Results 221 to 230 of about 104,551 (278)

Titanium-Catalyzed Intermolecular Hydrothiomethylation of Alkenes. [PDF]

Chemistry
Thye H, Fornfeist F, Schlüschen LL, Doye S.   +3 more
europepmc   +1 more source

β‐Scission of Tertiary Alcohols on a Platinum‐Loaded Titanium Dioxide Photocatalyst for C─C Bond‐Forming Reactions

Chemistry – A European Journal, EarlyView.
A strategy for the Pt/TiO2‐photocatalyzed β‐scission of nonactivated 3° alcohols in the absence of external oxidants and additives was developed. A wide variety of C‐centered radicals were generated and subsequently engaged in C─C bond‐forming reactions.
Shu Sakurai, Sha Xue, Shogo Mori, Susumu Saito   +3 more
wiley   +1 more source

Photocatalytic delayed hydration by alkene-alkene coupling: Modular access to highly substituted γ- and δ-lactones. [PDF]

Sci Adv
Ren YF, Chen JK, Chen XY, Du HW, Yu Q, Shu W.   +5 more
europepmc   +1 more source

Dual Ligand‐Enabled Nondirected C─H Olefination of (Hetero)Arenes for the Synthesis of Clickable Derivatives

Chemistry – A European Journal, EarlyView.
We report an efficient method for late‐stage installation of “clickable” alkyne groups into diverse (hetero)arenes. Using a dual‐ligand palladium catalyst that combines an NASA ligand with an N‐heterocycle, an acrylate unit bearing a terminal alkyne can be introduced via nondirected C─H activation.
Tommaso Braga, Maria Hergert, Manuel van Gemmeren   +2 more
wiley   +1 more source

Thianthrenium Salts in Photochemistry. [PDF]

Acc Chem Res
Bai Z, Ritter T.
europepmc   +1 more source

Addition Reactions of Phosphorus‐Centered Radicals onto Olefins: Interplay Between Stability and Reactivity

Chemistry – A European Journal, EarlyView.
The energetics of the addition reaction of P‐centered radicals onto alkenes are primarily ruled by the stability of the attacking radical, as outlined by the computational screening of a wide range of reactions. In addition, donor‐acceptor substituents at the olefin have an important tuning role.
Meng Yang, Julianna Oláh, Zoltán Benkő   +2 more
wiley   +1 more source

Photoredox-controlled chemo-divergent, regio-, and stereoselective difunctionalization of olefins via switchable SO₂ reintegration. [PDF]

Sci Adv
Xia J, Zhu L, Lv Z, Guo Y, Lin L, Sun J, Zheng G, Zhang Q.   +7 more
europepmc   +1 more source

Enantioselectivity in Transition Metal Catalyzed Propargylic Substitution Reactions: A Theoretical Perspective

Chemistry – A European Journal, EarlyView.
Recent theoretical efforts to elucidate the origin of enantioselectivity in transition metal‐catalyzed propargylic substitution reactions are highlighted in this review. ABSTRACT In recent years, asymmetric catalytic propargylic substitution reactions have undergone remarkable development, enabling the construction of chiral carbon centers adjacent to ...
Ken Sakata, Yoshiaki Nishibayashi
wiley   +1 more source

Copper-Catalyzed Asymmetric Amino Lactonization of Alkenes: Direct Access to Enantioenriched 1,2-Alkylamino Alcohol Derivatives. [PDF]

J Am Chem Soc
Feng G, Hemric BN, Velopolcek M, Liu C, Wang Q.   +4 more
europepmc   +1 more source

Mechanochemical Synthesis of X-Vinylbenziodoxol(on)es and One-Pot Conversion to Complex Alkenes^*. [PDF]

Angew Chem Int Ed Engl
Doobary S, Braunreuther J, Inge AK, Olofsson B.   +3 more
europepmc   +1 more source