Results 31 to 40 of about 8,315 (196)

Visible-light-mediated copper photocatalysis for organic syntheses

open access: yesBeilstein Journal of Organic Chemistry, 2021
Photoredox catalysis has been applied to renewable energy and green chemistry for many years. Ruthenium and iridium, which can be used as photoredox catalysts, are expensive and scarce in nature.
Yajing Zhang   +4 more
doaj   +1 more source

Visible light driven perovskite-based photocatalysts: A new candidate for green organic synthesis by photochemical protocol

open access: yesCurrent Research in Green and Sustainable Chemistry, 2020
Photoredox catalysis, which can legitimately change visible-light (solar energy) into chemical energy, is a swiftly rising and promising approach to instigate chemical reactions because solar energy is clean, inexpensive, boundless and simply available ...
Anshu Dandia   +3 more
doaj   +1 more source

Olefination of Alkyl Halides with Aldehydes by Merging Visible-Light Photoredox Catalysis and Organophosphorus Chemistry

open access: yesiScience, 2018
Summary: Carbon-carbon double bond (C=C) formation is a crucial transformation in organic chemistry. Visible-light photoredox catalysis provides economical and sustainable opportunities for the development of novel and peculiar organic reactions. Here we
Min Jiang   +4 more
doaj   +1 more source

An anion-binding approach to enantioselective photoredox catalysis. [PDF]

open access: yesScience
Photoredox catalysis has emerged as a transformative strategy in synthetic chemistry, enabling a wide variety of valuable chemical reactions through generation of highly reactive radical ion intermediates. Pairing chiral counteranions with cation radical intermediates provides a potentially generalizable tool for controlling absolute stereochemistry in
Vojáčková P, Jacobsen EN.
europepmc   +3 more sources

Dicyanopyrazine: 10th Anniversary in Photoredox Catalysis. [PDF]

open access: yesChem Rec
The last decade unveiled dicyanopyrazine as a purely organic photocatalyst capable of initiating a variety of unprecedented photoredox transformations. The latest discoveries also pointed to a facile Mallory‐type photocyclization of the catalyst to quinoxaline‐2,3‐dicarbonitrile derivative, which proved to be the active catalytic species. Its principal
Burešová Z, Bureš F.
europepmc   +3 more sources

Ru-Photoredox-Catalyzed Decarboxylative Oxygenation of Aliphatic Carboxylic Acids through N‑(acyloxy)phthalimide [PDF]

open access: yes, 2018
Decarboxylative aminoxylation of aliphatic carboxylic acid derivatives with (2,2,6,6-tetramethylpiperidin-1-yl)­oxyl (TEMPO) in the presence of ruthenium photoredox catalysis is reported.
Zhen Chen (129176)   +5 more
core   +1 more source

Visible-light photoredox catalysis with organic polymers [PDF]

open access: yes, 2023
The development of photocatalysts to drive organic reactions is a frontier research topic. Organic polymers can be well tuned in terms of structural and photophysical properties and, therefore, constitute a promising class of photocatalysts in photoredox
Haining Tian   +7 more
core   +1 more source

Synergistic photoredox and copper catalysis by diode-like coordination polymer with twisted and polar copper–dye conjugation

open access: yesNature Communications, 2020
Synergistic photoredox–copper catalysis is limited by fluorescence quenching of Cu(II) ions to photoreductive dyes in solution. Here, the authors compromise photoreduction and Cu(II) catalysis by diode-like coordination polymer with twisted Cu(II)–dye ...
Yusheng Shi   +5 more
doaj   +1 more source

Recent advancements in iodide/phosphine-mediated photoredox radical reactions

open access: yesBeilstein Journal of Organic Chemistry, 2023
Photoredox catalysis plays a crucial role in contemporary synthetic organic chemistry. Since the groundbreaking work of Shang and Fu on photocatalytic decarboxylative alkylations in 2019, a wide range of organic transformations, such as alkylation ...
Tinglan Liu   +3 more
doaj   +1 more source

Lead halide perovskites for photocatalytic organic synthesis

open access: yesNature Communications, 2019
While photoredox catalysis provides organic chemistry new avenues for chemical reactions, typical photocatalysts require expensive noble metals and show modest stabilities.
Xiaolin Zhu   +5 more
doaj   +1 more source

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