalysis animated the synthetic chemistry field, providing greener opportunities for industry and academia.
Giacomo E. M. Crisenza, Paolo Melchiorre
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Modeling and Simulation of Reaction Environment in Photoredox Catalysis: A Critical Review
Frontiers in Chemical Engineering, 2022 From the pharmaceutical industry’s point of view, photoredox catalysis has emerged as a powerful tool in the field of the synthesis of added-value compounds.
Gabriela Xavier de Oliveira +4 more
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