RECENTES APLICAÇÕES EM SÍNTESE ORGÂNICA DE CATÁLISE FOTO REDOX MEDIADA POR LUZ VISÍVEL
Química Nova, 2015 In the past few years, photoredox catalysis has become a powerful tool in the field of organic synthesis. Using this efficient method, it is possible to excite organic compounds from visible light and attain alternative mechanistic pathways for the ...
Angelina M. de Almeida +2 more
doaj +1 more source
A dual catalytic strategy for carbon-phosphorus cross-coupling via gold and photoredox catalysis. [PDF]
, 2014 A new method for the P-arylation of aryldiazonium salts with H-phosphonates via dual gold and photoredox catalysis is described. The reaction proceeds smoothly at room temperature in the absence of base and/or additives, and offers an efficient approach ...
He, Ying, TOSTE, F. Dean, Wu, Hongmiao
core +1 more source
Radical Fluoroalkylation Reactions [PDF]
, 2018 Recent protocols and reactions for catalytic radical perfluoroalkylations will be described. The production of perfluoroalkyl radicals (RF = CnF2n+1, n ≥ 2), which effect both addition and substitution reactions on organic substrates, can be realized ...
Barata Vallejo, Sebastian +2 more
core +1 more source
Advanced Energy & Sustainability Research, 2023 CO2 reduction (CO2RR) with selective benzyl alcohol (BA) oxidation in a single photoredox reaction can simultaneously utilize photogenerated electrons and holes to realize efficient production of fuels and value‐added chemicals.
Jian Lei +6 more
doaj +1 more source
Functionalized Polyamine Synthesis with Photoredox Catalysis
Chemistry – A European Journal, 2023 AbstractPolyamines, such as putrescine and spermidine, are pivotal in various biological processes across living organisms. Despite their significance, structurally modified polyamines offer a less‐explored avenue for discovering bioactive compounds. The limitation is attributed to the synthetic difficulty of accessing functionalized polyamines.
Yuta Makihara +4 more
openaire +2 more sources
Advances in asymmetric organocatalysis over the last 10 years
Nature Communications, 2020 Organocatalysis has become a major pillar of (asymmetric) catalysis. Here, the authors discuss recent trends in organocatalytic activation modes for challenging stereoselective transformations and the emerging integration with other fields, such as ...
Shao-Hua Xiang, Bin Tan
doaj +1 more source
Photochemical Approaches to Complex Chemotypes: Applications in Natural Product Synthesis. [PDF]
, 2016 The use of photochemical transformations is a powerful strategy that allows for the formation of a high degree of molecular complexity from relatively simple building blocks in a single step. A central feature of all light-promoted transformations is the
Kärkäs, Markus D. +2 more
core +2 more sources
Visible-light photoredox catalyzed synthesis of pyrroloisoquinolines via organocatalytic oxidation/[3 + 2] cycloaddition/oxidative aromatization reaction cascade with Rose Bengal [PDF]
, 2014 Pyrrolo[2,1-a]isoquinoline alkaloids have been prepared via a visible light photoredox catalyzed oxidation/[3 + 2] cycloaddition/oxidative aromatization cascade using Rose Bengal as an organo-photocatalyst.
Lau, Jonathan +2 more
core +7 more sources
Visible-light-mediated copper photocatalysis for organic syntheses
Beilstein Journal of Organic Chemistry, 2021 Photoredox catalysis has been applied to renewable energy and green chemistry for many years. Ruthenium and iridium, which can be used as photoredox catalysts, are expensive and scarce in nature.
Yajing Zhang +4 more
doaj +1 more source
Semiheterogeneous Dual Nickel/Photocatalytic (Thio)etherification Using Carbon Nitrides [PDF]
, 2019 A carbon nitride material can be combined with homogeneous nickel catalysts for light-mediated cross-couplings of aryl bromides with alcohols under mild conditions.
Cavedon, Cristian +3 more
core +1 more source