Results 171 to 180 of about 105,486 (290)

On the stability and nature of adsorbed pentene in Bronsted acid zeolite H-ZSM-5 at 323 K [PDF]

open access: yes, 2016
Cnudde, Pieter   +6 more
core   +1 more source

Isolation and Reactivity of a Square‐Planar Trisamido Silane

open access: yesAngewandte Chemie International Edition, EarlyView.
We report the synthesis and comprehensive characterisation of a square‐planar Si(+IV) hydride supported by an unsymmetric, trianionic and dearomatised N,N,N‐pincer ligand. This system enables element–ligand cooperative reactivity as an alternative to silicon‐centred redox chemistry, illuminating a largely unexplored regime in high‐valent silicon ...
David M. J. Krengel   +5 more
wiley   +1 more source

Visible light-mediated 1,2-difunctionalization reactions involving 4-cyanopyridines. [PDF]

open access: yesRSC Adv
Raymand P   +5 more
europepmc   +1 more source

Mapping the Reactivity of the C═C Bond of Cyclic Enol Ether Derivatives of Sugars: Nucleophilicity Parameters of Glycals

open access: yesAngewandte Chemie International Edition, EarlyView.
Endo or Exo? The first quantitative kinetic mapping of the nucleophilic reactivity of endo‐ and exo‐glycal compounds highlighted that endo‐glycals are typically 102 times less reactive than their corresponding parent cyclic enol ethers while exo‐glycals are 103 more nucleophilic. This experimental and computational structure–reactivity study highlights
Sophie Rodrigues   +7 more
wiley   +1 more source

Photooxidative Copper(II) Catalysis for Promoting anti-Markovnikov Hydration of Alkenes. [PDF]

open access: yesNat Commun
Oku N   +6 more
europepmc   +1 more source

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