Results 191 to 200 of about 135,124 (268)

Site-specific ribozyme-mediated alkylation of DNA substrates. [PDF]

open access: yesNucleic Acids Res
He Y   +7 more
europepmc   +1 more source

Precisely Controlled Electrochemical Phosphonylation: Tailoring π‐Conjugated Polymer Properties for High‐Performance Organic Electrochemical Transistors

open access: yesAngewandte Chemie, EarlyView.
The electrochemical C–H phosphonylation enabled precise control over the degree of functionalization (DOF). Systematic tuning of DOF (0.06–0.16) led to improved µC*, transconductance, and time constant values. This finding demonstrates that moderate functionalization enhances organic electrochemical transistor (OECT) performance, opening new avenues ...
Kohei Taniguchi   +2 more
wiley   +1 more source

Machine Learning Accelerates Crystallization for Structure Determination

open access: yesAngewandte Chemie, EarlyView.
Single‐crystal x‐ray diffraction (SCXRD) is often constrained by the difficulty of obtaining suitable crystals. Here, a machine learning‐accelerated co‐crystal discovery workflow is established for a crystalline mate strategy that achieves over 95% prediction accuracy and experimentally delivers 114 co‐crystals from 120 candidates.
Cui‐Zhou Luan   +10 more
wiley   +1 more source

Azetidinylideneketenimines as a Multimodal Synthetic Platform: Coordination Chemistry and Cycloaddition‐Triggered Transformations

open access: yesAngewandte Chemie, EarlyView.
Cross‐coupling/homologation sequence between a stable three‐membered‐ring carbene and isocyanides enables facile and rapid access to novel methyleneketenimines and the first bis(methyleneketenimine). Reactivity studies gave rise to the first methyleneketenimine‐transition metal complexes, unique multimodal reactivity ranging from CO2, isocyanate ...
Taichi Koike   +3 more
wiley   +1 more source

Deprotonative C(sp3)/C(sp2)–H (Multi)Silylation of (Hetero)Arenes Mediated by NaTMP

open access: yesAngewandte Chemie, EarlyView.
An operationally simple protocol using a strongly basic sodium amide in combination with sterically emcumbered silicon electrophiles enables the deprotonative C–H (multi)silylation of a myriad of (hetero)arenes. Mechanistic investigations highlight the pivotal role of steric and coordination effects in controlling the regioselectivity and efficiency of
David Sánchez‐Roa   +6 more
wiley   +1 more source

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