Photoredox-Neutral Platform for Direct Decarboxylative Cyclopropanation <i>via</i> Acridine-Iron Dual Catalysis. [PDF]
Bhatt K +7 more
europepmc +1 more source
A Carbon‐Induced Surface Reconstruction on an Operating Fischer–Tropsch Catalyst
It is widely believed that a cobalt Fischer–Tropsch catalyst initially undergoes an activity‐enhancing roughening, driven by the high chemical potential of carbon. In this operando STM and DFT study, we simulate such conditions. We show that, instead, a triangular stacking‐fault reconstruction may form, leaving the catalytic activity unchanged ...
Sebastian Kläger +3 more
wiley +1 more source
Stereoselective Synthesis and Functionalization of Acetylenic Boronic Esters. [PDF]
Schäfer P, Kazmaier U.
europepmc +1 more source
Catalytic Sulfur‐Atom Transfer Enabled by a Bis(disulfide) Titanium Complex
Multi‐electron transformations with titanium are underexplored due to limited access to low‐valent precursors. The four‐electron activation of elemental sulfur by a Ti(IV) complex yields a rare titanium bis(disulfide) complex, enabling the efficient catalytic synthesis of isothiocyanates from isonitriles under mild conditions.
Sebastian Samir Cremer +3 more
wiley +1 more source
Electrochemical hydroxylation of alkenes with H<sub>2</sub>O. [PDF]
Yang G, Jia J, Deng Y, Qiu Y.
europepmc +1 more source
Transition-Metal Hydride Catalysis Meets Nitrenoid Transfer: Design Principles for Precision C-N Bond Formation. [PDF]
Lyu X, Choi H, Chang S.
europepmc +1 more source
High-Fidelity Transfer of Chiral Sulfonimidoyl Radicals. [PDF]
Li R +10 more
europepmc +1 more source
Palladium-catalyzed asymmetric migratory diarylation of unactivated directing-group-free internal alkenes. [PDF]
Fan L +6 more
europepmc +1 more source
(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications. [PDF]
Eghbarieh N +5 more
europepmc +1 more source
Oxidizing pollutants can disrupt nestmate recognition in ants. [PDF]
Jiang NJ +6 more
europepmc +1 more source

